介绍了利用固体电解质进行金属熔体无污染脱氧的技术.分析表明,其实质是氧离子在异相间的可控流动.根据炉渣的电化学特性,探讨了渣-金属间外加电场脱氧的可行性及特点.此外,提出了用固体氧离子膜技术从氧化物、熔渣中回收有价金属的可能性,并讨论了在MgCl2-NdCl3-MgO熔盐电解过程中,以MgO作为主要原料用固体氧离子渗透膜生产金属镁的环保新技术.确认冶金过程的带电粒子控制将是十分有前途的研究领域.
参考文献
| [1] | Ian Christmas.2001年中国钢铁年会论文集[M].北京:冶金工业出版社,2001:4-8. |
| [2] | 殷瑞钰.2001年中国钢铁年会论文集[M].北京:冶金工业出版社,2001:53-57. |
| [3] | Pal U B .[J].Journal of The Minerals,Metals & Materials Society,2001,10:25. |
| [4] | Korousic B;Marincek B .[J].Chimica Acta,1968,51:907-911. |
| [5] | Fischer W A;Janke D .[J].Scripta Metallurgica et Materialia,1972,6:923-930. |
| [6] | Oberg K E;Friedman L M;Rapp R A .[J].Metallurgical and Materials Transactions,1973,4B(04):75-80. |
| [7] | 王龙妹;金振坚;高峰 等.[J].中国稀土学报,1998,16(01):441-444. |
| [8] | Iwase M;Tanida M;Mori T .[J].Metallurgical and Materials Transactions,1981,12B(12):517-522. |
| [9] | Yuan S;Pal U B;Chou K C .[J].Journal of the Electrochemical Society,1994,141(02):467-476. |
| [10] | Hasham Z.;Chou KC.;Worrell WL.;Pal U. .DEOXIDATION OF MOLTEN STEEL USING A SHORT-CIRCUITED SOLID OXIDE ELECTROCHEMICAL CELL[J].Journal of the Electrochemical Society,1995(2):469-475. |
| [11] | Yuan S.;Chou KC.;Pal UB. .MODELING AND SCALEUP OF GALVANIC DEOXIDATION OF MOLTEN METALS USING SOLID ELECTROLYTE CELLS[J].Journal of the American Ceramic Society,1996(3):641-650. |
| [12] | Pal U B;Chou K C .[P].United States Patent 312525,1994. |
| [13] | Pal U B;Chou K C;Yuan S et al.[P].United States Patent 443699,1995. |
| [14] | Pal U B;Chou K C;Yuan S et al.[P].United States Patent 567286,1996. |
| [15] | 周国治;李福 .[P].中国专利:971169543 |
| [16] | 胡晓军;肖莉;李福 等.[J].金属学报,1999,35(03):316-319. |
| [17] | Chou Kou-chih;Li Fu-shen;Lu Xiong-gang.China-KoreaJoint Symposium on Advanced Steel Technology for FutureIndustry[M].北京,1999:30-33. |
| [18] | LI Fu-shen;Lu Xiong-gang;Hu Xiao-jun.Proceedings of7th Asian Conference on Solid State Ionics[M].Fuzhou,2000:675-679. |
| [19] | Chou Kou-chih.Workshop on New Generation Steel[M].北京,2001:249-253. |
| [20] | Sen N;Ghosh M;Banerjee U .[J].Scandinavian Journal of Metallurgy,1999,28:249-253. |
| [21] | 周国治;鲁雄刚;丁伟中 .[P].中国专利:021114773 |
| [22] | YAO S;Kozuka Z .[J].Journal of the Japan Society of Powder and Powder Metallurgy,1988,35(04):252-256. |
| [23] | Britten S.C.;Pal U.B. .Solid-State Amperometric Sensor for the In-Situ Monitoring of Slag Composition and Transport Properties[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2000(4):733-753. |
| [24] | Victorovich G S;Diaz C;Vallbacka D K.[M].Metallurgical Soc ofAIME,1984:907-924. |
| [25] | Pal U B;Woolley D;Kenney G.[J].Journal of The Minerals,Metals & Materials Society,2001(10):32-35. |
| [26] | Soral P;Pal U B;Larson H R et al.[J].Metallurgical and Materials Transactions,1999,30B(04):307-321. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%