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研究了圆柱腔体共振频率的测量方法,测试了新建立的声速实验系统,结果显示圆柱共鸣腔具有较高的信噪比,共振频率的测量不确定度小于5×10^-6.采用Ar气(99.999%)标定了声速共鸣腔的有效长度,不确定度为1.8×10^-5。开展了303~333K下CO2的气相声速实验研究,实验结果表明,当实验工质具有较高的纯度(〉99.995%)时,气相声速的测量精度优于0.01%。

The measurement method of the frequency of a cylindrical resonator was investigated with a result of high signal-to-noise performance. Experimental study was conducted with the uncertainty of the resonance frequency reduced to 5 ×10^-6. Argon was used to calibrate the length and the radius of the cylinder with the uncertainty of 1.8×10^-5. Speed of sound for CO2 was measured from 303 to 333 K with a relative uncertainty of 0.01% when the purity of the substances better than 99.995%.

参考文献

[1] Moldover, M.R. .Optimizing acoustic measurements of the Boltzmann constant[J].Comptes rendus. Physique,2009(9):815-827.
[2] Ch. Tegeler;R. Span;W. Wagner .A New Equation of State for Argon Covering the Fluid Region for Temperatures From the Melting Line to 700 K at Pressures up to 1000 MPa[J].Journal of Physical and Chemical Reference Data,1999(3):779-850.
[3] Andrés F. Estrada-Alexanders;John J. Hurly .Kinematic viscosity and speed of sound in gaseous CO, CO_2, SiF_4, SF_6, C_4F_8, and NH_3 from 220 K to 375 K and pressures up to 3.4 MPa[J].The Journal of Chemical Thermodynamics,2008(2):193-202.
[4] Estrada-Alexanders AF.;Trusler JPM. .Speed of sound in carbon dioxide at temperatures between (220 and 450) K and pressures up to 14 MPa[J].The Journal of Chemical Thermodynamics,1998(12):1589-1601.
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