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在化学共沉淀法制备细晶PSZ陶瓷的基础上,用工业ZrO2作原料,以MgO、Y2O3、CeO2及α-Al2O3作为复合稳定剂及添加剂,采用机械球磨混合法,并在制备过程中部分用去离子水代替乙醇作为球磨介质,探讨了水磨混合法制备粉料的可行性.实验结果表明:在较低的固溶烧结温度(1550℃)下,经1100℃适当时间热处理,亦可制备出具有较好力学性能的细晶PSZ陶瓷材料,其室温强度约700MPa,断裂韧性在15MPa·m1/2左右;在(180℃,1MPa)水热条件下,采用CeO2作复合稳定剂的PSZ陶瓷材料要比Y2O3复合稳定的PSZ材料更具良好的抗水化性.

Compared to fine-grained PSZ ceramics prepared by coprecipitation, the costabilized (Y, Mg)-PSZ and (Ce, Mg)-PSZ wigh MgAl2O4 spinel additions were developed, in
which industrial zirconia was used as the main starting material. Powders were prepared by mechanical milling-mixing process. During mixing process, distilled water was partially used as
ball-milling medium instead of ethanol. Feasibility for milling-mixing in distilled water was studied. The experimental results showed that fine-grained PSZ ceramics sintered at low solid
solution temperature (≤1550℃) could be achieved by mechanical mixing process, as well as coprecipitation. These materials had good mechanical properties: the flexural strength and
fracture toughness at room temperature were about 700MPa and 15MPa·m1/2, respectively. After hydrothermal treatment (180℃, 1MPa, in distilled water) up to 20h, (Ce, Mg)-PSZ materials
exhibited much better thermal stability than (Y, Mg)-PSZ ceramics.

参考文献

[1] 马亚鲁, 王树强, 谈家琪等. 硅酸盐学报, 1995, 23 (4): 495--500
2 马亚鲁, 张国亮, 王树强等. 硅酸盐学报, 1996, 24 (1): 38--44
3 Nettleship I, Stevens R. Int J Technology Ceramics, 1987, 3 (1): 1--5
4 Jone S L, Norman C J. J. Am. Ceram. Soc., 1988, 71 (4): c-190--c-191
5 马亚鲁. [博士论文], 天津大学研究生院, 1997年3月
6 Hernandez M T. J. Am. Ceram. Soc., 1991, 74 (4): 1254--1258
7 Swain M V. J. Mater. Sci. Lett., 1985, 4: 848--850
8 Hirano M. Br. Ceram. Trans. J., 1992, 91 (5): 139--147
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