借助计算机模拟剖析了Ni体积分数对Ni-A12O3太阳光谱选择性吸收薄膜光学性能的影响规律,并依据这一规律指导了以水溶胶一凝胶法制备的Ni-A12O3太阳光谱选择性吸收膜系的优化。模拟结果表明,以呈现类金属特征的基层Ni-A12O3薄膜与Ni体积分数不超过基层0.5倍且呈非金属特征的中间层薄膜组合,在其上再沉积一减反射顶层,如此3层复合可获得高吸收率和低发射率的太阳光谱选择性吸收膜系。依据这一规律指导的以水溶胶一凝胶法制备的Ni-A12O3膜系其吸收率高达0.93,发射率低至0.04,成为一个很好的太阳光选择性吸收表面。
The effect of the volume fraction of nickel on the optical properties of Ni-Alz 03 solar selective absorb- ing films was investigated by computer simulation. The knowledge obtained was used to guide the optimization of Ni-A12O3 coatings fabricated by aqueous sol-gel method. The results of theoretical simulation showed that the double absorbing coatings, of which consists of a base layer with metal-like character and a middle layer with volume fraction less than 0.5 times of the base layer, together with an anti-reflection top layer could pro- duce excellent optical absorption. Based on the principles, the optimized Ni-Al2O3 coatings were fabricated by aqueous sol-gel method, which attained a high solar absorptance of 0.94 and a low thermal emittance of 0.04.
参考文献
[1] | 赵剑曦;李镇祥 .一种用于制备太阳光热转换吸收薄膜的水溶胶[P].中国专利:201110109700.0,2011-0429. |
[2] | Li Zhenxiang;Zhao Jianxi;Ren Lihui .Aqueous solution- chemical derived Ni-A12 03 solar selective absorbing coat- ings[J].Solar Energy Materials and Solar Cells,2012,105:90-95. |
[3] | Li Zhenxiang;Zhao Jianxi .Progress in preparation of so- lar selective absorbing coatings by sol gel method[J].Journal of the Chinese Ceramic Society,2012,40(05):762-768. |
[4] | 蒋家兴,赵剑曦,廖新焕,李镇祥,姜蓉.溶胶-凝胶法制备Ni-Al2O3太阳光热转换吸收薄膜:过渡金属筛选和还原[J].功能材料,2009(10):1685-1687. |
[5] | Sathiaraj T S;Thangaraj R;Agnihotri O P .Ni A1203 cermet solar absorbers by RF planar magnetron sputtering for high temperature applications[J].Solar Energy Materials,1989,18(06):343-356. |
[6] | Yitzhak Mastai;Sebastian Polarz;Markus Antonietti .Silica-Carbon Nanocomposites-A New Concept for the Design of Solar Absorbers[J].Advanced functional materials,2002(3):197-202. |
[7] | Ritchie I T;Window B .Applications of thin graded-index films to solar absorbers[J].Applied Optics,1977,16(05):1438-1443. |
[8] | Harding G L .Alternative grading profile for sputtered solar selective surfaces[J].Journal of Vacuum Science and Technology,1979,16(06):2111-2113. |
[9] | Window B;Mckenzie D;Harding G .Selective absorber design[J].Sot Energy Mater,1980,2(04):395-401. |
[10] | Farooq M.;Hutchins MG. .A novel design in composities of various materials for solar selective coatings[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2002(4):523-535. |
[11] | Shen Yue;Shi Yueyan;Wang Fengchun .High-temper- at ure opticalproperties and stability of AIx Oy-A1N.-A1 solar selective absorbing surface prepared by DC magne tron reactive sputtering[J].Solar Energy Materials and Solar Cells,2003,77(04):393-403. |
[12] | Zhang Qichu;Mills D R .New cermet film structures with much improved selectivity for solar thermal appli- cations[J].Applied Physics Letters,1992,60(05):545-547. |
[13] | Zhang Qichu;Mills D R .High solar performance selec tive surface using bi sublayer cermet film structures[J].Solar Energy Materials and Solar Cells,1992,27(03):273-290. |
[14] | Bostrom T;Westin G;Wackelgard E .Optimization of a solution-chemically derived solar absorbing spectrally selective surface[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2007(1):38-43. |
[15] | Zhang Qichu;Hadavi M S;Lee K D et al.Zr-Zr02 cermet solar coatings designed by modelling calculations and deposited by DC magnetron sputtering[J].J PhysD:Appl Phys,2003,36(06):723-729. |
[16] | Zhao SX;Wackelgard E .Optimization of solar absorbing three-layer coatings[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2006(3):243-261. |
[17] | Bruggeman D A G .Calculation of various physics con- stants in heterogenous substances I dielectricity con- stants and conductivity of mixed bodies from isotropic substances[J].Ann Physic-Berlin,1935,24(07):636-664. |
[18] | Zhao Shuxi .Spectrally selective solar absorbing coatings prepared by DC magnetron sputtering[D].Uppsala:Uppsala University,2007. |
[19] | Heavens O S.Optical properties of thin solid films[M].New York:Dover Publications,Inc,1991 |
[20] | Bostrom TK;Wackelgard E .Optical properties of solution-chemically derived thin film Ni-Al2O3 composites and Si, Al and Si-Ti oxides[J].Journal of Physics. Condensed Matter,2006(32):7737-7750. |
[21] | Ribbing C G;Karlsson B .On the selection of oxides for metal-based tandem absorbers[J].Thin Solid Films,1984,116(04):341-349. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%