采用溶胶-凝胶颗粒包覆技术在Ph(Zn1/3Nb3/3)O3基因溶体颗粒表面形成一层低熔硼硅包覆物,以包覆后的两种固溶体为高低温组元制备复相陶瓷.结果表明;颗粒包覆物可显著降低复相陶瓷的烧结温度,并有效抑制两相固溶反应,获得了低烧结温度、高介电常数、具有X7R温度特性的Ph(Zn1/3Nb2/3)O3基复相陶瓷
A novel sol-gel particle-coating technique was developed to form a thin glassy layer on the surface of PZN particles. Two types of
powders with different Curie temperatures were used as high-temperature constituent and low-temperature one to prepare PZN-based composite ceramics.
A PZN-based diphasic ceramic with X7R character and high dielectric constant was successfully obtained at low sintering temperature.
The results show that the particle-coating method is effective to lower sintering temperature of the composite ceramics and suppress the reaction
between the two starting constituents.
参考文献
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