本文通过液相化学还原和热还原联合作用制备了柔性透明导电石墨烯膜.阳极氧化铝(AAO)模板在制备过程中既作为抽滤的滤网,又作为热还原处理时支撑石墨烯膜的衬底,制成的柔性透明石墨烯膜对波长为540-840nm的可见光透光率为80%,面电阻为850Ω/平方,这与化学气相沉积法制备的石墨烯膜(280-770Ω/平方)相近,而低于溶液法制备的石墨烯膜(通常是103-104Ω/平方).
参考文献
[1] | Novoselov KS;Jiang Z;Zhang Y;Morozov SV;Stormer HL;Zeitler U;Maan JC;Boebinger GS;Kim P;Geim AK .Room-temperature quantum Hall effect in graphene.[J].Science,2007(5817):1379-0. |
[2] | (O)zyilmaz B;Pablo J H;Efetov D;Kim P .Electronic transport in locally gated graphene nanoconstrictions[J].Applied Physics Letters,2007,91(192107):1-3. |
[3] | Chen C Y;Rosenblatt S;Bolotin K I;Kalb W Kim P Kymissis I Stormer H L Heinz T F Hone J .Current saturation in zero-bandgap,topgated graphene field-effect transistors[J].Nature Nanotechnology,2009,4:861-867. |
[4] | Ozyilmaz B;Jarillo-Herrero P;Efetov D;Abanin DA;Levitov LS;Kim P .Electronic transport and quantum hall effect in bipolar graphene p-n-p junctions[J].Physical review letters,2007(16):166804-1-166804-4-0. |
[5] | Geim AK;Novoselov KS .The rise of graphene[J].Nature materials,2007(3):183-191. |
[6] | Lee DS;Riedl C;Krauss B;von Klitzing K;Starke U;Smet JH .Raman Spectra of Epitaxial Graphene on SiC and of Epitaxial Graphene Transferred to SiO2[J].Nano letters,2008(12):4320-4325. |
[7] | Li, XS;Zhu, YW;Cai, WW;Borysiak, M;Han, BY;Chen, D;Piner, RD;Colombo, L;Ruoff, RS .Transfer of Large-Area Graphene Films for High-Performance Transparent Conductive Electrodes[J].Nano letters,2009(12):4359-4363. |
[8] | Kim K S;Zhao Y;Jang H;Lee S Y Kim J M Kim K S Ahn J H Kim P Choi J Y Hong B H .Large-scale pattern growth of graphene films for stretchable transparent electrodes[J].Nature,2009,457:706-709. |
[9] | Reina A;Jia X T;Ho J;Nezich D Son H B Bulovic V Dresselhaus M S Kong J .Large-scale arrays of single-layer graphene resonators[J].Nano Letters,2009,9(08):3087. |
[10] | Chen J H;Jang C;Xiao S;Ishigami D M,Fuhrer M S,Graphene N .Electronic and photonic properties and devices[J].Nanotechnology,2008,3:206. |
[11] | Liao, K.-H.;Mittal, A.;Bose, S.;Leighton, C.;Mkhoyan, K.A.;MacOsko, C.W. .Aqueous only route toward graphene from graphite oxide[J].ACS nano,2011(2):1253-1258. |
[12] | Li, S.-S.;Tu, K.-H.;Lin, C.-C.;Chen, C.-W.;Chhowalla, M. .Solution-processable graphene oxide as an efficient hole transport layer in polymer solar cells[J].ACS nano,2010(6):3169-3174. |
[13] | Chen, G.-L.;Shau, S.-M.;Juang, T.-Y.;Lee, R.-H.;Chen, C.-P.;Suen, S.-Y.;Jeng, R.-J. .Single-layered graphene oxide nanosheet/polyaniline hybrids fabricated through direct molecular exfoliation[J].Langmuir: The ACS Journal of Surfaces and Colloids,2011(23):14563-14569. |
[14] | Li XL;Zhang GY;Bai XD;Sun XM;Wang XR;Wang E;Dai HJ .Highly conducting graphene sheets and Langmuir-Blodgett films[J].Nature nanotechnology,2008(9):538-542. |
[15] | Eda G;Fanchini G;Chhowalla M .Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material[J].Nature nanotechnology,2008(5):270-274. |
[16] | Yamaguchi, H.;Eda, G.;Mattevi, C.;Kim, H.;Chhowalla, M. .Highly uniform 300 mm wafer-scale deposition of single and multilayered chemically derived graphene thin films[J].ACS nano,2010(1):524-528. |
[17] | Becerril, H.A.;Mao, J.;Liu, Z.;Stoltenberg, R.M.;Bao, Z.;Chen, Y. .Evaluation of solution-processed reduced graphene oxide films as transparent conductors[J].ACS nano,2008(3):463-470. |
[18] | Shu Jun Wang;Yan Geng;Qingbin Zheng .Fabrication of highly conducting and transparent graphene films[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(6):1815-1823. |
[19] | Jianxin Geng;Leijing Liu;Seung Bo Yang .A Simple Approach for Preparing Transparent Conductive Graphene Films Using the Controlled Chemical Reduction of Exfoliated Graphene Oxide in an Aqueous Suspension[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(34):14433-14440. |
[20] | De S;King P J;Lotya M;Doherty E.M,Coleman J N .Chemical sensors based on randomLy stacked graphene flakes[J].Small,2009,6(03):458. |
[21] | Zhu Y W;Cai W W;Piner R D;Ruoff R.S .Transparent self-assembled films of reduced graphene oxide platelets[J].Applied Physics Letters,2009,95:103104. |
[22] | Blake P;Brimicombe P.D;Nair R.R;Geim A K,Novoselov K S .Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations[J].Nano Letters,2008,8(06):1704. |
[23] | Kovtyukhova N I;Ollivier P J;Martin B R;Thomas E.Mallouk,Gorchinskiy A D .Layer-by-layer assembly of ultrathin composite films from micron-sized graphite oxide sheets and polycations[J].Chemistry of Materials,1999,11(03):771-778. |
[24] | Wufeng Chen;Lifeng Yan;P. R. Bangal .Chemical Reduction of Graphene Oxide to Graphene by Sulfur-Containing Compounds[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(47):19885-19890. |
[25] | Paredes, JI;Villar-Rodil, S;Solis-Fernandez, P;Martinez-Alonso, A;Tascon, JMD .Atomic Force and Scanning Tunneling Microscopy Imaging of Graphene Nanosheets Derived from Graphite Oxide[J].Langmuir: The ACS Journal of Surfaces and Colloids,2009(10):5957-5968. |
[26] | Ching-Yuan Su;Yanping Xu;Wenjing Zhang .Electrical and Spectroscopic Characterizations of Ultra-Large Reduced Graphene Oxide Monolayers[J].Chemistry of Materials: A Publication of the American Chemistry Society,2009(23):5674-5680. |
[27] | Jincheng Liu;Huiseong Jeong;Jinzhang Liu .Reduction of functionalized graphite oxides by trioctylphosphine in non-polar organic solvents[J].Carbon: An International Journal Sponsored by the American Carbon Society,2010(8):2282-2289. |
[28] | Tamas Szabo;Anna Szeri;Imre Dekany .Composite graphitic nanolayers prepared by self-assembly between finely dispersed graphite oxide and a cationic polymer[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(1):87-94. |
[29] | Park S J;An J H;Potts J R;Velamakanni A Murali S Ruoff R S .Hydrazine-reduction of graphite-and graphene oxide[J].Carbon,2011,49:3019-3023. |
[30] | Michael J.McAllister;Je-Luen Li;Douglas H.Adamson .Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(18):4396-4404. |
[31] | Sasha Stankovich;Dmitriy A. Dikin;Richard D. Piner .Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(7):1558-1565. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%