为保证锡银铜合金及焊点在低温环境下使用可靠性,将SnAg3.0Cu0.5合金焊料和焊点在25、4、-20和-60℃恒温环境中进行储存565 d后,考察不同温度下SnAg3.0Cu0.5无铅焊料微观组织和物相变化,对经冷储存后SnAg3.0Cu0.5/Cu焊接接头进行拉伸强度和低周疲劳测试.结果表明,焊料经低温储存后没有发生灰锡转变,合金主要由Ag3Sn和β-Sn组成,组织形貌转变为树枝状组织,排列具有一定取向,β-Sn相晶面间距变小,焊料出现低温脆性倾向;随储存温度降低,SnAg3.0Cu0.5焊料与Cu基板互连结构的断裂界面从焊料侧向铜基体方向移动,焊缝的抗拉强度随之下降;在恒幅对称应变条件下,疲劳极限-循环次数曲线的斜率随焊件储存温度降低而变大,焊接接口的抗疲劳性能变差.
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