欢迎登录材料期刊网

材料期刊网

高级检索

非晶态合金由于其优异的物理化学性能而备受研究者重视.特殊的空间结构使其表现出良好的化学活性,利用其亚稳态特性赋予电极材料特殊的化学性能,可将非晶态合金用于析氢电极材料.综述了非晶态合金阴极材料的研究进展,对过渡族金属元素的特性进行了分析,指出由过渡族金属元素组成的、具有低析氢超电势和低成本的非晶态合金复合镀层是目前与今后研究催化析氢电极材料的主要方向.

参考文献

[1] Giz M J;Machado S A S;Avaca L A et al.High area Ni-Zn and Ni-Co-Zn co-deposits as hydrogen electrodes in al-kaline solutions[J].Journal of Applied Electrochemistry,1992,22(08):973-977.
[2] Valand T;Burchardt T;Grontoft T .Structure and catalytic behavior of NiS,films with respect to the hydrogen evolution[J].Hydrogen Energy Progress,2002,27:39-44.
[3] S. J. Choi;J. Choi;C. Y. Seo .The optimal condition of acidic electroless copper plating method for Ti, Zr-based hydrogen storage alloys for electrode use[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2003(0):720-724.
[4] Magdalena Popczyk;Antoni Budniok;Andrzej Lasia .Electrochemical properties of Ni-P electrode materials modified with nickel oxide and metallic cobalt powders[J].International journal of hydrogen energy,2005(3):265-271.
[5] Jaksic M M .Advances in electroeatalysis for hydrogen evo-lution in the light of the Brewer Engel valance bond theory[J].Journal of Molecular Catalysis,1986,38:161-202.
[6] Hout J Y;Brossard L .In-situ activation of nickel cathodes by sodium molybdate during alkaline water electrolysis at constant current[J].Journal of Applied Electrochemistry,1990,20:281-288.
[7] Brown D E;Mahmood M N;Man M C M et al.Prepara-tion and characterization of low over voltage transition metal alloy electrocatalysis for hydrogen evolution in alkaline solu-tion[J].Eleetroehem Acts,1989,29:1551-1556.
[8] 牛振江,吴廷华,杨防祖,姚士冰,周绍民.非晶态Fe-Mo合金在碱性溶液中的电催化析氢活性[J].材料保护,2003(08):9-12.
[9] Jaksic M M .Towards the reversible electrode for hydrogen evolution in industrially important electrochemical processes[J].Hydrogen Energy Progress,1986,11:519-532.
[10] Chen L;Lasia A .Hydrogen evolution reaction on nickel-molybdenum powder electrodes[J].Journal of the Electrochemical Society,1992,139(12):3458-3464.
[11] 刘萍,唐致远,宋全生,赵孟,王媛媛.Ni-Mo合金电极的制备条件对其析氢性能的影响[J].电镀与精饰,2006(03):11-14.
[12] Hu W K;Cao X J;Wang F P et al.Short eommuniea-tion:a novel cathode for alkaline water electrolysis[J].Hydrogen Energy Progress,1997,22:441-443.
[13] G. Schiller;R. Henne;P. Mohr .High performance electrodes for an advanced intermittently operated 10-kw alkaline water electrolyzer[J].International journal of hydrogen energy,1998(9):761-765.
[14] Hu C C;Weng C Y .Hydrogen evolution activity on niekel-molybdenum deposits using experimental strategies[J].Appl Electroehem,2000,30:499-506.
[15] Jukic A.;Metikos-Hukovic M.;Piljac J. .Electrocatalytic behavior of the Co33Zr67 metallic glass for hydrogen evolution[J].Journal of molecular catalysis, A. Chemical,2001(2):293-302.
[16] 高诚辉.铁组金属-半金属非晶合金镀[J].材料保护,1991(01):7.
[17] 杜敏,高荣杰,蒲艳丽.电沉积Ni-S合金作碱液电解活性阴极的研究进展[J].腐蚀科学与防护技术,2001(z1):543-封3.
[18] 杜敏,高荣杰,魏绪钧.电沉积Ni-S合金阴极析氢反应[J].电源技术,2001(03):223-224,234.
[19] Paseka I .Sorption of hydrogen and kinetics of hydrogen evo-lution on amorphous Ni-S,electrodes[J].Electrochimica Acta,1993,38(16):2449-2454.
[20] Valand T;Burehardt T;Grotoft .Structure and catalytic be-havior of Ni-S,films with respect to the hydrogen evolution[J].Hydrogen Energy Progress,2002,27:39-44.
[21] Valand T;Burehardt T;Van Der Meet S F .The hydrogen evolution and eorrosion of amorphous FeS,films[J].Corrosion Science,2001,43:147-156.
[22] 李友遐,高诚辉,林有希,柳丽娜.非晶态镍磷镀层析氢阴极活性的控制与机理[J].材料保护,2004(01):27-29,32.
[23] Paseka I;Velicka J .Hydrogen evolution and hydrogen sorp-tion on amorphous smooth Me-P(x) (Me =Ni,Co and Fe-Ni) electrodes[J].Electrochemical Acts,1997,42(02):237-242.
[24] De Giz M J;Tremiliosi-Filho G;Fonzalez E R et al.The hydrogen evolution on amorphous nickle and cobalt alloys[J].Hydrogen Energy Progress,1995,20(06):423-427.
[25] 杨静,张存中,吴仲达.非晶态Ni-Mo-Co合金电极的制备和析氢性能[J].应用化学,2000(05):475-478.
[26] 王龙彪;黄清安;陈永言 等.电沉积Ni-Co-P合金析氢反应电催化行为的研究[J].电镀与涂饰,1998,17(04):1-3.
[27] 李宁,丁大勇,黎德育.非晶态Ni-Co-P膜层在碱性介质中的电催化析氢性能[J].哈尔滨工业大学学报,2005(09):1185-1188.
[28] Narayanan TSNS.;Selvakumar S.;Stephen A. .Electroless Ni-Co-P ternary alloy deposits: preparation and characteristics[J].Surface & Coatings Technology,2003(2/3):298-307.
[29] Han Q;Liu K;Chen J et al.A study of the eleetrodeposit-ed Ni-S alloys as hydrogen evolution reaction cathodes[J].Hydrogen Energy Progress,2003,28(11):1207-1212.
[30] 刘芳,何捍卫,周科朝,袁铁锤,刘红江,李军.电沉积Ni-S合金硫含量的影响因素[J].粉末冶金材料科学与工程,2005(01):60-64.
[31] Qing Han;Jianshe Chen;Kuiren Liu;Xin Li;Xujun Wei .The heat-treatment effect of amorphous Ni-S(La) electrode on the hydrogen evolution reaction in an alkaline media[J].International journal of hydrogen energy,2004(6):597-603.
[32] Qing Han;Kuiren Liu;Jianshe Chen;Xujun Wei .Hydrogen evolution reaction on amorphous Ni-S-Co alloy in alkaline medium[J].International journal of hydrogen energy,2003(12):1345-1352.
[33] Qing Han;Kuiren Liu;Jianshe Chen;Xin Li;Xujun Wei .Study of amorphous Ni-S-Co alloy used as hydrogen evolution reaction cathode in alkaline medium[J].International journal of hydrogen energy,2004(3):243-248.
[34] 谢原寿.水溶液电解新阴极材料Ni-Co-S-Mo合金的研究[J].电化学,1998(04):434.
[35] Pawar S H;Pendse M H .Electrodeposition of Dy-Ba-Cu alloyed films from aqueous bath[J].Materials Research Bulletin,1991,26(07):641-648.
[36] Pawar S H;Tonape M M;Shinde V N .Pulse e.leetrodeposi-tion of Y-Ba Cu alloyed films from an aqueous bath[J].Materials Chemistry and Physics,1993,35(01):86-91.
[37] Therese GHA.;Kamath PV. .Electrochemical synthesis of Ln(2)Cr(3)O(12)center dot 7H(2)O (Ln = La, Pr, Nd)[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,1998(1):1-7.
[38] Lokhande C D .Electrodeposition of yttrium from aqueous bath[J].Electrochemical Society of India,1992,41(04):221-224.
[39] Jundale S B;Lokhande C D .Electrosynthesis of Sm-Te films[J].Materials Chemistry and Physics,1994,37:333-337.
[40] Jundale S B;Lokhande C D .Studies on electrosynthesis of Sm-Se films[J].Materials Chemistry and Physics,1994,38:325-331.
[41] 吴俊,黄清安,喻敬贤.电沉积Ni-La-P合金上析氢的研究[J].武汉水利电力大学学报,1999(05):92-94.
[42] 邵光杰;秦秀娟;于升学 等.稀土对电沉积Ni-P合金镀层显微组织的影响[J].中国有色金属学报,2000,10(zk):239-241.
[43] Paseka I .Influence of Hydrogen Absorption in Amorphous Ni-P Electrode on Double Layer Capacitance and Charge Transfer Coefficient of Hydrogen Evolution Reaction[J].Electrochimica Acta,1999,44:4551-4558.
[44] Podesta J J;Piatti R CV;Arvia A J et al.The Behavior of Ni-Co-P Base Amorphous Alloys for Water Electrolysis in Strongly Alkaline Solutions Prepared Through Electroless Depositioa[J].Hydrogen Energy Progress,1992,17(01):9-22.
[45] 汪继红,费锡明,李伟.稀土铈对镍-钴-磷合金电极的析氢催化性能的影响[J].材料保护,2004(01):9-10.
[46] Brunelli K;Dabalaá M;Frattini R et al.Electrochemical behavior of Cu-Zr and Cu-Ti glassy alloys[J].Journal of Alloys and Compounds,2001,317-318:595-602.
[47] J. Panek;A. Serek;A. Budniok;E. Rowinski;E. Lagiewka .Ni + Ti composite layers as cathode materials for electrolytic hydrogen evolution[J].International journal of hydrogen energy,2003(2):169-175.
[48] 肖秀峰,刘榕芳.非晶态Ni-W-WC复合镀层的制备及镀层性能研究[J].材料保护,2003(04):46-47,50.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%