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氮化硼纤维是继炭纤维和炭化硅纤维后广受关注的高性能无机纤维,在航空航天等领域已显示出重要应用前景.聚合物先驱体转化法是其有效的制备方法,合成性能优异的聚硼氮烷先驱体则是该方法的关键.文中介绍了近年来氮化硼纤维聚合物先驱体的最新研究成果,重点综述了先驱体的合成路线及性能,并展望了其未来的研究重点.

参考文献

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[7] Bernard S;Ayadi K;Berthet MP;Chassagneux F;Cornu D;Letoffe JM;Miele P .Evolution of structural features and mechanical properties during the conversion of poly[(methylamino)borazine] fibers into boron nitride fibers[J].International Journal of Quantum Chemistry,2004(6):1803-1810.
[8] Toury B.;Bernard S.;Cornu D.;Chassagneux F.;Letoffe JM.;Miele P. .High-performance boron nitride fibers obtained from asymmetric alkylaminoborazine[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2003(2):274-279.
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[10] Miele P;Toury B;Cornu D;Bernard S .Borylborazines as new precursors for boron nitride fibres[J].Journal of Organometallic Chemistry,2005(11):2809-2814.
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