综合介绍了分子式为Mn+1AXn的三元碳化物和氮化物的结构特征、制备方法、主要性能和应用前景. 该类化合物为层状的六方晶体结构, 空间群为P63/mmc; 采用热等静压方法能制备出高纯、致密的材料; 单相材料具有很好的导热性能和导电性能, 有较低的显微硬度和较高的弹性模量和剪切模量, 可以像金属一样进行加工, 并在高温下具有塑性等金属特性, 同时具有高的屈服强度, 高熔点、高热稳定性等陶瓷特性.
参考文献
[1] | Varsoum M W;Brodkin D;EI-Raghy T .Layered machinable ceramics for high temperature application[J].Scripta Materialia,1997,36(05):535-541. |
[2] | P. Finkel;M. W. Barsoum;T. El-Raghy .Low temperature dependencies of the elastic properties of Ti_(4)AlN_(3), Ti_(3)Al_(1.1)C_(1.8), and Ti_(3)SiC_(2)[J].Journal of Applied Physics,2000(4):1701-1703. |
[3] | Jeitschlo W;Nowotny H.Die kristallstructur von Ti3SiC2-Ein neuer komplexcarbid-typ[J].Monatshefte Fur Chemie,1967(98):329-337. |
[4] | Goto T;Hirai T.Chemically vapor deposited Ti3SiC2[J].Materials Research Bulletin,1987(22):1195. |
[5] | Pampuch R;Lis J;Stobierski L.Solid combustion synthesis of Ti3SiC2[J].Journal of the European Ceramic Society,1989(05):283. |
[6] | Pampuch R;Lis J;Piekarczyk J.Solid combustion synthesis of Ti3SiC2[J].Journal of Materials Synthesis and Processing,1993(01):93. |
[7] | Lis J;Miamoto Y;Pampuch R.Ti3SiC2-based materials by HIP-SHS techniques[J].Materials Letters,1995(22):163-168. |
[8] | Rudnik T;Lis J.The Ti3SiC2-based structural ceramics[J].ARCHIVES OF METALLURGY,1997(42):59. |
[9] | Barsoum MW.;Elraghy T. .SYNTHESIS AND CHARACTERIZATION OF A REMARKABLE CERAMIC - TI3SIC2[J].Journal of the American Ceramic Society,1996(7):1953-1956. |
[10] | EI-Raghy T;Barsoum M W .Processing and mechanical properties of Ti3SiC2: Ⅰ,reaction path and microstructure evolution[J].Journal of the American Ceramic Society,1999,82(10):2849-2854. |
[11] | EI-Raghy T;Barsoum M W;Zavaliangos A et al.Processing and mechanical properties of Ti3SiC2:Ⅱ,effect of grain size and deformation temperature[J].Journal of the American Ceramic Society,1999,82(10):2855-2860. |
[12] | Barsoum MW.;Ogbuji LUJT.;Elraghy T. .OXIDATION OF TI3SIC2 IN AIR[J].Journal of the Electrochemical Society,1997(7):2508-2516. |
[13] | Barsoum, M.W.;El-Raghy, T.;Rawn, C.J.;Porter, W.D.;Wang, H.;Payzant, E.A.;Hubbard, C.R. .Thermal properties of Ti_3SiC_2[J].The journal of physics and chemistry of solids,1999(4):429-439. |
[14] | Gao N F;Miyamoto Y;Zhang D.Dense Ti3SiC2:prepared by reactive HIP[J].Journal of Materials Science,1999(34):4358-4392. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%