研究了纯Y和两种Fe-Y合金在600~800℃0.1MPa纯氧中的氧化.两种合金形成的外氧化膜包括Fe、Y的氧化物及其复合氧化物,并发生了Y的内氧化.内氧化区继承了原始合金的显微组织形貌,且内氧化区前沿无贫Y现象.这些特点是Y在基体金属中低的溶解度和合金中存在不同于基体金属α-Fe的金属间化合物相的直接结果.
The oxidation of two iron-based alloys containing 15wt % and 30wt % yttrium as well as pure yttrium has been studied in pure oxygen of 0. 1 MPa. Both alloys formed an external scale containing a mixture of iron and yttrium oxides and double Fe-Y oxides. A re- gion of internal oxidation of yttrium was formed in the alloys. The microstructure of the in- ternal oxidation region followed closely that of the original alloys and there was no any yttri- um depletion in the internal oxidation region. These results are examined by taking into ac- count the limited solubility of yttrium in iron and the presence of intermetallic compounds in the alloy.
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