采用水热合成法制备钛酸钠纳米管,然后依次与HNO3,正四丁基氢氧化铵水溶液(TBAOH)离子交换后,经过高速离心,将所得沉淀物分散于无水乙醇溶液中,并应用电泳沉积的方法成功地在不锈钢或导电玻璃表面构筑了钛酸纳米管薄膜.采用TEM、XRD、SEM及EDS等对纳米管薄膜的表面形貌、结构和组成等进行表征.结果表明,电泳沉积法制备钛酸纳米管薄膜致密均匀、厚度可控并与基体结合力良好;经高温烧结后,形貌基本保持不变,可望成为一种新的功能材料.文中还对纳米管薄膜的形成机理进行了讨论.
参考文献
[1] | Kasuga T.;Hoson A.;Sekino T.;Niihara K.;Hiramatsu M. .Formation of titanium oxide nanotube[J].Langmuir: The ACS Journal of Surfaces and Colloids,1998(12):3160-3163. |
[2] | Tsai C C;Teng H .[J].CHEMISTRY OF MATERIALS,2004,16:4352-4358. |
[3] | Sun X;Li Y .[J].Chemistry-A European Journal,2003,9:2229-2238. |
[4] | Jianguo H;Toyoki K;Shin-ya O .[J].Chemical Communications,2004,32:1008-1009. |
[5] | Ma R;Sasaki T;Bando Y .[J].Journal of the American Chemical Society,2004,126:10382-10388. |
[6] | Hiromasa T;Masahiro M .[J].Chemical Communications,2004,32:958-959. |
[7] | Tian Z R;Voigt J A;Liu J et al.[J].Journal of the American Chemical Society,2003,125:12384-12385. |
[8] | Tomoko K;Masayoshi H;Akihiko H .[J].Advanced Materials,1999,11:1307-1311. |
[9] | Chen Q;Zhou W;Du G et al.[J].Advanced Materials,2002,14:1208-1211.C. |
[10] | Wataru S;Osamu T;Yasushi M et al.[J].Journal of Materials Chemistry,2002,12:3814-3818. |
[11] | Kim J Y;Chung I;Choy J H et al.[J].CHEMISTRY OF MATERIALS,2001,13:2759-2761. |
[12] | Matsumoto Y;Funatsu A;Matsuo D et al.[J].Journal of Physical Chemistry B,2001,105:10893-10899. |
[13] | Wang N;Lin H;Li JB;Yang XZ;Chi B .Electrophoretic deposition and optical property of titania nanotubes films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(2):649-652. |
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