欢迎登录材料期刊网

材料期刊网

高级检索

以柠檬酸三钠为晶形控制剂,采用简单沉淀法合成了绒毛球状SrCO3晶体.用扫描电子显微镜(SEM)、X射线衍射仪(XRD)、傅里叶红外光谱仪(FTIR)、热重分析仪(TG)、透射电镜(TEM)和能谱仪(EDX)等对样品的结构和形貌进行了表征.结果表明,绒毛球状SrCO3的主体结构为微米级实心球,实心球壳表面被一层稠密的粒径为5~15 nm、长度为100 ~ 150 nm的毛发状晶体所覆盖;机理分析认为绒毛球状SrCO3的形成可以用“棒状-束状-哑铃形-球形”的生长机理(RBDS)进行解释.

参考文献

[1] Homeijer, SJ;Barrett, RA;Gower, LB .Polymer-Induced Liquid-Precursor (PILP) Process in the Non-Calcium Based Systems of Barium and Strontium Carbonate[J].Crystal growth & design,2010(3):1040-1052.
[2] Jin T X .Strontium Carbonate Industry Needs Urgent Upgrade[J].China Chemical Reporter,2007,1:16.
[3] 康明,燕文清,刘军,刘君玉,孙蓉,宋丽贤,宋开平.碳酸锶基绿色荧光粉的制备及其发光性能[J].四川大学学报:工程科学版,2011(05):209-212,223.
[4] You C;Zhang Q;Zhao Y et al.Surfactants Controlled Morphosynthesis of Strontium Carbonate[J].Current Advances in Materials and Processes,2011,194:683-688.
[5] Yu HG;Guo H;Cheng B .Shape evolution of SrCO3 particles in the presence of poly-(styrene-alt-maleic acid)[J].International Journal of Quantum Chemistry,2006(3):800-803.
[6] Guolong Guo;Guowei Yan;Lina Wang;Jianhua Huang .Crystallization of strontium carbonate in alcohol or water solution containing mixed nonionic/anionic surfactants[J].Materials Letters,2008(24):4018-4021.
[7] Wang L;Zhu Y F .Effects of Nanostructure on Catalytic Degradation of Ethanol on SrCO3 Catalysts[J].Journal of Physical Chemistry B,2005,109:5118-5123.
[8] Chen L;Shen YH;Xie AJ;Huang FZ;Li SK;Zhang QF .Synthesis of rhombohedral strontium carbonate aggregates at the water/hexamethylene interface with cetyltrimethylammonium bromide[J].Crystal Research and Technology: Journal of Experimental and Industrial Crystallography,2008(8):797-800.
[9] Wang WS;Zhen L;Xu CY;Yang L;Shao WZ .Room temperature synthesis of hierarchical SrCO3 Architectures by a surfactant-free aqueous solution route[J].Crystal growth & design,2008(5):1734-1740.
[10] ZHAGN Ming-Xuan,HUO Ji-Chuan,YU Yong-Sheng,CUI Cai-Ping,LEI Yong-Lin.Morphology Control of SrCO3 Crystals using Complexons as Modifiers in the Ethanol-water mixtures[J].结构化学,2008(10):1223-1229.
[11] qing Huang;Lian Gao;Fritz Aldinger .Synthesis and Characterization of Strontium carbonate nanowires with a Axis orientation and Dendritic nanocrystals[J].Chemistry Letters,2004(3):290-291.
[12] Zhu, W.;Zhang, G.;Liu, C.;Zhang, Q.;Zhu, S. .Hierarchical strontium carbonate submicron spheres self-assembled under hydrothermal conditions[J].Crystal Research and Technology: Journal of Experimental and Industrial Crystallography,2010(8):845-850.
[13] Jun Yang;Xiaoming Liu;Chunxia Li;Zewei Quan;Deyan Kong;Jun Lin .Hydrothermal synthesis of SrCO3:Eu3+/Tb3+ microneedles and their luminescence properties[J].Journal of Crystal Growth,2007(2):480-486.
[14] Liange Shi;Fanglin Du .Solvothermal synthesis of fusiform hexagonal prism SrCO_3 microrods via ethylene glycol solution[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2007(8):1550-1555.
[15] Cao MH;Wu XL;He XY;Hu CW .Microemulsion-mediated solvothermal synthesis of SrCO3 nanostructures[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(13):6093-6096.
[16] Murat Erdemoglu;Salih Aydogan;Mehmet Canbazoglu .A kinetic study on the conversion of celestite (SrSO_4) to SrCO_3 by mechanochemical processing[J].Hydrometallurgy,2007(1/2):1-5.
[17] Mohammad Amin Alavi;Ali Morsali .Syntheses and characterization of Sr(OH)2 and SrCO3 nanostructures by ultrasonic method[J].Ultrasonics sonochemistry,2010(1):132-138.
[18] Debabrata Rautaray;Ambarish Sanyal;Suguna D.Adyanthaya;Absar Ahmad;Murali Sastry .Biological Synthesis of Strontium Carbonate Crystals Using the Fungus Fusarium oxysporum[J].Langmuir: The ACS Journal of Surfaces and Colloids,2004(16):6827-6833.
[19] 陈先勇,唐琴,胡卫兵,但悠梦,周贵云.孪生球状碳酸钙的直接混合沉淀法制备及表征[J].高等学校化学学报,2010(10):1940-1944.
[20] 陈先勇;唐琴;胡卫兵 等.西兰花状碳酸钙的制备及表征[J].硅酸盐学报,2010,38(10):57-62.
[21] Du, JM;Liu, ZM;Li, ZH;Han, BX;Huang, Y;Zhang, JL .Synthesis of mesoporous SrCO3 spheres and hollow CaCO3 spheres in room-temperature ionic liquid[J].Microporous and Mesoporous Materials,2005(1/3):145-149.
[22] 张明轩,霍冀川,王海滨,刘树信,雷永林,崔彩萍.CTAB与SDBS对碳酸锶粒子生长形态调控及机理研究[J].人工晶体学报,2007(05):1136-1141.
[23] Wu, SS;Cao, HQ;Yin, SF;Zhang, XR;Chernow, V .Biomineralization and Superhydrophobicity of BaCO3 Complex Nanostructures[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2009(21):10326-10329.
[24] Li, W.;Sun, S.;Yu, Q.;Wu, P. .Controlling the morphology of BaCO_3 aggregates by carboxymethyl cellulose through polymer induced needle-stacking self-assembly[J].Crystal growth & design,2010(6):2685-2692.
[25] Shu-Hong Yu;Helmut Colfen;An-Wu Xu;Wenfei Dong .Complex Spherical BaCO_3 Superstructures Self-Assembled by a Facile Mineralization Process under Control of Simple Polyelectrolytes[J].Crystal growth & design,2004(1):33-37.
[26] 雷永林,霍冀川,张明轩.软模板调控碳酸锶结晶特性的研究[J].人工晶体学报,2007(01):205-209.
[27] 孟令镕,彭卿,周和平,李亚栋.从纳米晶到三维超晶格结构[J].高等学校化学学报,2011(03):429-436.
[28] 蒋锡华,郑明波,陈惠钦,潘力佳,陶杰,曹洁明.PAM溶液中合成核/壳结构花生状碳酸钙粒子[J].无机材料学报,2008(06):1283-1286.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%