二氧化碳作为温室气体和储量大、无毒且可循环利用的碳资源,其化学利用受到了人们的广泛关注. 二氧化碳与环氧化合物通过环加成反应制备环状碳酸酯是二氧化碳化学法利用最为有效的途径之一. 本文综述了近年来该反应的研究进展,讨论了催化剂作用下的反应机理.
参考文献
[1] | Kruper W J;Dellar D D .[J].Journal of Organic Chemistry,1995,60(03):725. |
[2] | Paddock R L;Nguyen S T .[J].Journal of the American Chemical Society,2001,123(46):11498. |
[3] | Lu X B;He R;Bai C .[J].Journal of Molecular Catalysis A:Chemical,2002,186(1-2):1. |
[4] | Lu X B;Feng X J;He R .[J].Applied Catalysis A:General,2002,234(1-2):25. |
[5] | Lu X B;Zhang Y J;Liang B;Li X Wang H .[J].Journal of Molecular Catalysis A:Chemical,2004,210(1-2):31. |
[6] | Lu XB;Zhang YJ;Jin K;Luo LM;Wang H .Highly active electrophile-nucleophile catalyst system for the cycloaddition of CO2 to epoxides at ambient temperature[J].Journal of Catalysis,2004(2):537-541. |
[7] | Paddock R L;Hiyama Y;McKay J M;Nguyen S T .[J].Tetrahedron Letters,2004,45(09):2023. |
[8] | Paddock R L;Nguyen S T.[J].Chemical Communications,2004(14):1622. |
[9] | Chang T;Jing H W;Jin L L;Qiu W Y .[J].Journal of Molecular Catalysis A:Chemical,2006,264(1-2):241. |
[10] | Lu X B;Liang B;Zhang Y J;Tian Y Z Wang Y M Bai C X Wang H Zhang R .[J].Journal of the American Chemical Society,2004,126(12):3732. |
[11] | Berkessel A;Brandenburg M .Catalytic asymmetric addition of carbon dioxide to propylene oxide with unprecedented enantioselectivity[J].Organic letters,2006(20):4401-4404. |
[12] | Chen S W;Kawthekar R B;Kim J .[J].Tetrahedron Letters,2007,48(02):297. |
[13] | Kim H S;Kim J J;Lee B G;Jung O S Jang H G Kang S O .[J].Angewandte Chemie International Edition,2000,39(22):4096. |
[14] | Kim H S;Kim J J;Lee S D;Lah M S Moon D Jang H G .[J].Chemistry-A European Journal,2003,9(03):678. |
[15] | Kim HS;Bae JY;Lee JS;Kwon OS;Jelliarko P;Lee SD;Lee SH .Phosphine-bound zinc halide complexes for the coupling reaction of ethylene oxide and carbon dioxide[J].Journal of Catalysis,2005(1):80-84. |
[16] | De Pasquale R L.[J].Journal of the Chemical Society,Chemical Communications,1973(05):157. |
[17] | Tsuda T;Chujo Y;Saegusa T.[J].Journal of the Chemical Society,Chemical Communications,1976(11):415. |
[18] | Li F W;Xia C G;Xu L W;Sun W Chen G X.[J].Chemical Communications,2003(16):2042. |
[19] | 李福伟,肖林飞,夏春谷.高效Ni/Zn催化剂体系固定CO2与环氧化合物的环加成反应[J].化学学报,2004(21):2195-2199. |
[20] | Shen Y M;Duan W L;Shi M .[J].Journal of Organic Chemistry,2003,68(04):1559. |
[21] | Shen Y M;Duan W L;Shi M .[J].Advanced Synthesis and Catalysis,2003,345(03):337. |
[22] | Huang JW.;Shi M. .Chemical fixation of carbon dioxide by NaI/PPh3/PhOH[J].The Journal of Organic Chemistry,2003(17):6705-6709. |
[23] | Shen Y M;Duan W L;Shi M.[J].European Journal of Organic Chemistry,2004(14):3080. |
[24] | Jing HW;Nguyen ST .SnCl4-organic base: Highly efficient catalyst system for coupling reaction of CO2 and epoxides[J].Journal of molecular catalysis, A. Chemical,2007(26):12-15. |
[25] | Fujinami T;Suzuki T;Kamiya M;Fukuzawa S I Sakai S .[J].Chemistry Letters,1985,14(02):199. |
[26] | Trost B M;Angle S R .[J].Journal of the American Chemical Society,1985,107(21):6123. |
[27] | Aye K T;Gelmini L;Payne N C;Vittal J J Puddephatt R J .[J].Journal of the American Chemical Society,1990,112(06):2464. |
[28] | Man ML;Lam KC;Sit WN;Ng SM;Zhou ZY;Lin ZY;Lau CP .Synthesis of heterobimetallic Ru-Mn complexes and the coupling reactions of epoxides with carbon dioxide catalyzed by these complexes[J].Chemistry: A European journal,2006(4):1004-1015. |
[29] | Srivastava R;Bennur TH;Srinivas D .Factors affecting activation and utilization of carbon dioxide in cyclic carbonates synthesis over Cu and Mn peraza macrocyclic complexes[J].Journal of molecular catalysis, A. Chemical,2005(2):199-205. |
[30] | Welton T .[J].Chemical Reviews,1999,99(08):2071. |
[31] | Dupont J;de Souza R F;Suarez P A Z .[J].Chemical Reviews,2002,102(10):3667. |
[32] | Peng J J;Deng Y Q .[J].New Journal of Chemistry,2001,25(04):639. |
[33] | Caló V;Nacci A;Monopoli A;Fanizzi A .[J].Organic Letters,2002,4(15):2561. |
[34] | Anthony J L;Maginn E J;Brennecke J F .[J].Journal of Physical Chemistry B,2002,106(29):7315. |
[35] | Corma A;Garcia H .[J].Chemical Reviews,2003,103(11):4307. |
[36] | Kawanami H;Sasaki A;Matsui K;Ikushima Y.[J].Chemical Communications,2003(07):896. |
[37] | Kossev K;Koseva N;Troev K .[J].Journal of Molecular Catalysis A:Chemical,2003,194(1-2):29. |
[38] | Kim H S;Kim J J;Kim H;Jang H G .[J].Journal of Catalysis,2003,220(01):44. |
[39] | Li F W;Xiao L F;Xia C G;Hu B .[J].Tetrahedron Letters,2004(45):8307. |
[40] | 李福伟,肖林飞,夏春谷.溴化锌-离子液体复合催化体系高效催化合成环状碳酸酯[J].高等学校化学学报,2005(02):343-345. |
[41] | Sun JM;Fujita SI;Zhao FY;Arai M .A highly efficient catalyst system of ZnBr2/n-Bu4NI for the synthesis of styrene carbonate from styrene oxide and supercritical carbon dioxide[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2005(2):221-226. |
[42] | Sun JM;Fujita S;Arai M .Development in the green synthesis of cyclic carbonate from carbon dioxide using ionic liquids[J].Journal of Organometallic Chemistry,2005(15):3490-3497. |
[43] | Sun JM;Fujita S;Zhao FY;Arai M .Synthesis of styrene carbonate from styrene oxide and carbon dioxide in the presence of zinc bromide and ionic liquid under mild conditions[J].Green chemistry,2004(12):613-616. |
[44] | Bok T;Noh E K;Lee B Y .[J].Bulletin of the Korean Chemical Society,2006,27(08):1171. |
[45] | Ono F;Qiao K;Tomida D;Yokoyama C .Rapid synthesis of cyclic carbonates from CO2 and epoxides under microwave irradiation with controlled temperature and pressure[J].Journal of molecular catalysis, A. Chemical,2007(1/2):223-226. |
[46] | Xie H B;Li S H;Zhang S B .[J].Journal of Molecular Catalysis A:Chemical,2006,250(1-2):30. |
[47] | Palgunadi J;Kwon O S;Lee H;Bae J Y Ahn B S Min N Y Kim H S .[J].Catalysis Today,2004,98(04):511. |
[48] | Kim, YJ;Varma, RS .Tetrahaloindate(III)-based ionic liquids in the coupling reaction of carbon dioxide and epoxides to generate cyclic carbonates: H-bonding and mechanistic studies[J].The Journal of Organic Chemistry,2005(20):7882-7891. |
[49] | Sun J;Wang L;Zhang SJ;Li ZX;Zhang XP;Dai WB;Mori RH .ZnCl2/phosphonium halide: An efficient Lewis acid/base catalyst for the synthesis of cyclic carbonate[J].Journal of molecular catalysis, A. Chemical,2006(1/2):295-300. |
[50] | Yano T;Matsui H;Koike T;Ishiguro H Fujihara H Yoshihara M Maeshima T.[J].Chemical Communications,1997(12):1129. |
[51] | Yamaguchi K;Ebitani K;Yoshida T;Yoshida H Kaneda K .[J].Journal of the American Chemical Society,1999,121(18):4526. |
[52] | Tu M;Davis R J .[J].Journal of Catalysis,2001,199(01):85. |
[53] | Hattori H .[J].Chemical Reviews,1995,95(03):537. |
[54] | Yasuda H;He L N;Sakakura T .[J].Journal of Catalysis,2002,209(02):547. |
[55] | Xiao LF;Li FW;Xia CG .An easily recoverable and efficient natural biopolymer-supported zinc chloride catalyst system for the chemical fixation of carbon dioxide to cyclic carbonate[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2005(1/2):125-129. |
[56] | Yasuda H;He LN;Takahashi T;Sakakura T .Non-halogen catalysts for propylene carbonate synthesis from CO2 under supercritical conditions[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2006(0):177-180. |
[57] | Yasuda H;He LN;Sakakura T;Hu CW .Efficient synthesis of cyclic carbonate from carbon dioxide catalyzed by polyoxometalate: the remarkable effects of metal substitution[J].Journal of Catalysis,2005(1):119-122. |
[58] | Sun D W;Zhai H J .[J].Catalysis Communications,2007,8(07):1027. |
[59] | Lu X B;Wang H;He R .[J].Journal of Molecular Catalysis A:Chemical,2002,186(1-2):33. |
[60] | Alvaro M;Baleizao C;Das D;Carbonell E;Garcia H .CO2 fixation using recoverable chromium salen catalysts: use of ionic liquids as cosolvent or high-surface-area silicates as supports[J].Journal of Catalysis,2004(1):254-258. |
[61] | Kim H S;Kim J J;Kwon H N;Chung M J Lee B G Jang H G .[J].Journal of Catalysis,2002,205(01):226. |
[62] | Shiels RA;Jones CW .Homogeneous and heterogeneous 4-(N,N-dialkylamino)pyridines as effective single component catalysts in the synthesis of propylene carbonate[J].Journal of molecular catalysis, A. Chemical,2007(26):160-166. |
[63] | Zhang X H;Zhao N;Wei W;Sun Y H .[J].Catalysis Today,2006,115(1-4):102. |
[64] | Shi F;Zhang Q H;Ma Y B;He Y D Deng Y Q .[J].Journal of the American Chemical Society,2005,127(12):4182. |
[65] | Jagtap SR;Raje VP;Samant SD;Bhanage BM .Silica supported polyvinyl pyridine as a highly active heterogeneous base catalyst for the synthesis of cyclic carbonates from carbon dioxide and epoxides[J].Journal of molecular catalysis, A. Chemical,2007(1/2):69-74. |
[66] | Du Y;Wang J Q;Chen J Y;Cai F Tian J S Kong D L He L N .[J].Tetrahedron Letters,2006,47(08):1271. |
[67] | Wang J Q;Kong D L;Chen J Y;Cai F He L N .[J].Journal of Molecular Catalysis A:Chemical,2006,249(1-2):143. |
[68] | Xiao L F;Li F W;Peng J J;Xia C G .[J].Journal of Molecular Catalysis A:Chemical,2006,253(1-2):265. |
[69] | Takahashi T;Watahiki T;Kitazume S;Yasuda H Sakakura T.[J].Chemical Communications,2006(15):1664. |
[70] | Lai GQ;Peng JJ;Li JY;Qiu HY;Jiang JX;Jiang KZ;Shen YJ .Ionic liquid functionalized silica gel: novel catalyst and fixed solvent[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,2006(39):6951-6953. |
[71] | Wang J Q;Yue X D;Cai F;He L N .[J].Catalysis Communications,2007,8(02):167. |
[72] | Xie Y;Zhang Z F;Jiang T;He J L Han B X Wu T B Ding K L .[J].Angewandte Chemie International Edition,2007,46(38):7255. |
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