Thermoelectric power generation represents a class of energy conversion technology,which has been used in power supply of aeronautic and astronautic exploring missions,now showing notable advantages to harvest the widely distributed waste heat and convert the abundant solar energy into electricity at lower cost than Si-based photovoltaic technology.Thermoelectric dimensionless figure of merit ZT plays a key role in the conversion efficiency from thermal to electrical energy.Low thermal conductivity and large Seebeck coefficient make the AgSbTe2 compound a very promising candidate for high efficiency p-type thermoelectric applications.The AgSbTe2-based thermoelectric system has been repeatedly studied as prospective thermoelectric materials.In this review,we firstly clarify some fundamental tradeoffs dictating the ZT value through the relationship ZT =S2σT/κ.We also pay special attentions to the recent advances in AgSbTe2-based thermoelectric materials.Finally,we provide an outlook of new directions in this filed.
参考文献
[1] | BBC News[OL].http://www.bbc.co.uk/news/business-12745899 |
[2] | Gratzel M .Solar energy conversion by dye-sensitized photovoltaic cells[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2005(20):6841-6851. |
[3] | Bennett G L;Rowe D M.CRC handbook of thermoelectrics[M].Boca Raton:crc Press,1995:515-537. |
[4] | Rowe D M;Bhandari C M.Modern Thermoelectric[M].Reston:Reston Publishing Company Inc,1983 |
[5] | Minnich A J;Dresselhaus M S;Ren Z F et al.Bulk nanostructured thermoelectric materials:current research and future prospects[J].Energy Environ Sci,2009,2:466-479. |
[6] | Pichanusakom P;Bandanu P .Nanostructured thermoelectrics[J].Materials Science and Engineering Report,2010,67:19-25. |
[7] | Ali Shakouri.Recent Developments in Semiconductor Thermoelectric Physics and Materials[J].Annual review of materials research,2011:399-431. |
[8] | Medlin D L;Snyder G J .Interfaces in bulk thermoelectric materials[J].Current Opinion in Colloid and Interface Science,2009,14:226-231. |
[9] | Lan Y C;Minnich A J;Chen G et al.Enhancement of thermoelectric figure-of-merit by a bulk nanostructure approach[J].Advanced Functional Materials,2010,20:357. |
[10] | Li J F;Liu W S;Chen L D et al.High-performance nanostructured thermoelectric materials[J].NPG Asia Materials,2010,2:152-157. |
[11] | Vineis C J;Shakouri A;Majumdar A et al.Nanostructured thermoelectrics:big efficiency gains from small features[J].Advanced Materials,2010,22:3970-3977. |
[12] | Wan C L;Wang Y F;Wang N et al.Development of novel thermoelectric materials by reduction of lattice thermal conductivity[J].Science and Technology of Advanced Materials,2010,11:044306. |
[13] | Kleinke H .New bulk materials for thermoelectric power generation:clathrates and complex antimonides[J].Chemistry of Materials,2010,22:604-610. |
[14] | Eric S. Toberer;Andrew F. May;G. Jeffrey Snyder .Zintl Chemistry for Designing High Efficiency Thermoelectric Materials[J].Chemistry of Materials: A Publication of the American Chemistry Society,2010(3):624-634. |
[15] | Mercouri G. Kanatzidis .Nanostructured Thermoelectrics: The New Paradigm?[J].Chemistry of Materials: A Publication of the American Chemistry Society,2010(3):648-659. |
[16] | Ohta H;Sugiura K;Koumoto K .Recent progress in oxide thermoelectric materials: p-type Ca3CO4O9 and n-type SrTiO3-[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2008(19):8429-8436. |
[17] | Sootsman J R;Chung D Y;Kanatzidis M G .New and old concepts in thermoelectric materials[J].Angewandte Chemie International Edition,2009,48:8616. |
[18] | Li L F;Chen Z;Zhou M et al.[J].Front Energy,2011,5:125-129. |
[19] | Bubnova O;Khan Z U;Malti A et al.Optimization of the thermoelectric figure of merit in the conducting polymer poly(3,4-ethylenedioxythiophene)[J].Nature Materials,2011,10:429-431. |
[20] | Wernick J H;Benson K E .New semiconducting temary compounds[J].Journal of Physics and Chemistry of Solids,1957,3:157. |
[21] | Geller S;Wernick J H .Ternary semiconducting compounds with sodium chloride-like structure:AgSbSe2,AgSbTe2,AgBiS2,AgBiSe2[J].Acta Crystallographica,1959,46:132-138. |
[22] | Quarez, E;Hsu, KF;Pcionek, R;Frangis, N;Polychroniadis, EK;Kanatzidis, MG .Nanostructuring, compositional fluctuations, and atomic ordering in the thermoelectric materials AgPbmSbTe2+m. The myth of solid solutions[J].Journal of the American Chemical Society,2005(25):9177-9190. |
[23] | Geller S;Wernick J H .Ternary semiconducting compounds with sodium chloride-like structure:AgSbSe2,AgSbTe2,AgBiS2,AgBiSe2[J].Acta Crystallographica,1959,46:427-431. |
[24] | Wojciechowski K;Tobola J;Schmidt M;Zybala R .Crystal structure, electronic and transport properties of AgSbSe2 and AgSbTe2[J].The journal of physics and chemistry of solids,2008(11):2748-2755. |
[25] | Hoang K;Mahanti SD;Salvador JR;Kanatzidis MG .Atomic ordering and gap formation in Ag-Sb-based ternary chalcogenides[J].Physical review letters,2007(15):166403-1-166403-4-0. |
[26] | Irie T;Takahama T;Ono T .The thermoelectric properties of AgSbTe2-AgBiTe2,AgSbTe2-PbTe and-SnTe systems[J].Japanese Journal of Applied Physics,1963,2:72-82. |
[27] | Wolfe R;Wemick J H;Haszko S E .Anomalous hall effect in AgSbTe2[J].Journal of Applied Physics,1960,3:1959-1964. |
[28] | Berri, S.;Maouche, D.;Medkour, Y. .Ab initio study of the structural, electronic and elastic properties of AgSbTe _2, AgSbSe _2, Pr _3AlC, Ce _3AlC, Ce _3AlN, La _3AlC and La _3AlN compounds[J].Physica, B. Condensed Matter,2012(17):3320-3327. |
[29] | Wojciechowski K;Tobola J;Schmidt M;Zybala R .Crystal structure, electronic and transport properties of AgSbSe2 and AgSbTe2[J].The journal of physics and chemistry of solids,2008(11):2748-2755. |
[30] | Zayed HA.;Soliman LI.;Ibrahim AM. .OPTICAL ABSORPTION BEHAVIOUR OF AGSBTE2 THIN FILMS[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,1996(1):49-51. |
[31] | Morelli D T;Jovovic V;Heremans J P .Intrinsically minimal thermal conductivity in cubic Ⅰ-Ⅴ-Ⅵ2.semiconductors[J].Physical Review Letters,2008,101:035901. |
[32] | Xu J J;Li H;Du B L Du et al.[J].Journal of Materials Chemistry,2010,20:6138. |
[33] | Wang H;Li J F;Zou M M et al.Synthesis and transport property of AgSbTe2 as a promising thermoelectric compound[J].Applied Physics Letters,2008,93:202106. |
[34] | Wood C .Materials for thermoelectric energy conversion[J].Reports on Progress in Physics,1988,51:459-464. |
[35] | Hsu K F;Loo S;Guo F et al.Cubic AgPbmSbTe2+m:Bulk thermoelectric materials with high figure of merit[J].Science,2004,303:818-825. |
[36] | Androulakis J;Hsu KF;Pcionek R;Kong H;Uher C;DAngelo JJ;Downey A;Hogan T;Kanatzidis MG .Nanostructuring and high thermoelectric efficiency in p-type Ag(Pb1-ySny)(m)SbTe2+m[J].Advanced Materials,2006(9):1170-1173. |
[37] | Androulakis J;Pcionek R;Quarez E et al.Coexistence of large thermopower and degenerate doping in the nanostructured material Ag0.85SnSb1.15Te3[J].Chemistry of Materials,2006,18:4719-4725. |
[38] | Jiaqing Xu;Bo Liu;Zhitang Song .Crystallization and C-RAM application of Ag-doped Sb_2Te_3 material[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2006(2/3):228-232. |
[39] | Feinleib J;Neufville de J;Moss SC et al.Rapid reversible light-induced crystallization of amorphous semiconductors[J].Applied Physics Letters,1971,18:254-260. |
[40] | Identification of Te alloys with suitable phase change characteristics[J].Applied physics letters,2003(13):2572-2574. |
[41] | Wojciechowski K;Tobola J;Schmidt M;Zybala R .Crystal structure, electronic and transport properties of AgSbSe2 and AgSbTe2[J].The journal of physics and chemistry of solids,2008(11):2748-2755. |
[42] | Geller S;Hwernick J .Ternary semiconducting compounds with sodium chloride-like structure:AgSbSe2,AgSbTe2,AgBiS2,AgBiSe2[J].Acta Crystallographica,1959,12:46-51. |
[43] | Zayed HA.;Soliman LI.;Ibrahim AM. .OPTICAL ABSORPTION BEHAVIOUR OF AGSBTE2 THIN FILMS[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,1996(1):49-51. |
[44] | Wolfe R;Wernick J H;Haszko E .Anomalous hall effect in AgSbTe2[J].Journal of Applied Physics,1960,31:1959-1964. |
[45] | Wernick J H .New semiconducting ternary compounds[J].Phys Soc,1957,21:33-37. |
[46] | Zhang S N;Jiang G Y;Zhu T J et al.Doping effect on thermoelectric properties of norstoichiometricAgSbTe2 compounds[J].International Journal of Minerals Metallurgy and Materials,2011,18:352-357. |
[47] | Rosi F D;Hockings E F;Lindenblad N E .Semiconducting materials for thermoelectric power generation[J].RCA Review,1961,22:82. |
[48] | Wernick J H;Benson K E .New semiconducting ternary compounds[J].Journal of Physics and Chemistry of Solids,1957,3:157. |
[49] | Armstrong R W;Faust Jr J W;Tiller W A .A structural study of the compound AgSbTe2[J].Journal of Applied Physics,1960,31:1954. |
[50] | Wolfe R;Wernick J H;Haszko S E .Anomalous hall effect in AgSbTe2[J].Journal of Applied Physics,1960,31:1959-1964. |
[51] | Ye LH;Hoang K;Freeman AJ;Mahanti SD;He J;Tritt TM;Kanatzidis MG .First-principles study of the electronic, optical, and lattice vibrational properties of AgSbTe2[J].Physical review, B. Condensed matter and materials physics,2008(24):245203-1-245203-6-0. |
[52] | Hoang K;Mahanti SD;Salvador JR;Kanatzidis MG .Atomic ordering and gap formation in Ag-Sb-based ternary chalcogenides[J].Physical review letters,2007(15):166403-1-166403-4-0. |
[53] | Hoang K .Atomic and electronic structures of novel ternary and quaternary narrow gand-gap semiconductors[D].Michigan State University,2007. |
[54] | Jovovic, V;Heremans, JP .Measurements of the energy band gap and valence band structure of AgSbTe2[J].Physical review. B, Condensed Matter And Materials Physics,2008(24):245204-1-245204-8-0. |
[55] | V. JOVOVIC;J.P. HEREMANS .Doping Effects on the Thermoelectric Properties of AgSbTe_(2)[J].Journal of Electronic Materials,2009(7):1504-1509. |
[56] | Arachchige I U;Wu J S;Dravid V P et al.Nanocrystals of the quaternary thermoelectric materials AgPbmSbTem+2 (m=l-18)phase segregated or solid solutions[J].Advanced Materials,2008,20:3638. |
[57] | Wu L J;Zheng J C;Zhou J et al.Nanostructures and defects in thermoelectric AgPb1sSbTe20 single crystal[J].Journal of Applied Physics,2009,105:094317. |
[58] | Gueguen A;Poudeu P F P;Li C P et al.Thermoelectric properties and nanostructuring in the p-type materials NaPb18-xSnxMTe (M=Sb,Bi)[J].Chemistry of Materials,2009,21:1683-1687. |
[59] | Yang SH;Zhu TJ;Sun T;Zhang SN;Zhao XB;He J .Nanostructures in high-performance (GeTe)(x)(AgSbTe2)(100-x) thermoelectric materials[J].Nanotechnology,2008(24):245707-1-245707-5-0. |
[60] | Hsu K F;Loo S;Guo F et al.Cubic AgPbmSbTe2+m:bulk thermoelectric materials with high figure of merit[J].Science,2004,303:818. |
[61] | Skrabek E A;Trimmer D S.Properties of the general TAGS system[A].Boca Raton:crc Press,1995 |
[62] | Morelli D T;Jovovic V;Heremans J P .Intrinsically minimal thermal conductivity in cubic Ⅰ-Ⅴ-Ⅵ2 semiconductors[J].Physical Review Letters,2008,101:035901. |
[63] | Jovovic, V;Heremans, JP .Measurements of the energy band gap and valence band structure of AgSbTe2[J].Physical review. B, Condensed Matter And Materials Physics,2008(24):245204-1-245204-8-0. |
[64] | Ye LH;Hoang K;Freeman AJ;Mahanti SD;He J;Tritt TM;Kanatzidis MG .First-principles study of the electronic, optical, and lattice vibrational properties of AgSbTe2[J].Physical review, B. Condensed matter and materials physics,2008(24):245203-1-245203-6-0. |
[65] | Zhang S N;Zhu T J;Yang S H et al.Improved thermoelectric properties of AgSbTe2 based compounds with nanoscale Ag2Te in situ precipitates[J].Journal of Alloys and Compounds,2010,499:215. |
[66] | Sheng-nan Zhang,Guang-yu Jiang,Tie-jun Zhu,Xin-bing Zhao,Sheng-hui Yang.Doping effect on thermoelectric properties of nonstoichiometric AgSbTe2 compounds[J].矿物冶金与材料学报,2011(03):352-356. |
[67] | Du Baoli;Li Han;Xu Jingjing .Enhanced figure-of-merit in Se-doped p-Type AgSbTe2 thermoelectric compound[J].Chemistry of Materials,2010,22:5521-5527. |
[68] | Jovovic, V;Heremans, JP .Measurements of the energy band gap and valence band structure of AgSbTe2[J].Physical review. B, Condensed Matter And Materials Physics,2008(24):245204-1-245204-8-0. |
[69] | Sugar J D;Medlin D L .Precipitation of Ag2Te in the thermoelectric material AgSbTe2[J].Journal of Alloys and Compounds,2009,478:75. |
[70] | Zhang S N;Zhu T J;Yang S H et al.Phase composition,nanoscale microstructures and thermoelectric properties in Ag2-ySbyTe1+y alloys with precipitated Sb2Te3 plates[J].Acta Materialia,2010,58(12):4160. |
[71] | Hsu K F;Loo S;Guo F et al.Cubic AgPbmSbTe2+m:bulk thermoelectric materials with high figure of merit[J].Science,2004,303:818. |
[72] | Chen N;Gascoin F;Snyder GJ;Muller E;Karpinski G;Stiewe C .Macroscopic thermoelectric inhomogeneities in (AgSbTe2)(x)(PbTe)(1-x)[J].Applied physics letters,2005(17):1903-1-1903-3-0. |
[73] | Kosuga A;Uno M;Kurosaki K et al.Thermoelectric properties of AgPbmSbTem+2 (12 ≤ m ≤ 26) at elevated[J].Journal of Alloys and Compounds,2005,391:288. |
[74] | Wu H J;Chen S W .Phase equilibria and solidification of ternary Sn-Bi-Ag alloys[J].Journal of Alloys and Compounds,2011,509:656. |
[75] | Wernick J H;Benson K E .New semiconducting ternary compounds[J].Journal of Physics and Chemistry of Solids,1957,3:157. |
[76] | Armstrong R W;Faust Jr J W;Tiller W A .A structural study of the compound AgSbTe2[J].Journal of Applied Physics,1960,31:1954. |
[77] | McHugh J P;Tiller W A;Haszko S E .[J].Journal of Applied Physics,1961,32:1785. |
[78] | Offergeld G;Gilles J M;Hatwell H et al.[J].Academic Science,1961,22:3788. |
[79] | Burmeister R A;Stevenson D A .[J].Transactions TMS-AIME,1964,230:329. |
[80] | Marin R M;Brun G;Tedenac J C .[J].Journal of Materials Science,1985,20:730. |
[81] | Ayralmarin R M;Brun G;Maurin M .[J].European Journal of Solid State and Inorganic Chemistry,1990,27:747. |
[82] | Vineis C J;Shakouri A;Majumdar A .Nanostrctured thermoelectrics:big efficiency gains from small features[J].Advanced Materials,2010,22:3970. |
[83] | Enhancement of Thermoelectric Figure-of-Merit by a Bulk Nanostructuring Approach[J].Advanced functional materials,2010(3):357. |
[84] | Ji X;Zhang B;Tritt T M et al.Solution-chemical syntheses of nano-structured Bi2Te3 and PbTe thermoelectric materials[J].Journal of Electronic Materials,2007,36:721. |
[85] | Ikeda T;Ravi V A;Collins L A et al.Development and evolution of nanostructure in thermoelectric Pb-Te-Sb alloys[J].Journal of Electronic Materials,2007,36:716. |
[86] | K.X. Zhang;X.Y. Qin;H.X. Xin .Transport and thermoelectric properties of nanocrystal substitutional semiconductor alloys (Mg_(1-x)Cd_x)_3Sb_2 doped with Ag[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2009(1/2):498-504. |
[87] | Cui J;Liu X;Yang W et al.[J].Journal of Applied Physics,2009,105:063703. |
[88] | Savary, E.;Gascoin, F.;Marinel, S. .Fast synthesis of nanocrystalline Mg_2Si by microwave heating: A new route to nano-structured thermoelectric materials[J].Dalton transactions: An international journal of inorganic chemistry,2010(45):11074-11080. |
[89] | Ren, W.;Cheng, C.;Ren, Z.;Zhong, Y. .The effect of the precursor nanopowder size on the thermoelectric properties of nanostructured BiSbTe bulk materials[J].Physica, B. Condensed Matter,2010(24):4931-4936. |
[90] | Quarez, E;Hsu, KF;Pcionek, R;Frangis, N;Polychroniadis, EK;Kanatzidis, MG .Nanostructuring, compositional fluctuations, and atomic ordering in the thermoelectric materials AgPbmSbTe2+m. The myth of solid solutions[J].Journal of the American Chemical Society,2005(25):9177-9190. |
[91] | Han Mi-Kyung;Androulakis John;Kim Sung-Jin et al.Lead-free thermoelectrics:high figure of merit inp-type AgSnmSbTem+2[J].Adv Energy Mater,2012,2:157-161. |
[92] | Du, B.;Li, H.;Xu, J.;Tang, X.;Uher, C. .Enhanced thermoelectric performance and novel nanopores in AgSbTe _2 prepared by melt spinning[J].Journal of Solid State Chemistry,2011(1):109-114. |
[93] | Lakshminarayana D;Desal R R .Thickness dependence of electrical resistivity and activation energy in AgSbTe2 thin films[J].Journal of Materials Science:Materials in Electronics,1993,4(02):183-186. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%