高分子材料科学与工程, 2013, 29(4): 1-4.
聚(二乙炔基苯-硅烷-硼烷)树脂的合成及性能
陈明锋 1, , 周权 2, , 倪礼忠 {"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"目前,国内就航空用高强度钢表面电镀锌-镍合金层对氢脆性能的影响研究较少.在30CrMnSiNi2A高强钢表面电镀锌-镍合金层,并对其进行除氢处理.采用X射线荧光光谱仪测量镀层厚度和镀层中的镍含量,采用划线法测试镀层与基体的结合力,通过拉伸试验研究了镀层对基体氢脆性能的影响,通过盐雾试验测试了镀层的耐蚀性能.结果表明:锌-镍合金镀层的防蚀能力达到航空用材防蚀要求;当电镀时间较短、镀层较薄时,电镀过程对基体的氢脆性影响较小;电镀时间较长、镀层较厚(16 μm左右)时,电镀过程中产生的氢会渗入基体并积累,并可导致氢脆,镀后1h内进行除氢,则可有效去除基体中的氢.","authors":[{"authorName":"王亚伟","id":"fca83156-9a0b-4fff-b576-1543c56b381c","originalAuthorName":"王亚伟"},{"authorName":"乔永莲","id":"6970df2c-4fbb-4a83-ba58-d5d30870e47f","originalAuthorName":"乔永莲"},{"authorName":"沙春鹏","id":"32d09172-909c-4ab6-90d0-c5f7168886cc","originalAuthorName":"沙春鹏"},{"authorName":"马超","id":"272ae90b-cd17-4e6f-9655-5c4f3bf4d50c","originalAuthorName":"马超"}],"doi":"","fpage":"61","id":"d40a6052-6cca-4caf-96b7-f7294575a1d4","issue":"12","journal":{"abbrevTitle":"CLBH","coverImgSrc":"journal/img/cover/CLBH.jpg","id":"7","issnPpub":"1001-1560","publisherId":"CLBH","title":"材料保护"},"keywords":[{"id":"3b5039c9-7aad-4fdc-ba7d-79fd9ad7fdaa","keyword":"电镀","originalKeyword":"电镀"},{"id":"6956b483-1a57-4598-b096-e9dc9f18ca65","keyword":"锌-镍合金","originalKeyword":"锌-镍合金"},{"id":"0558943b-b004-4802-9be6-4d172cd3a1db","keyword":"30CrMnSiNi2A高强钢","originalKeyword":"30CrMnSiNi2A高强钢"},{"id":"2a895ac3-6e88-4db8-ab3b-28e789fbc28a","keyword":"氢脆性能","originalKeyword":"氢脆性能"}],"language":"zh","publisherId":"clbh201312019","title":"航空用30CrMnSiNi2A高强钢电镀锌-镍合金层及其对氢脆性能的影响","volume":"46","year":"2013"},{"abstractinfo":"在计算出61个单硫醚的各种量化参数之后,用逐步回归方法,预测了单硫醚在4种极性固定相上的气相色谱保留值,建立了相应的定量模型.结果表明,该模型具有较强的预测能力,回归方程的均方根误差不超过4%. ","authors":[{"authorName":"王亚伟","id":"4d919a70-f767-44ba-88bb-4e1489c5ad3b","originalAuthorName":"王亚伟"},{"authorName":"高玉红","id":"a2603ed9-cf9d-4229-a5df-73c39c6ffd3a","originalAuthorName":"高玉红"},{"authorName":"姚小军","id":"df335c11-16ec-42ce-80ee-c3ff56214595","originalAuthorName":"姚小军"},{"authorName":"刘满仓","id":"95c87a5e-2d3e-46d7-9cc8-e76dede555e1","originalAuthorName":"刘满仓"},{"authorName":"胡之德","id":"191bc95f-626a-4dd0-926e-c91201c48ba1","originalAuthorName":"胡之德"},{"authorName":"范波涛","id":"6b229baf-5270-4937-a2d5-cd596f2c6fe7","originalAuthorName":"范波涛"}],"doi":"10.3321/j.issn:1000-8713.2002.05.008","fpage":"415","id":"d43db0b9-6f27-46f9-95b1-259b347a6a9d","issue":"5","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"fdc4b4e1-ba4d-4014-b5c2-a973f938f023","keyword":"单硫醚","originalKeyword":"单硫醚"},{"id":"90ca7523-46fa-455f-9b29-28535aa66e8b","keyword":"多元线性回归","originalKeyword":"多元线性回归"},{"id":"ae21c516-291f-4bd8-bd39-13a9b44bb7ba","keyword":"定量结构-色谱保留相关","originalKeyword":"定量结构-色谱保留相关"},{"id":"e9d45124-645b-4363-b101-e5e5dca4bfd7","keyword":"保留值","originalKeyword":"保留值"}],"language":"zh","publisherId":"sp200205008","title":"单硫醚在不同极性固定相上的气相色谱保留指数与结构的相关性研究","volume":"20","year":"2002"},{"abstractinfo":"建立了利用高分辨气相色谱-高分辨质谱定量测定多溴联苯醚(PBDEs)的方法,参与了测定PBDEs的国际比对实验,实验结果表明该法是可行的.对不同地区(北京、山东临沂、上海)的3个污水处理厂的活性污泥进行了索氏提取、多层复合硅胶柱分离,然后用所建立的方法测定了19种多溴联苯醚单体的含量.结果表明,北京某污水处理厂的活性污泥中PBDEs的总量高于其他两者.","authors":[{"authorName":"王亚伟","id":"5430a0e7-6b10-428b-886b-edf415b3cb8b","originalAuthorName":"王亚伟"},{"authorName":"张庆华","id":"5083ef62-e06e-4b5e-812e-3742ffeacc5b","originalAuthorName":"张庆华"},{"authorName":"刘汉霞","id":"fbddb013-6940-4d50-90dd-c653353ce36b","originalAuthorName":"刘汉霞"},{"authorName":"江桂斌","id":"76d6e002-963d-4433-b282-a7ff53902719","originalAuthorName":"江桂斌"}],"doi":"10.3321/j.issn:1000-8713.2005.05.011","fpage":"492","id":"cca65a15-bb9e-4fee-a5aa-5521a89dd694","issue":"5","journal":{"abbrevTitle":"SP","coverImgSrc":"journal/img/cover/SP.jpg","id":"58","issnPpub":"1000-8713","publisherId":"SP","title":"色谱 "},"keywords":[{"id":"26114f64-2ef9-482e-afd0-0004cc80d80e","keyword":"高分辨气相色谱-高分辨质谱","originalKeyword":"高分辨气相色谱-高分辨质谱"},{"id":"0e993cf5-e566-4a60-8d3e-1935fdd980ec","keyword":"多溴联苯醚","originalKeyword":"多溴联苯醚"},{"id":"3c7fe2dd-3067-4bb7-9ef9-75eaabcbf133","keyword":"污泥","originalKeyword":"污泥"}],"language":"zh","publisherId":"sp200505011","title":"高分辨气相色谱-高分辨质谱测定活性污泥中的多溴联苯醚","volume":"23","year":"2005"},{"abstractinfo":"脱脂棉在碱存在下与环硫氯丙烷发生醚化反应,合成了一种环境功能材料--聚硫醚纤维素(PTCC). 考察了溶液酸度对吸附容量的影响并研究了PTCC对3种阳离子染料的吸附动力学与热力学. 研究结果表明,中性介质较有利于吸附的进行;298 K、pH=7.0时,静态吸附2 h后,吸附趋于平衡,PTCC对碱性艳蓝B、碱性艳蓝R和夜蓝的饱和吸附量分别为726、652和320 mg/g;PTCC对阳离子染料的吸附过程符合Lagergren二级吸附动力学方程,吸附速率常数k2随着温度的降低而升高,低温有利于吸附反应的进行;吸附过程ΔG、ΔH和ΔS均为负值,表明该吸附是自发的放热过程,主要是通过范德华力实现的. 吸附过程的吸附等温模型符合Langmuir等温式,可以用单分子层吸附理论加以解释.","authors":[{"authorName":"王亚伟","id":"0b393206-3fce-4fa9-bb92-8f5bab3d88e8","originalAuthorName":"王亚伟"},{"authorName":"施文健","id":"f603eb94-937f-4b0e-a484-173fd535bde5","originalAuthorName":"施文健"},{"authorName":"陈轩","id":"510faad5-bab2-43a4-8093-9573cf0116c2","originalAuthorName":"陈轩"},{"authorName":"韩悦","id":"be080d23-dd9f-4d3a-a8cd-ad03ab3deca1","originalAuthorName":"韩悦"},{"authorName":"杨琴淋","id":"ed3a6f7c-7bd2-4c2d-a25e-14a6b4926f38","originalAuthorName":"杨琴淋"},{"authorName":"周艳","id":"703dfae2-3584-4343-872d-abff70630178","originalAuthorName":"周艳"}],"doi":"10.3724/SP.J.1095.2010.90668","fpage":"817","id":"dc2a9416-a054-448f-af69-4d04fc5f1c16","issue":"7","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"64223c57-98c8-4e3d-b10e-d5473b00bafe","keyword":"聚硫醚纤维素","originalKeyword":"聚硫醚纤维素"},{"id":"b631b8a1-24ce-4827-86d6-28c275b95ac1","keyword":"阳离子染料","originalKeyword":"阳离子染料"},{"id":"cd885469-8f53-4410-8b13-9886504be9d9","keyword":"吸附","originalKeyword":"吸附"},{"id":"f35bee9b-44f1-489d-941b-e70da21f644b","keyword":"热力学","originalKeyword":"热力学"},{"id":"f57cf7a1-ead8-4434-96ea-bc0f07154af7","keyword":"动力学","originalKeyword":"动力学"}],"language":"zh","publisherId":"yyhx201007015","title":"聚硫醚纤维素吸附阳离子染料的动力学与热力学","volume":"27","year":"2010"},{"abstractinfo":"镁合金微弧氧化陶瓷膜具有较好的耐蚀性和机械性能.综述了镁合金微弧氧化膜耐蚀性、硬度、摩擦磨损和拉伸性能等的最新研究进展,归纳了电解液成分和工艺参数对陶瓷膜耐蚀性和机械性能的影响.概括了镁合金微弧氧化处理技术的不足之处.","authors":[{"authorName":"高宁宁","id":"4f0b0c03-69c7-4110-97b9-7de31e3c1fcb","originalAuthorName":"高宁宁"},{"authorName":"王亚伟","id":"5de58eaa-084a-4340-8fb2-9a0b26fc4476","originalAuthorName":"王亚伟"},{"authorName":"胡会利","id":"f36e7a25-e18a-46c3-8ef4-b83dde19ba58","originalAuthorName":"胡会利"}],"doi":"10.3969/j.issn.1001-3849.2009.11.005","fpage":"17","id":"633b182e-91d3-4180-8cb4-32e388b0e28a","issue":"11","journal":{"abbrevTitle":"DDYJS","coverImgSrc":"journal/img/cover/DDYJS.jpg","id":"20","issnPpub":"1001-3849","publisherId":"DDYJS","title":"电镀与精饰 "},"keywords":[{"id":"b0fe182a-00cd-4aca-965e-7b5f1c00deaa","keyword":"镁合金","originalKeyword":"镁合金"},{"id":"9f8acb16-a5a3-41f6-a02f-c29556b1b326","keyword":"微弧氧化","originalKeyword":"微弧氧化"},{"id":"bf979e2e-f057-4510-9ca3-c26c9ac627db","keyword":"耐蚀性","originalKeyword":"耐蚀性"},{"id":"415c1a0c-39bb-437c-a540-c1dd1e9af8ba","keyword":"机械性能","originalKeyword":"机械性能"}],"language":"zh","publisherId":"ddjs200911005","title":"镁合金微弧氧化陶瓷膜层性能研究进展","volume":"31","year":"2009"},{"abstractinfo":"介绍了利用组态王作为监控,可编程控制器作为下位机,实现了耐火厂散料配料系统的自动化生产,该系统具有手动功能和自动功能,手动功能具有现场手动和上位机手动功能,自动功能具有全自动和半自动功能.该系统可实现配方和配料制度的任意更改,投资低,故障少,自动化程度高.","authors":[{"authorName":"胡万里","id":"1adf7690-152f-4613-8672-0f57838973f3","originalAuthorName":"胡万里"}],"doi":"10.3969/j.issn.1001-1935.2010.01.023","fpage":"79","id":"1dfe65c5-d8e0-4c0f-8675-5a16012754bd","issue":"1","journal":{"abbrevTitle":"NHCL","coverImgSrc":"journal/img/cover/NHCL.jpg","id":"55","issnPpub":"1001-1935","publisherId":"NHCL","title":"耐火材料 "},"keywords":[{"id":"c439469b-f720-48b4-9591-ac1972753d5a","keyword":"组态王","originalKeyword":"组态王"},{"id":"57ed6c1f-ef90-4357-8a60-32ade74e3327","keyword":"配料","originalKeyword":"配料"},{"id":"41435bef-3a13-40c3-9a86-acb7115813a4","keyword":"上位机","originalKeyword":"上位机"}],"language":"zh","publisherId":"nhcl201001023","title":"基于组态王的包钢耐火配料系统设计","volume":"44","year":"2010"},{"abstractinfo":"针对目前由金属开口谐振环与金属杆构成的左手材料结构存在构造比较复杂、工艺实现较难的缺点,设计实现了一种基于金属条的改进结构一”王”字型结构.通过理论分析和电磁仿真软件Ansoft HFSS 10模拟仿真,利用散射参量法提取参数结果表明该结构可以在X波段实现介电常数和磁导率同时为负.讨论研究了该左手结构的金属条宽度、中间缺口宽度、中间条宽度三个结构尺寸参数变化对谐振频率和透射峰幅值的影响,结果表明三个参数的变化都会对二者产生影响,其中金属条宽度改变对透射峰值影响幅度相对较大,缺口宽度改变对谐振频率影响幅度相对较大.","authors":[{"authorName":"孙振","id":"9082c3be-c293-4b15-909c-5363afc0fb88","originalAuthorName":"孙振"},{"authorName":"竹有章","id":"8794de66-28bc-4427-979c-0fb97ab9ed96","originalAuthorName":"竹有章"},{"authorName":"何星","id":"6f08d970-e077-44f0-b31d-5ff4c5df0ddf","originalAuthorName":"何星"},{"authorName":"杨成莱","id":"5bc766cf-c957-469f-bbec-fd1d91e6a29e","originalAuthorName":"杨成莱"},{"authorName":"李磐石","id":"5e728fff-ba05-408f-beb6-bbddd58f2624","originalAuthorName":"李磐石"}],"doi":"","fpage":"107","id":"59adf8cc-36c0-4ea6-9f45-b82068f1d277","issue":"1","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"0445fc0a-e195-44ae-af64-1760db975e7a","keyword":"金属条","originalKeyword":"金属条"},{"id":"d8320c68-3cf6-4f73-a0e7-166c6d16aebd","keyword":"左手材料","originalKeyword":"左手材料"},{"id":"ac328512-f54f-4710-8a77-4dab2151863d","keyword":"负折射率","originalKeyword":"负折射率"},{"id":"46c8a8fd-6c41-46c9-a435-b75cc3ba30f2","keyword":"谐振频率","originalKeyword":"谐振频率"},{"id":"f5aef037-2407-4220-9e53-1a929c2f3666","keyword":"S参数","originalKeyword":"S参数"}],"language":"zh","publisherId":"clkxygc201301022","title":"“王”字型左手材料结构的设计与仿真","volume":"31","year":"2013"},{"abstractinfo":"2011年9月27日，正值《材料科学与工程学报》第四届编辑委员会荣誉主任王启东先生九十华诞暨从教68周年。在此，我们向王启东先生表示最热烈的祝贺。","authors":[{"authorName":"无","id":"fa1f4c18-4b21-41fe-a5da-f75bee6fcc9f","originalAuthorName":"无"}],"doi":"","fpage":"0003","id":"2723bfaa-3a2b-477a-b3a3-34e9caa3dceb","issue":"6","journal":{"abbrevTitle":"CLKXYGCXB","coverImgSrc":"journal/img/cover/CLKXYGCXB.jpg","id":"13","issnPpub":"1673-2812","publisherId":"CLKXYGCXB","title":"材料科学与工程学报"},"keywords":[{"id":"1695bd23-b0d0-4d65-9a72-a2e0e859d3b0","keyword":"材料科学与工程","originalKeyword":"材料科学与工程"},{"id":"73611c6e-b3e7-45fe-a831-ffebce6bbf74","keyword":"编辑委员会","originalKeyword":"编辑委员会"},{"id":"318bfe79-321e-4d80-b6c7-b14714da80e6","keyword":"桃","originalKeyword":"桃"}],"language":"zh","publisherId":"clkxygc201106034","title":"寿山千寻碧，桃李几度红——热烈祝贺王启东先生九十华诞","volume":"29","year":"2011"},{"abstractinfo":"恒利铁矿是王窑矿区的一部分,该矿0-15线矿体一期开采深度在-40m以上,一期开采储量为705万t,矿石品位平均为TFe48.07%.文章针对恒利铁矿矿产资源特点,研究制定了综合开采工程技术方案,并详细进行了技术论证和经济分析,以确保该部分矿产资源能安全高效地获得回收.","authors":[{"authorName":"余斌","id":"03949a35-7e95-495a-938c-334d816d8947","originalAuthorName":"余斌"},{"authorName":"龚宇同","id":"15cd43c7-bf9f-4b1a-91f8-c8650d1ae20b","originalAuthorName":"龚宇同"},{"authorName":"谢源","id":"c21a63fe-d14d-4653-84f4-e73ad3a2a3c7","originalAuthorName":"谢源"},{"authorName":"褚志勇","id":"f7382db6-2c95-4db7-ac38-c52c53a4d90a","originalAuthorName":"褚志勇"}],"doi":"10.3969/j.issn.1000-6826.2006.03.006","fpage":"14","id":"7d738339-d21d-442d-ac57-d71f8ad722f3","issue":"3","journal":{"abbrevTitle":"JSSJ","coverImgSrc":"journal/img/cover/3abe017a-2574-4821-8152-4ae974ef0471.jpg","id":"47","issnPpub":"1000-6826","publisherId":"JSSJ","title":"金属世界"},"keywords":[{"id":"cbf3c134-3cf6-4029-86f0-6c35d3811582","keyword":"恒利铁矿开采","originalKeyword":"恒利铁矿开采"},{"id":"6bfaae58-4cb0-4142-b18d-24bcd93c7ba6","keyword":"方案研究","originalKeyword":"方案研究"},{"id":"0a182b87-2725-44fd-8cbc-e447518344f5","keyword":"投资估算","originalKeyword":"投资估算"},{"id":"f1fee395-db7a-4af6-a75d-356b813cdd24","keyword":"财务评价","originalKeyword":"财务评价"}],"language":"zh","publisherId":"jssj200603006","title":"王窑矿区恒利铁矿0-15线矿体安全开采技术研究","volume":"","year":"2006"},{"abstractinfo":"踏王山金矿位于海南省戈枕金矿带东南部,矿体主要产于东西向构造蚀变带中,矿石类型为蚀变岩型和石英脉型.在详细的野外地质调查基础上,对踏王山金矿床流体包裹体特征进行研究,并结合矿体产出形态特征,对流体来源以及矿床成因进行探讨.结果表明:矿区流体包裹体主要为气液两相包裹体和纯CO2包裹体,成矿流体具有中低温(均一温度为192～362℃)、中盐度(平均值为7.52％)及低密度(0.46～0.87g/cm3)的特征,成矿深度为中深环境.从包裹体成分上看,流体包裹体既有岩浆水特征(高H2O、H2含量,w(F-)/w(Cl-)≥1),又具有地下热卤水的特征(w(Na+)/w(K+)＞1),明显富集Ca2+或者Ca2+含量较高的成分,显示可能为混合流体.矿床成因为岩浆热液与地下热卤水叠加的复合型中低温热液矿床.","authors":[{"authorName":"熊瑛","id":"9206db25-0760-46a1-9d07-bfba05bb6068","originalAuthorName":"熊瑛"},{"authorName":"朱自强","id":"4c01c4cc-1589-40d6-81b3-36898dafe57a","originalAuthorName":"朱自强"},{"authorName":"胡祥昭","id":"26536afa-30fc-4543-b259-95329f09de88","originalAuthorName":"胡祥昭"},{"authorName":"鲁光银","id":"b917a7c2-6764-49a3-823f-af88b9a9bf3e","originalAuthorName":"鲁光银"}],"doi":"","fpage":"1281","id":"bb0c79a2-4865-40ef-afcb-2fdc21a73843","issue":"6","journal":{"abbrevTitle":"ZGYSJSXB","coverImgSrc":"journal/img/cover/ZGYSJSXB.jpg","id":"88","issnPpub":"1004-0609","publisherId":"ZGYSJSXB","title":"中国有色金属学报"},"keywords":[{"id":"e2eb0ef2-992b-44a0-bdfc-6925da207589","keyword":"流体包裹体","originalKeyword":"流体包裹体"},{"id":"c4490cdb-1c45-4424-b6ac-10048ba4254a","keyword":"矿床成因","originalKeyword":"矿床成因"},{"id":"1c8ded80-f8cd-47d6-b9e9-3dec0ae33385","keyword":"金矿","originalKeyword":"金矿"},{"id":"a7d7b293-6843-4e66-b6ac-f5bf5acf51d3","keyword":"海南","originalKeyword":"海南"}],"language":"zh","publisherId":"zgysjsxb201606016","title":"海南省东方市踏王山金矿床流体包裹体特征及矿床成因","volu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