采用阳极氧化法以NH4F/乙二醇为电解液制备高度有序的TiO2纳米管,研究了不同电解液浓度、电解电压、电解时间等参数对TiO2纳米管的影响.在不同温度下对TiO2纳米管进行退火处理.分别利用转靶X射线衍射仪(XRD)和场发射扫描电子显微镜(SEM)对TiO2纳米管阵列的物相结构和形貌变化进行表征.结合氧化过程电流密度变化探讨了TiO2纳米管的生长机理.结果表明,不同的阳极氧化参数对TiO2纳米管的形貌有着一定的影响,不同退火温度可以使TiO2纳米管的晶相结构发生转变.
参考文献
| [1] | Michailowski A;Aimawlawi D;Cheng G S et al.[J].Chemical Physics Letters,2001,349:1-51. |
| [2] | Chu S Z;Wada K;Inoue S et al.[J].Electrochimica Acta,2003,48:3147. |
| [3] | Varghese O K;Gong D;Paulose M.[J].Advanced Materials,2003:15-624. |
| [4] | Paulose M;Shankar K;Varghese OK;Mor GK;Grimes CA .Application of highly-ordered TiO2 nanotube-arrays in heterojunction dye-sensitized solar cells[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,2006(12):2498-2503. |
| [5] | 夏天,曹望和,田莹,付姚,周立新.锐钛矿相TiO2纳米薄膜的制备及光致发光研究[J].功能材料,2005(01):100-102,106. |
| [6] | 郭力,梁林云,陈冲,王命泰,孔明光,王孔嘉.聚苯胺基固态染料敏化太阳电池中电子输运性能的研究[J].物理学报,2007(07):4270-4276. |
| [7] | Gong D;Grimes C A;Varghese O K et al.[J].Journal of Materials Research,2001,16:3331. |
| [8] | Macak J M;Tsuchiya H;Angew S P .[J].Angewandte Chemie International Edition,2005,44:2100-2102. |
| [9] | Zheng Haidong;Sadek A Z et al.[J].Electrochemistry Communications,2009,11:1308-1311. |
| [10] | Mor GK;Varghese OK;Paulose M;Shankar K;Grimes CA .A review on highly ordered, vertically oriented TiO2 nanotube arrays: Fabrication, material properties, and solar energy applications[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2006(14):2011-2075. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%