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通过透射电镜观察了低氮低钒D36船板钢的析出相特征,并讨论了其沉淀强化作用。结果表明:实验用钢的组织均为铁素体-珠光体组织,珠光体中未见析出相,仅在铁素体中观察到析出相。VCx析出相为矩形片状形貌,在铁素体基体上均匀弥散沉淀,析出相以{100}α-Fe为惯习面,与基体存在Baker-Nutting取向关系;少量球状V6C5析出相(单斜结构)与铁素体基体存在一定取向关系,可能是共格VCx相通过碳原子重新分布转变而成。低氮低钒钢中加入0.05%V,沉淀强化值约为63 MPa,加入微量铌后在铁素体内形成一定密度的位错能有效发挥钒的沉淀强化作用。

Characteristics of precipitates in low-nitrogen and low-vanadium D36 ship plate steel was observed by tansmission electron microscopy and the effect of precipitation strengthening was discussed.The results indicate that the microstructure of the steel consists of ferrite and pearlite.Precipitates are observed in ferrite but have not been detected in pearlite.Within ferrite the precipitates of VCx with rectangular platelet shape present a uniform and dispersive distribution.The precipitates,with a(001)α-Fe habit plane exhibit the Baker-Nutting orientation relationship with matrix.The TEM observation also reveals the existence of a few sphericall shaped precipitate of V6C5(monoclinic system) having an orientation relationship with ferrite.It appears that the V6C5 phase is transformed from the coherent VCx by redistribution of carbon atoms.The precipitation strengthening increment is about 63 MPa in the low-nitrogen and low-vanadium steel containing 0.05%V.The strengthening effect of vanadium can be enhanced by high density dislocations in ferrite with addition of small amounts of niobium.

参考文献

[1] Woodhead J H.The physical metallurgy of vanadium steels[A].VANITEC Pub,1979:3-10.
[2] T. N. Baker .Processes, microstructure and properties of vanadium microalloyed steels[J].Materials Science and Technology: MST: A publication of the Institute of Metals,2009(9):1083-1107.
[3] Davenport A T;Honeycombe R W K.Precipitation of carbides at γ-α boundaries in alloy steels[A].The Royal Society,1971:191-205.
[4] Edmonds D V .The strengthening of an Fe-V-C low-alloy steel by carbide precipitation during continuous cooling from the austenitic condition[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,1973,4(11):2527-2533.
[5] Bepari M A .Structure of continuously cooled low-carbon vanadium steels[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,1990,21:2839-2855.
[6] Shanmugam S;Misra R D K;Mannering T et al.Impact toughness and mlerostructure relationship in niohlum- and vanadium-microalloyed steels processed with varied cooling rates to similar yield strength[J].Materials Science and Engineering A:Structural Materials Properties Microstructure and Processing,2006,437(02):436-445.
[7] Lagneborg R;Siwekki T;Zajac S et al.The role of vanadium in microalloyed steels[J].Scandinavian Journal of Metallurgy,1999,28(05):186-241.
[8] G. FOURLARIS;A. J. BAKER;G. D. PAPADIMITRIOU .A MICROSCOPIC INVESTIGATION OF THE PRECIPITATION PHENOMENA OBSERVED DURING THE PEARLITE REACTION IN VANADIUM ALLOYED CARBON STEELS[J].Acta Metallurgica et Materialia,1995(10):3733-3742.
[9] Todd J A;Li P .Microstructure-mechanical property relationships in isothermally transformed vanadium steels[J].Metallurgical and Materials Transactions A:Physical Metallurgy and Materials Science,1986,17(07):1191-1202.
[10] Epicier T;Acevedo D;Perez M .Crystallographic structure of vanadium carbide precipitates in a model Fe-C-V steel[J].Philosophical magazine: structure and properties of condensed matter,2008(1):31-45.
[11] B.K. Show;R. Veerababu;R. Balamuralikrishnan;G. Malakondaiah .Effect of vanadium and titanium modification on the microstructure and mechanical properties of a microalloyed HSLA steel[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2010(6):1595-1604.
[12] B illingham J;Bell P S;Lewis M H .A superlattice with monoclinic symmetry based on the compound V6 C5[J].Philosophical Magazine,1972,25(03):661-671.
[13] Lipatnikov V.N.;Ettmayer P.;Lengauer W.;Gusev A.I. .Phase transformations in non-stoichiometric vanadium carbide[J].Journal of Physics. Condensed Matter,1999(1):163-184.
[14] M.D.C. Sobral;P.R. Mei;H.-J. Kestenbach .Effect of carbonitride particles formed in austenite on the strength of microalloyed steels[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2004(1/2):317-321.
[15] Kesternbach H J;Gallego J .On dispersion hardening of mieroalloyed hot strip steels by carbonitride precipitation in austenite[J].Scripta Materialia,2001,44(05):791-796.
[16] Pickering F B.Physical Metallurgy and the Design of Steels[M].London:Applied Science Publishers LTD,1978:50-63.
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