对垂直转盘式MOCVD反应器生长GaN的气相化学反应路径进行研究.结合反应动力学模型,分别采用预混合进口但改变反应腔高度,以及采用环形分隔进口,对反应器的温场、流场和浓度场进行CFD数值模拟,由此确定反应器结构参数对化学反应路径的影响.通过观察主要含Ga粒子的浓度分布以及不同反应路径对生长速率的贡献,判断该反应器可能采取何种反应路径.研究发现,RDR反应器的主要反应路径是TMG热解为DMG,DMG为薄膜沉积的主要前体.反应腔高度变化对反应路径影响较小,但生长速率略有增大;当从预混合进口改为环形分隔进口时,生长更倾向于TMG热解路径,同时生长速率增大,但均匀性变差.
参考文献
[1] | Manasreh M O;Ferguson I T.Ⅲ-Nitride Semiconductor Materials:Growth,Taylor & Francis[M].New York Press,2003:159. |
[2] | Manasevit H M .Single-crystal Gallium Arsenide on Insulating Substrates[J].Applied Physics Letters,1968,12:156-159. |
[3] | Bergmann U;Reimer V;Atakan B .Gas Phase Studies of Trimethylgallium with Ammonia,Propylamine and Water at Elevated Temperatures:Towards an Understanding of GaN Growth and Oxygen Incorporation[J].Physical Status Solidi,1999,176:719-722. |
[4] | Schafer J.;Wolfrum J.;Fischer RA.;Simons A. .Detection of gas-phase species in MOCVD of GaN using molecular beam quadrupole mass spectrometry[J].Chemical Physics Letters,2000(5-6):477-481. |
[5] | Almond M J;Drew M G B;Jenkins C E.Organometallic Precursors for the Formation of GaN by Metal-organic Chemical Vapour Deposition:a Study of[(CH3) 2 GaNH2]3[J].Journal of the Chemical Society Dalton Transactions,1992:5-9. |
[6] | Mazzarese D;Tripathi A;Conner W C .In Situ FTIR and SurfaceAnalysis oft he Reaction of Trimethylgallium and Ammonia[J].Journal of Electronic Materials,1989,18(03):369-377. |
[7] | Thon A;Kuech T F .High Temperature Adducts Formation of Trimethylgallium and Ammonia[J].Applied Physics Letters,1996,69:55-57. |
[8] | Thon A;Kuech T F .Metal Organic Vapor Phase Growth of Complex Semiconductor Alloys[J].Materials Research Society Symposium Proceedings,1996,395:97. |
[9] | J. Randall Creighton;George T. Wang;Michael E. Coltrin .Fundamental chemistry and modeling of group-Ⅲ nitride MOVPE[J].Journal of Crystal Growth,2007(0):2-7. |
[10] | Creighton JR;Wang GT .Reversible adduct formation of trimethylgallium and trimethylindium with ammonia[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,2005(1):133-137. |
[11] | Parikh RP;Adomaitis RA .An overview of gallium nitride growth chemistry and its effect on reactor design: Application to a planetary radial-flow CVD system[J].Journal of Crystal Growth,2006(2):259-278. |
[12] | Theodoropoulos C.;Moffat HK.;Han J.;Mountziaris TJ. .Design of gas inlets for the growth of gallium nitride by metalorganic vapor phase epitaxy[J].Journal of Crystal Growth,2000(1/2):65-81. |
[13] | Parikh RP;Adomaitis RA;Aumer ME;Partlow DP;Thomson DB;Rubloff GW .Validating gallium nitride growth kinetics using a precursor delivery showerhead as a novel chemical reactor[J].Journal of Crystal Growth,2006(1):15-26. |
[14] | JINGXI SUN;J.M. REDWING;T.F. KUECH .Model Development of GaN MOVPE Growth Chemistry for Reactor Design[J].Journal of Electronic Materials,2000(1):2-9. |
[15] | Hirako A.;Yoshitani M.;Nishibayashi M.;Nishikawa Y.;Ohkawa K. .GaN-MOVPE growth and its microscopic chemistry of gaseous phase by computational thermodynamic analysis[J].Journal of Crystal Growth,2002(Pt.2):931-935. |
[16] | Chang-Yong Shin;Byung-Joon Baek;Cheul-Ro Lee;Bokchoon Pak;Jeong-Mo Yoon;Keun-Seop Park .Numerical analysis for the growth of GaN layer in MOCVD reactor[J].Journal of Crystal Growth,2003(3/4):301-312. |
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