低温离子渗硫技术克服了传统渗硫方法的不足，是目前最常用的FeS固体润滑薄膜制备方法。由于存在理论研究尚未完善、应用材料相对单一、微纳米硫化物薄膜表征困难等问题，该技术的应用推广及其工业化进程受到限制。综述了离子渗硫技术在渗硫机理、工艺研究、硫化物薄膜表征及渗硫层摩擦学性能等方面的研究进展，分析了渗硫层减摩作用机理和当前离子渗硫应用的基体材料类型，指出了其未来的发展方向。
ABSTRACT:Low-temperature ion sulfurizing technology overcomes many shortcomings existing in traditional sulfurizing methods, and has become the most commonly used preparation method of ferrous sulfide solid lubrication film. However, its theoretical study is not perfect yet, the sorts of materials applied are relatively deficient, and the characterization of micro/nano sulfide layer is diffi-cult, all these factors restrict its promotion and industrialization process. The achievements and disadvantages of ion sulfurizing technology based on principle and process research, characterization of sulfide film and its tribological properties were presented in this paper. The anti-friction mechanism of sulfide layer was discussed. The substrate types of ion sulfurizing were introduced and the future prospects of ion sulfurizing technology were proposed.
参考文献
| [1] | MA G Z;XU B S;WANG H D.The Low-temperature Ion Sulfurizing Technology and Its Applications[J].Physics Procedia,2013(50):131-138. |
| [2] | 张戈飞 .金属零件表面形成硫化物层的方法及设备[P].中国,85106828,1987-03-11. |
| [3] | 张燕,张行,刘朝辉,邓智平.热喷涂技术与热喷涂材料的发展现状[J].装备环境工程,2013(03):59-62. |
| [4] | Kang, JJ;Wang, CB;Wang, HD;Xu, BS;Liu, JJ;Li, GL .Characterization and tribological properties of composite 3Cr13/FeS layer[J].Surface & Coatings Technology,2009(14):1927-1932. |
| [5] | 刘沅东,王成彪,车延岗,袁静静,刘家浚.离子轰击热处理技术对轴承钢摩擦学性能的影响[J].机械工程学报,2011(05):126-133. |
| [6] | 戴兵,张恒华,黄波,高国强.DLC表面处理对高速钢耐磨性能的影响[J].表面技术,2008(06):24-26. |
| [7] | HU Chun-Hua;MA Shi-Ning;QIAO Yu-Lin et al.Forma-tion Mechanism of Ion Sulphurized Layer on Nitrocarburized Surface of 45 Steel[J].Materials Science and Technology,2008,16(01):52-57. |
| [8] | Hai-dou Wang;Bin-shi Xu;Jia-jun Liu;Da-ming Zhuang .The friction–reduction model of the iron sulfide film prepared by plasma source ion sulfuration[J].Surface & Coatings Technology,2007(9/11):5236-5239. |
| [9] | 黄文波,蒙继龙.离子渗硫技术进展[J].金属热处理,2001(07):43-45. |
| [10] | 王红波 .离子渗氮—渗硫复合处理对Ti-6Al-4V合金摩擦学性能的影响[D].长安大学,2009. |
| [11] | 江静华 .钢的稀土催化渗硫新工艺及渗层摩擦学性能研究[D].东南大学,2003. |
| [12] | 张君 .冷作模具钢Cr12MoV表面改性及摩擦学性能的研究[D].上海大学,2005. |
| [13] | 江静华,蒋建清,涂益友,杨恒,马爱斌,蔡磊.稀土催化低温熔融渗硫工艺及渗硫层组织形貌[J].中国稀土学报,2002(05):440-443. |
| [14] | 周潘兵,周浪.氧化层对渗氮动力学的影响[J].材料热处理学报,2005(04):102-105. |
| [15] | 王天生,于金库,董冰峰,张福成.1Cr18Ni9Ti不锈钢的喷丸表面纳米化及其对耐蚀性的影响[J].机械工程学报,2005(09):51-54. |
| [16] | Yue, W.;Gao, X.;Liu, Y.;Sun, X.;Wang, C.;Liu, J. .Tribological properties of sulfurized-nitrided layer prepared by a two-step method[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2011(11):1011-1016. |
| [17] | 马世宁,胡春华,乔玉林,王长生.活性屏离子渗硫层的结构与减摩耐磨性能研究[C].第7届全国表面工程学术会议暨第二届表面工程青年学术论坛论文集,2008:150-153. |
| [18] | 康蓉莉,冯雪艳,何恩山.兵器装备环境工程发展需求[J].装备环境工程,2010(03):56-58. |
| [19] | 唐殿福;卯石刚.钢的化学热处理[M].沈阳:辽宁科学技术出版社,2009 |
| [20] | 钟厉,戴仲谋,邵丽.循环N/C/O/S离子共渗对316Ti钢组织及耐腐蚀性的影响[J].表面技术,2012(03):67-70. |
| [21] | 徐永礼,庞祖高,马宽猷,韦曼云,黄银燕.RE-N-C-S-V-Nb多元共渗H13钢的热疲劳性能研究[J].表面技术,2013(05):35-38,44. |
| [22] | 万盛,韩彬,王勇,薛敏鹏.激光相变硬化-离子渗硫复合改性层的性能[J].金属热处理,2012(01):68-71. |
| [23] | Wang, H.-D.;Ma, G.-Z.;Xu, B.-S.;Si, H.-J.;Yang, D.-X. .Microstructure and vacuum tribological properties of 1Cr18Ni9Ti steel with combined surface treatments[J].Surface & Coatings Technology,2011(11):3546-3552. |
| [24] | 杨军胜 .采用复合渗镀技术提高Ti-6Al-4V摩擦学性能[D].长安大学,2010. |
| [25] | 孙雪洁 .渗氮层与渗氮/渗硫复合层在润滑条件下的摩擦学性能研究[D].北京:中国地质大学,2011. |
| [26] | Li-Na, Z.;Cheng-Biao, W.;Hai-Dou, W.;Bin-Shi, X.;Da-Ming, Z.;Jia-Jun, L.;Guo-Lu, L. .Tribological properties of WS_2 composite film prepared by a two-step method[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2010(1):16-21. |
| [27] | 田晓东,王利捷,郑文鹏.TC4钛合金表面辉光离子渗Mo渗S复合处理涂层的组织和摩擦学性能[J].表面技术,2013(02):4-6. |
| [28] | Kang Jia-jie;Wang Cheng-biao;Wang Hai-dou;Xu Bin-shi;Liu Jia-jun;Li Guo-lu .Research on tribological behaviors of composite Zn/ZnS coating under dry condition[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2012(6):1940-1943. |
| [29] | 车延岗,袁静静,刘沅东,马向东.35CrMo钢硫氮共渗层的摩擦学性能[J].材料保护,2010(08):25-28. |
| [30] | 杨臻,底月兰,张平,李奇,侯玉涛.CrN／MoS2固体自润滑复合膜渗硫层相结构研究[J].装甲兵工程学院学报,2012(04):78-82. |
| [31] | 董玉明.低温渗硫研究[J].机械工人（热加工）,2006(02):49,51. |
| [32] | 王海斗;徐滨士;刘家浚.微纳米硫系固体润滑[M].北京:科学出版社,2009:69-72. |
| [33] | GB/T 25898-2010.仪器化纳米压入试验方法-薄膜的压入硬度和弹性模量[S].北京:中国标准出版社,2011. |
| [34] | Hai-dou Wang;Da-ming Zhuang;Kun-lin Wang .The comparison on tribological properties of ion sulfuration steels under oil lubrication[J].Materials Letters,2003(15):2225-2232. |
| [35] | 马世宁,胡春华,朱乃姝.氮碳共渗-渗硫复合层的摩擦学行为[J].中国工程机械学报,2007(01):104-107. |
| [36] | 王海斗,徐滨士,刘家浚,庄大明.基体状态对FeS层固体润滑性能的影响[J].润滑与密封,2005(01):34-36. |
| [37] | 张平,曾庆强,蔡志海,李奇.激光淬火渗硫复合层的抗高温摩擦磨损性能[J].装甲兵工程学院学报,2010(01):71-73,82. |
| [38] | 杜明英,向楠,朱张校,武庆兰,张欣.灰铸铁离子渗氮渗硫复合处理改性层的摩擦学性能[J].金属热处理,2005(05):12-15. |
| [39] | Zhang N.;Liu JJ.;Fang XD.;Guan MX.;Zhuang DM. .Effect of sulphide layers on the tribological behavior of steels under boundary lubrication conditions[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2001(1/2):61-67. |
| [40] | Wang HD;Xu BS;Liu JJ;Zhuang DM .Investigation on friction and wear behaviors of FeS films on L6 steel surface[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2005(4):1084-1091. |
| [41] | 李新,马世宁,刘吉延.CrMoCu合金铸铁离子渗硫层的摩擦学性能研究[J].材料热处理学报,2008(03):156-158. |
| [42] | Kang, JJ;Wang, CB;Wang, HD;Xu, BS;Liu, JJ;Li, GL .Characterization and tribological properties of composite 3Cr13/FeS layer[J].Surface & Coatings Technology,2009(14):1927-1932. |
| [43] | 马世宁,胡春华.活性屏离子渗硫层的制备及形貌结构研究[J].装甲兵工程学院学报,2007(05):81-83. |
| [44] | 王海斗,庄大明,王昆林,刘家浚,方晓东,李永良.低温离子渗硫层的干摩擦学性能对比研究[J].材料热处理学报,2002(04):30-33. |
| [45] | 刘沅东,王成彪,岳文,田斌,袁科,刘家浚.磨损条件对轴承钢低温离子渗硫层摩擦学行为的影响[J].润滑与密封,2007(11):108-111,117. |
| [46] | 孟凡深,侯林峰.19CN5、20CrMnMo钢渗碳后硫化对摩擦磨损性能的影响[J].河南科技大学学报（自然科学版）,2004(04):6-9. |
| [47] | 葛利玲,路彩虹,井晓天,卢正欣,刘忠良.40Cr钢表面纳米化组织与性能的研究[J].表面技术,2008(02):11-13. |
| [48] | MA Guo-zheng;XU Bin-shi;WANG Hai-dou.Effects of Surface Nanocrystallization Pretreatment on Low-tempera-ture Ion Sulfurization Behavior of 1Cr18Ni9Ti Stainless Steel[J].Applied Surface Science,2010(257):1204-1210. |
| [49] | 乔玉林,胡春华,马世宁,王长生,杜云峰.活性屏离子渗硫工作气压对铝合金表面FeS固体润滑层的影响[J].材料保护,2010(10):53-54,57. |
| [50] | WANG Lijie,XING Yazhe,WANG Hongbo,HAO Jianmin.Effect of nitriding-sulfurizing composite treatment on the tribological behavior of titanium alloys[J].稀有金属（英文版）,2010(06):604-607. |
| [51] | 欧信兵,张津.强烈塑性变形表面纳米化的研究现状[J].表面技术,2008(03):60-64. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%