欢迎登录材料期刊网

材料期刊网

高级检索

利用碳吸附沉淀法合成Y2O3纳米粉体.采用TG-DTA、XRD、TEM、BET、UV-Vis和粒度分析等测试方法分别对粉体进行了表征.结果表明,750℃下焙烧的Y2O3粉体具有良好的分散状态,晶粒度为16.7 nm,颗粒范围为34~45 nm,比表面积为75.7 m2/g.与氨水直接沉淀制得的Y2O3粉体相比,碳吸附沉淀法制备的Y2O3粉体在紫外光下有良好的光催化活性,80 min内对甲基橙的降解率达78%.

参考文献

[1] D.V.Kozlov;A.V.Vorontsov;E.N.Savinov;P.G.Smirniotis .Gas-phase photocatalytic oxidation of diethyl sulfide over TiO_2: kinetic investigations and catalyst deactivation[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(1):77-87.
[2] Habibi MH;Vosooghian H .Photocatalytic degradation of some organic sulfides as environmental pollutants using titanium dioxide suspension[J].Journal of Photochemistry and Photobiology, A. Chemistry,2005(1):45-52.
[3] Bamwenda GR.;Arakawa H. .Cerium dioxide as a photocatalyst for water decomposition to O-2 in the presence of Ce-aq(4+) and Fe-aq(3+) species[J].Journal of molecular catalysis, A. Chemical,2000(1/2):105-113.
[4] Juan C;Maira J;Arturo M et al.EPR Study of the Radicals Formed upon UV Irradiation of Ceria-based Photocatalystsy[J].Journal of Photochemistry and Photobiology A:Chemistr,2002,150:213.
[5] Maria D.Hernandez-Alonso;Ana Belen Hungria;Arturo Martinez-Arias .EPR study of the photoassisted formation of radicals on CeO_2 nanoparticles employed for toluene photooxidation[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2004(3):167-175.
[6] Nan Li;Kazumichi Yanagisawa .Controlling the Morphology of Yttrium Oxide through Different Precursors Synthesized by Hydrothermal Method[J].Journal of Solid State Chemistry,2008,181:1738.
[7] L.F. Mei;G.Y. Chen;B. Zhang;G.G. Chen;K. Huang .Measurement of YAG laser absorptance by artificial diamond and cubic boron nitride[J].Optics & Laser Technology,2009(6):770-777.
[8] Richardson K;Akinc M .Preparation of Spherical Yttrium Oxide Powders Using Emulsion Vaporation[J].Ceramics International,1987,13:253.
[9] Young Kwan Kim;Ho Kyung Kim;Do Kyung Kim .Synthesis of Eu-doped (Gd,Y)_2O_3 transparent optical ceramic scintillator[J].Journal of Materials Research,2004(2):413-416.
[10] 孙巧珍,邵鑫,赵利民,尹贻彬,刘凤珍,李文智.水热微乳液法合成氧化钇粉体前驱体[J].聊城大学学报(自然科学版),2010(03):50-54.
[11] 刘志强,李杏英,梁振锋.碳铵沉淀法制备纳米氧化钇过程中氯离子的行为[J].中国稀土学报,2005(03):373-377.
[12] Saito N.;Ikegami T.;Matsuda S. .Fabrication of transparent yttria ceramics at low temperature using carbonate-derived powder[J].Journal of the American Ceramic Society,1998(8):2023-2028.
[13] Li Ling.Synthesis of Y2O3 Nano-Powder from Yttrium Oxalate under Ambient Temperature[J].稀土学报(英文版),2005(03):358-361.
[14] 闻雷,孙旭东.碳酸盐前驱物制备Y2O3超细粉及透明陶瓷[J].中国稀土学报,2003(02):166-169.
[15] 袁文俊,周勇敏.纳米颗粒团聚的原因及解决措施[J].材料导报,2008(z3):59-61.
[16] Ramasamy Srinivasan;Rajeswari Yogamalar;Arumugam Chandra Bose .Structural and optical studies of yttrium oxide nanoparticles synthesized by co-precipitation method[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2010(9):1165-1170.
[17] Kubo R .Electronic Properties of Metallic Fine Particles[J].Journal of the Physical Society of Japan,1962,17:975-986.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%