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采用纳米ZrO2(8Y)粉和纳米ZnO粉为原料,对掺少量ZnO的ZrO2(8Y)进行无压烧结研究.实验结果表明,掺少量的ZnO能促进ZrO2与Y2O3的反应,加快四方相向立方相的转变,样品致密度和电导率显著提高.掺0.5wt%ZnO样品在1200℃煅烧2h的陶瓷致密度为94%,700℃时的电导率为9.02×10-3cm-1·Ω-1.

With adding of nano-ZnO, nano ZrO2(8Y) powder was used as raw materials for pressureless sintering at 1200℃. The results show that a small addition
of nano-ZnO accelerates the reaction between Y2O3 and ZrO2 in ZrO2(8Y). The ZrO_2(8Y)ceramic without nano-ZnO exhibits predominant tetragonal phase
with a small percentage of monoclinic, but the samples doped with nano-ZnO(0.5%~2.0% in mass)show a purely cubic phase. The densification and the conductivity of the
ceramic doped with nano-ZnO increase significantly.The densification of 94% and the conductivity of 9.02×10-3cm-1·Ω-1 at 700℃ were
observed for the sintered body doped with 0.5wt% nano-ZnO.

参考文献

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[3] 袁望治, 劳令耳, 田卫, 等.材料科学与工程, 2000, 18 (3): 57--60.
[4] 劳令耳, 袁望治, 田卫, 等(LAO Ling-Er, et al).硅酸盐学报(Journal of the Chinese Ceramic Society), 2002, 30 (1): 14--19.
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