采用化学沉淀法制备纳米TiO2-xNx粉体,使粉体的禁带宽度变窄,在可见光下表现出较高的抗茵率(32%).再采用浸渍法制备掺Fe的TiO2-xNx粉体,实现TiO2粉体的金属一非金属双掺杂.Fe-TiO2-xNx粉体在可见光下的抗茵率随着掺Fe量的增加呈先增加后减小的趋势,当掺杂量为0.5%(原子分数)时抗茵活性最高,达71%.
参考文献
[1] | Fujishima A;Honda K .Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238(5358):37. |
[2] | Carey J H;Lawrence J;Tosine H M.Photodechlorination of PCBs in the presence of TiO2 in aqueous suspensions[J].Bulletin of Environmental Contamination and Toxicology,1976(16):697. |
[3] | Sun F;Wu M;Li W et al.Relationshp between crystalliste size and photocatalytie activtiy of titaniurndioxide[J].Journal of Catalysis,1998,19(03):229. |
[4] | Michael R. Hoffmann;Scot T. Martin;Wonyong Choi;Detlef W. Bahnemann .Environmental Applications of Semiconductor Photocatalysis[J].Chemical Reviews,1995(1):69-96. |
[5] | Choi W;Terrnin A;Hofmann M R .The role of metal ion dopants in quantum-sized TiO2:Correlation between photoreactivity and charge carried recombination dynamics[J].Journal of Physical Chemistry,1994,98(05):13669. |
[6] | Wang Y;Liu W;Lu M et al.Preparation and photocatlytie properties of Zr4+ doped TiO2 nanoerystals[J].Journal of Molecular Catalysis A:Chemical,2004,215:137. |
[7] | 吴玉程,陈挺松,解挺,李广海,郑治祥,张立德.纳米TiO2稀土元素掺杂改性与光催化性能研究[J].功能材料,2005(01):124-126. |
[8] | 蔡河山,刘国光,吕文英,余林,张惠芳.稀土元素掺杂改性纳米TiO2光催化性能[J].稀有金属,2006(03):390-394. |
[9] | E Lei;Xu Mingxia .Preparation and properties of titanium oxide photocatalyst with visible light activity[J].Key Engineering Materials,2005,280-283:381. |
[10] | 鄂磊 .可见光活性TiO<,2>光催化剂的制备及其光催化性能的研究[D].天津大学,2005. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%