过去十几年国内外对镁基储氢材料的催化剂研究表明,使用催化剂能够有效改善材料的表面特性,提高材料的吸放氢动力学性能.目前常用的催化剂体系有过渡族金属、金属氧化物、金属卤化物、金属间化合物以及碳素非金属.通过比较发现,不同种类的催化剂催化效果不同,相应的催化机理也有所差异.目前,国外研究者已发现几种催化剂共同催化的效果显著,国内应加强金属间化合物和碳素材料催化荆以及不同催化剂共同作用方面的研究.
参考文献
| [1] | 胡子龙.贮氢材料[M].北京:化学工业出版社,2002 |
| [2] | Liang G;Huot J;Boily S et al.Catalytic effect of transition metals on hydrogen sorption in nanocrystalline ball milled MgH《,2》-Tm(Tm=Ti,V,Mn,Fe and Ni) systems[J].Journal of Alloys and Compounds,1999,292:247. |
| [3] | Abdellaoui M;Cracco D;Percheron-Guegan A .Structural study and hydrogen sorption kinetics of hall-milled magnesium hydride[J].Journal of Alloys and Compounds,1999,293-295:495. |
| [4] | Terashita N;Takahashi M;Kohayashi K et al.Synthesis and hydriding/dehydriding properties of amorphous Mg《,2》Ni《,1.9》-M《,0.1》 alloys mechanically alloyed from Mg《,2》 Ni《,1.9》 M《,0.1》(M =none,Ni,Ca,La,Y,Al,Si,Cu and Mn) and Ni powder[J].Journal of Alloys and Compounds,1999,293-295:541. |
| [5] | Klyamkin S N .Metal hydride compositions on the basis of magnesium as materials for hydrogen accumulation[J].Russian Journal of General Chemistry,2007,77:712. |
| [6] | Chiaki Iwakura;Ryuji Shin-ya;Keisuke Miyanohara;Shinji Nohara;Hiroshi Inoue .Effects of Ti-V substitution on electrochemical and structural characteristics of MgNi alloy prepared by mechanical alloying[J].Electrochimica Acta,2001(18):2781-2786. |
| [7] | Orimo S;Fujii H .Material science of Mg-Ni-based new hydrides[J].Applied Physics A:Materials Science and Processing,2001,72:167. |
| [8] | Wang Lianbang;Tang Yuanhua;Wang Yijing et al.The hydrogenation properties of Mg《,1.8》 Ag《,0.2》 Ni alloy[J].Journal of Alloys and Compounds,2002,336(1-2):297. |
| [9] | Hee Yong Lee;Nam Hoon Goo .The surface state of nanocrystalline and amorphous Mg_2Ni alloys prepared by mechanical alloying[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):258-262. |
| [10] | Huot J;Pelletier J F;Liang G et al.Structure of nanocomposite metal hydrides[J].Journal of Alloys and Compounds,2002,330-332:727. |
| [11] | Lenain C;Dupont L;Tarascon JM;Aymard L .A New Mg sub 0.9 Y sub 0.1 Ni hydride forming composition obtained by mechanical grinding[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(1/2):84-89. |
| [12] | 张耀,田琦峰,褚海亮,孙立贤,徐芬,张涛.Mg基非晶合金及La-Mg-Ni基复合物储氢电极的结构与电化学性能[J].合成化学,2007(z1):165-177. |
| [13] | 张庆安,赵刚,斯庭智,庞刚.Ca3-xMg2+xNi13合金的储氢性能[J].中国材料进展,2009(05):17-21. |
| [14] | 陈玉安,唐体春,傅洁,潘复生,邓世平,李家鸣,赵光明.Al的添加对Mg2Ni合金储氢性能的影响[J].材料导报,2007(z2):194-195,207. |
| [15] | 张羊换,李保卫,任慧平,郭世海,祁焱,王新林.纳米晶和非晶Mg20-xLaxNi10（x=0-6）贮氢合金的贮氢行为[J].稀有金属材料与工程,2010(08):1317-1322. |
| [16] | Barkhoudarian G;Klassen T;Bormann R .Effect of Nb《,2》O《,5》 content on hydrogen reaction kinetics of Mg[J].Journal of Alloys and Compounds,2004,364:242. |
| [17] | Barkhordarian G;Klassen T;Bormann R .Effect of Nb《,2》O《,5》content on hydrogen reaction kinetics of Mg[J].Journal of Alloys and Compounds,2004,364:242. |
| [18] | Friedrichs O;Klassen T;Sanchez-Lopez J C et al.Hydrogen sorption improvement of nanocrystalline MgH《,2》 by Nb《,2》 O《,5》 nanoparticals[J].Scripta Materialia,2006,54:1293. |
| [19] | Friedrichs O;Sanchez-Lopez J C;Cartes-Lopez C et al.Nb《,2》O《,5》"pathway effect" on hydrogen sorption in Mg[J].Journal of Physical Chemistry B,2006,110(15):7845. |
| [20] | Khrussanova M;Terzieva M;Peshey P.Hydriding of mechanically alloyed mixtures of magnesium with MnO《,2》,Fe《,2》 O《,3》 and NiO[J].Materials Research Bulletin,1991(26):561. |
| [21] | Ik-Hyun Kwon;Jean-Louis Bobet;Jong-soo Bee et al.Improvement of hydrogen storage properties of Mg by reactive mechanical grinding with Fe《,2》 O《,3》[J].Journal of Alloys and Compounds,2005,396(1-2):264. |
| [22] | Myoung-Youp Song;Seong-Hyeon Hong;Ik-Hyun Kwon .Improvement of hydrogen-storage properties of Mg by reactive mechanical grinding with Fe_2O_3 prepared by spray conversion[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2005(1/2):283-288. |
| [23] | Myoung Youp Song;IkHyun Kwon;SungNam Kwon;ChanGi Park;HyeRyoung Park;Jong-Soo Bae .Preparation of hydrogen-storage alloy Mg-10 wt% Fe_2O_3 under various milling conditions[J].International journal of hydrogen energy,2006(1):43-47. |
| [24] | Oelerich W;Klassen T;Bormann R .Comparison of the catalytic effects of V,V《,2》O《,5》,VN and VC on the hydrogen sorption of nanocrystalline Mg[J].Journal of Alloys and Compounds,2001,322(1-2):L5. |
| [25] | Bobet J L;Desmoulins-Krawiec S;Grigorova E et al.Addition of nanosized Cr《,2》 O《,3》 to magnesium for improvement of the hydrogen sorption properties[J].Journal of Alloys and Compounds,2003,351(1-2):217. |
| [26] | MyoungYoup Song;Jean-Louis Bobet;Bernard Darriet .Improvement in hydrogen sorption properties of Mg by reactive mechanical grinding with Cr_2O_3, Al_2O_3 and CeO_2[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2002(1/2):256-262. |
| [27] | Klassen T;Oelerich W;Bormann R .Nanocrystalline Mgbased hydrides:Hydrogen storage for the zero-emission vehicle[J].Materials Science Forum,2001,360(03):603. |
| [28] | Croston D L;Grant D M;Walker G S .The catalytic effect of titanium oxide based additives on the dehydrogenation and hydrogenation of milled MgH《,2》[J].Journal of Alloys and Compounds,2010,492(1-2):251. |
| [29] | 朱旭光,董星龙,黄昊,雷军鹏,孙舰鹏.氢等离子体电弧法Mg/TiO2复合纳米粒子的制备与表征[J].纳米技术与精密工程,2008(03):170-173. |
| [30] | Huabin Yang;Hua Sun;Endong Yang .The Corrosion Behavior of Ternary Mg_(2-x)Mm_xNi Alloys[J].Journal of the Electrochemical Society,2002(5):A543-A545. |
| [31] | Florent Tonus;Valeria Fuster;Guillermina Urretavizcaya;Facundo J. Castro;Jean-Louis Bobet .Catalytic effect of monoclinic WO_3, hexagonal WO_3 and H_(0.23)WO_3 on the hydrogen sorption properties of Mg[J].International journal of hydrogen energy,2009(8):3221-3233. |
| [32] | Seon-Ah Jin;Jae-Hyeok Shim;Young Whan Cho;Kyung-Woo Yi .Dehydrogenation and hydrogenation characteristics of MgH_2 with transition metal fluorides[J].Journal of Power Sources,2007(2):859-862. |
| [33] | L. Xie;Y. Liu;Y.T. Wang .Superior hydrogen storage kinetics of MgH_2 nanoparticles doped with TiF_3[J].Acta materialia,2007(13):4585-4591. |
| [34] | Luo Ye;Wang Ping;Ma Laipeng et al.Hydrogen sorption kinetics of MgH《,2》 catalyzed with NbF《,5》[J].Journal of Alloys and Compounds,2008,453(1-2):138. |
| [35] | Fu Y;Groll M;Mertz R et al.Effect of LaNi《,5》 and additional catalysts on hydrogen storage properties of Mg[J].Journal of Alloys and Compounds,2008,460:607. |
| [36] | Molinas B;Ghilarducci A A;Melnichuk M et al.Scaled up production of promising Mg based hydride for hydrogen storage[J].International Journal of Hydrogen Energy,2009,34:4597. |
| [37] | Makihara Y;Umeda K et al.Cooperative dehydriding mechanism in a mechanically milled Mg-50mass% ZrMn《,2》 composite[J].Journal of Alloys and Compounds,2008,455:385. |
| [38] | Vijay R;Sundaresan R;Maiya M P et al.Characterization of Mg-x wt% FeTi(x=5～30) and Mg-40wt% FeTiMn hydrogen absorbing materials prepared by mechanical alloying[J].Journal of Alloys and Compounds,2004,384:283. |
| [39] | Yu X B;Guo Y H;Yang H et al.Improved hydrogen storage in magnesium hydride catalyzed by nanosized Ti《,0.4-》Cr《,0.15》 Mn《,0.15》 V《,0.3》 alloy[J].Journal of Physical Chemistry C,2009,113:5324. |
| [40] | 谢衍生,孙岳明,傅岩,雷立旭.储氢材料的发展概况[J].材料导报,2004(05):76-78. |
| [41] | Imamura H;Takesme Y et al.Hydrogen-absorbing magenesium composites prepared by mechanical grinding with graphite[J].Journal of Alloys and Compounds,1999,293-295:564. |
| [42] | Wu C Z;Wang P;Yao X et al.Effect of carbon/noncarbon addition on hydrogen storage behaviors of magnesium hydride[J].Journal of Alloys and Compounds,2006,414:259. |
| [43] | Wu C Z;Wang P;Yao X et al.Hydrogen storage properties of MgH《,2》/SWNT composite prepared by ball milling[J].Journal of Alloys and Compounds,2006,420:278. |
| [44] | Bouaricha S.;Guay D.;Huot J.;Schulz R.;Dodelet JP. .Activation characteristics of graphite modified hydrogen absorbing materials[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2001(1/2):245-251. |
| [45] | Huang Z G;Guo Z P;Calka A et al.Effect of carbon black,graphite and carbon nanotube additives on hydrogen storage properties of magnesium[J].Journal of Alloys and Compounds,2007,427(1-2):94. |
| [46] | 周仕学,杨敏建,马怀营,张同环,张光伟.微晶碳在镁基复合储氢材料中的作用[J].山东科技大学学报（自然科学版）,2009(05):54-57,80. |
| [47] | YAO XiangDong,LU GaoQing.Magnesium-based materials for hydrogen storage: Recent advances and future perspectives[J].科学通报（英文版）,2008(16):2421-2431. |
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