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采用直流磁控溅射技术在玻璃衬底上制备了掺锡氧化铟(ITO)透明导电薄膜,通过XRD、XPS、四探针仪和分光光度计等测试方法,研究了沉积速率对ITO薄膜微观结构和光电性能的影响.实验结果表明:ITO样品为具有(222)择优取向的立方锰铁矿结构,其晶体结构和光电性能明显受到沉积速率的影响.当沉积速率为4 nm/min时,所制备的ITO薄膜具有最大的晶粒尺寸(32.5 nm)、最低的电阻率(1.1×10-3Ω·cm)、最高的可见光区平均透过率(86.4%)和最大的优良指数(7.9×102 S·cm-1),其光电综合性能最佳.同时采用Tauc法则计算了ITO薄膜的光学能隙,结果显示沉积速率增大时,ITO薄膜的光学能隙单调减小.

参考文献

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