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2,5-Dihydrazino-1,3,4-thiadiazole was prepared by 2,5-dimecapto-1,3,4-thiadiazole and hydrazine, and then the six novel different 2,5-bis(benzylidenehydrazino)-1,3,4-thiadiazole compounds were obtained by a condensation reaction of 2,5-dihydrazino-1,3,4-thiadiazole with substituted benzaldehyde and structurally confirmed by elemental analysis, IR, H-1 NMR and mass spectra. The result indicates that the six 2,5-bis(benzylidenehydrazino)-1,3,4-thiadiazole compounds are of definite inhibition against silver surface in corrosion jet fuel.

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