采用一种自主设计制备的含有端炔、醚键和酰亚胺环的硅烷偶联剂(AAS),对石英纤维/含硅芳炔复合材料进行增强、增韧改性.采用DSC、FT-IR以及TGA分析表征了AAS参与PSA的交联固化,与PSA形成良好的化学作用;XPS测试表明AAS与QF产生化学键合;SEM分析表明,AAS的使用改善了QF与PSA的粘结性能,提高了界面结合强度,常温条件下,复合材料的层间剪切强度(ILSS)和弯曲强度相比于未改性的分别提高了50.6%和43.0%,在250℃时,ILSS、弯曲强度的保留率分别为66.0%和84.2%.经过AAS改性后,复合材料的耐冲击性能也得到了提高,常温下QF/PSA的冲击强度较未改性时提升了20.4%.
参考文献
[1] | Zhang, J.;Huang, J.;Du, W.;Huang, F.;Du, L..Thermal stability of the copolymers of silicon-containing arylacetylene resin and acetylene-functional benzoxazine[J].Polymer Degradation and Stability,201112(12):2276-2283. |
[2] | Zhen-yu Jiang;Yan Zhou;Fa-rong Huang;Lei Du.CHARACTERIZATION OF A MODIFIED SILICON-CONTAINING ARYLACETYLENE RESIN WITH POSS FUNCTIONALITY[J].高分子科学(英文版),2011(06):726-731. |
[3] | 严浩;齐会民;黄发荣.新颖含硅芳基多炔树脂的合成与性能[J].石油化工,2004(9):880-884. |
[4] | 郑锡涛;陈浩远;李泽江;李光亮.先进复合材料在未来飞行器中的应用[J].航空工程进展,2011(2):181-187. |
[5] | 高金淼;齐会民;张健;黄发荣;杜磊.新型含硅芳炔树脂及其复合材料的性能[J].化工新型材料,2008(12):45-47,56. |
[6] | 汤乐旻;周燕;田鑫;邓诗峰;沈学宁;黄发荣;杜磊.改性含硅芳炔树脂及其复合材料性能研究[J].玻璃钢/复合材料,2012(6):41-46. |
[7] | Bin Li;Hongyan Mou;Youming Li.Synthesis and Thermal Decomposition Behavior of Zircoaluminate Coupling Agents[J].Industrial & Engineering Chemistry Research,201334(34):11980-11987. |
[8] | Kemal, I.;Whittle, A.;Burford, R.;Vodenitcharova, T.;Hoffman, M..Toughening of unmodified polyvinylchloride through the addition of nanoparticulate calcium carbonate and titanate coupling agent[J].Journal of Applied Polymer Science,20133(3):2339-2353. |
[9] | Shadpour Mallakpour;Mohammad Zarei.Novel, thermally stable and chiral poly(amide-imide)s derived from a new diamine containing pyridine ring and various amino acid-based diacids: Fabrication and characterization[J].High performance polymers,20133(3):245-253. |
[10] | 王林靖;扈艳红;杜磊;杨海荟.乙炔基芳酰胺酸硅烷改进石英纤维/含硅芳炔复合材料高温界面性能[J].复合材料学报,2016(2):287-296. |
[11] | 葛宇;扈艳红;杜磊.含端炔硅烷偶联剂处理石英纤维对透波用QF/PSA复合材料界面影响[J].功能材料,2014(20):20078-20084. |
[12] | Hsiao SH.;Chu KY.;Yang CP..SYNTHESIS AND PROPERTIES OF POLY(ETHER IMIDE)S HAVING ORTHO-LINKED AROMATIC UNITS IN THE MAIN CHAIN[J].Macromolecules,19972(2):165-170. |
[13] | Doris W.Y. Wong;Lin Lin;P.Terry McGrail.Improved fracture toughness of carbon fibre/epoxy composite laminates using dissolvable thermoplastic fibres[J].Composites, Part A. Applied science and manufacturing,20106(6):759-767. |
[14] | Behniafar, H;Ghorbani, M.New heat stable and processable poly(amide-ether-imide)s derived from 5-(4-trimellitimidophenoxy)-1-trimellitimido naphthalene and various diamines[J].Polymer Degradation and Stability,20083(3):608-617. |
[15] | Luo ZH;Wei LH;Liu F;Zhao T.Study on thermal cure and heat-resistant properties of Nl-(3-acetylenephenyl)maleimide monomer[J].European Polymer Journal,20078(8):3461-3470. |
[16] | 齐会民;王春兰;高金淼;黄发荣;杜磊.RTM用含硅芳炔树脂的流变特性与固化反应动力学[J].玻璃钢/复合材料,2009(6):62-66. |
[17] | 向毅斌;陈敦军;吴诗惇.材料界面增韧的力学机理及其强韧化设计[J].材料工程,2000(7):10-12. |
[18] | Ben W. Kim;John A. Nairn.Observations of Fiber Fracture and Interfacial Debonding Phenomena Using the Fragmentation Test in Single Fiber Composites[J].Journal of Composite Materials,200215(15):1825-1858. |
[19] | Jiang Zhu;Ashraf Imam;Roger Crane;Karen Lozano;Valery N. Khabashesku;Enrique V. Barrera.Processing a glass fiber reinforced vinyl ester composite with nanotube enhancement of interlaminar shear strength[J].Composites science and technology,20077/8(7/8):1509-1517. |
[20] | 陈现景;岳云龙;于晓杰;祝一民.界面改性方法对玻纤增强聚丙烯复合材料力学性能的影响[J].玻璃钢/复合材料,2008(1):14-16. |
[21] | Yanjun Xie;Callum A.S. Hill;Zefang Xiao.Silane coupling agents used for natural fiber/polymer composites: A review[J].Composites, Part A. Applied science and manufacturing,20107(7):806-819. |
[22] | 张玲玲;高飞;周围;张健;黄发荣;杜磊.含硅氢基团甲基芳炔树脂的合成及表征[J].过程工程学报,2009(3):574-579. |
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