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The subsolidus phase relations of a ZnO-V(2)O(5)-K(2)O system are investigated by X-ray powder diffraction. There is 1 ternary compound, 11 binary compounds and 14 three-phase regions in this system. The phase diagrams of V(2)O(5)-K(2)O with the K(2)O content ranging from 0 to 71 mol% and pseudo-binary system of ZnO-K(2)ZnV(2)O(7) are also studied by X-ray powder diffraction and differential thermal analysis methods.

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