用溶胶-凝胶方法以正硅酸乙酯、硼酸、乙醇钠为先驱体,盐酸为催化剂合成了钠硼硅玻璃,该均质基玻璃的化学组成为:5.74Na2O-21.38B2O3-72.88SiO2 (NBS).用氩离子激光器488 nm为激发光源,硅探测器检测可见光,对制备的玻璃进行了发射光谱检测,在可见光区域发现了非常强的发光,呈现强的、宽的发射带510nm～780nm,峰值位置位于541 nm和615 nm.简要讨论了发射光谱的特性和结构的起因.
参考文献
| [1] | Mackenzie J D .[J].Journal of Non-Crystalline Solids,1988,100:162. |
| [2] | Klien L C;Sakka S.Fibres from Sol-GelProcess[M].Park Ridge: N.J.USA Noyes Publications,2000:140. |
| [3] | Chang J H;Yasumori A;Kawazoe H;Yamane M .[J].Journal of Non-Crystalline Solids,1990,121:177. |
| [4] | Xiang W D .Sol-Gel Preparation of Third Order Nonlinear Optical Glasses[D].杭州:浙江大学,1995. |
| [5] | Hoof G W T et al.[J].Applied Physics Letters,1992,61:2344. |
| [6] | Shimizu T;Iwayama et al.[J].Journal of Applied Physics,1994,75:7779. |
| [7] | Kanimitsu Y et al.[J].Physical Review B,1993,48:4883. |
| [8] | Itoh C;Suzuki T;Itoh N .[J].Physical Review B,1990,41:3794. |
| [9] | Hinic I I;Stanic G M;Popoviv Z V .[J].Journal of Sol-Gel Science and Technology,1999,14:281. |
| [10] | Ayers MR;Hunt AJ .Visibly photoluminescent silica aerogels[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,1997(2/3):229-235. |
| [11] | Sakurai Y et al.[J].Journal of Applied Physics,1999,86:370. |
| [12] | Nishikawa H.;Ito D.;Sakurai Y.;Nagasawa K.;Ohki Y.;Watanabe E. .VISIBLE PHOTOLUMINESCENCE FROM SI CLUSTERS IN GAMMA-IRRADIATED AMORPHOUS SIO2[J].Journal of Applied Physics,1996(6):3513-3517. |
| [13] | Griscom D L;Friebele E J .[J].Physical Review B,1986,39:7524. |
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