采用真空热压烧结法制备La2O3-TiC/W复合材料,并对其组织结构和力学性能进行了研究.结果表明:在一定成分范围内,La2O3和TiC的加入提高了复合材料的力学性能,La2O3和TiC共同作用时的强化效果强于La2O3和TiC单独作用的强化效果,但La2O3-TiC/W复合材料的密度和相对密度随TiC含量的增加而下降,并进而影响硬度和弹性模量的提高,适量的La2O3有益于相对密度的提高;抗弯强度在1%La2O3-5%TiC/W成分含量时出现最大值901 MPa,而断裂韧性在成分含量为0.5%La2O3-10%TiC/W时出现最大值10.07 MPa·m1/2.本研究中,1%La2O3-5%TiC/W成分配比时具有较好的综合力学性能.La2O3-TiC/W复合材料的强化机制为细晶强化和载荷传递,韧化机制为细晶韧化、裂纹偏转和桥接.
参考文献
[1] | Barabash V,Akiba M,Mazul I,et al.Selection,development and characterization of the plasma facing materials for ITER application[J].Journal of Nuclear Material,1998,233/237(Part 1):718-723. |
[2] | Tanabe T,Wada M,Ohgo T,Philipps V,et al.The TEXTOR team,application of tungsten for plasma limiters in TEXTOR[J].Journal of Nuclear Material,2000,283/287(Part 2):1128-1133. |
[3] | Song Guiming,Wang Yujin,Zhou Yu.The mechanical and thermalphysieal of ZrC/W composites at elevated temperature[J].Materials Science and Engineering A,2002,334(1/2):223-232. |
[4] | Song Guiming,Wang Yujin,Zhou Yu.Thermomechanical properties of TiC particle-reinforced tungsten composites for high temperature applications[J].International Journal of Refractory Metals & Hard Materials,2003,21(1/2):1-12. |
[5] | Mabuchi M,Okamoto K,Satio N,et al.Tensile properties at elevated temperature of W-1% La2O3[J].Materials Science and Engineering A,1996,214(1/2):174-176. |
[6] | Mabuchi M,Okamoto K,Satio N,et al.Deformation behavior and strengthening mechanisms at intermediate temperatures in W-La2O3[J].Materials Science and Engineering A,1997,237(2):241-249. |
[7] | 范景莲,汪凳龙,刘涛.细晶钨合金制备工艺的研究[J].兵器材料科学与工程,2006,29(2):1-5.Fan Jinglian,Wang Denglong,Liu Tao.Preparing process of finegrain tungsten alloy with high mechanical properties[J].Ordnance Material Science and Engineering,2006,29(2):1-5. |
[8] | 马运柱,黄伯云,熊翔.稀土钇对纳米粉90W-7Ni-3Fe合金烧结特性的影响[J].中国有色金属学报,2005,15(6):882-887.Ma Yunzhu,Huang Baiyun,Xiong Xiang.Influence of rare earth Y on sintering properties of nano-powder 90W-7Ni-3Fe alloy[J].The Chinese Journal of Nonferrous Metals,2005,15(6):882-887. |
[9] | Ryu H J,Hong S H.Fabrication and properties of mechanically alloyed oxide-dispersed tungsten heavy alloys[J].Materials Science and Engineering A,2003,363(1/2):179-184. |
[10] | 宋桂明,杨跃平,王玉金,等.TiC颗粒增强钨基复合材料的组织结构与力学性能[J].有色金属,2000,52(1):78-82.Song Guiming,Yang Yueping,Wang Yujin,et al.Microstrueture and properties of TiC particles-reinforced tungsten matrix composite[J].Nonferrous Metals,2000,52(1):78-82. |
[11] | 宋桂明,王玉金,周玉.等.TiC和ZrC颗粒增强钨基复合材料[J].固体火箭技术,1998,21(4):54-59.Song Guiming,Wang Yujin,Zhou Yu,et al.Tungsten matrix composites strengthened with TiC and ZrC particles at elevated temperature[J].Journal of Solid Rocket Technology,1998,21(4):54-59. |
[12] | 张长鑫,张新.稀土冶金原理与工艺[M].北京:冶金工业出版社,1997:109-128.Zhang Changxin,Zhang Xin.Rare earth metallurgical principle and process[M].Beijing:Metallurgical Industry Press,1997:109-128. |
[13] | 稀有金属手册编委会.稀有金属手册[M].北京:冶金工业出版社,1992:601-603.Editorial Board for Handbook of Rare Metals.Handbook ofrare metals[M].Beijing..Metallurgical Industry Press,1992:601-603. |
[14] | 崔岩,耿林,姚忠凯.轻微界面反应对SiCp/6061Al复合材料弹性模量的影响[J].复合材料学报,1998,15(1):74-77.Cui Yah,Geng Lin,Yao Zhongkai.Effect of slight interracial on the Young's modulus of SiCe/6061 composite[J].Acta Materiae Compositae Sinica,1998,15(1):74-77. |
[15] | 刘宁,胡镇华.崔昆.陶瓷相(TiC,W)C的价电子结构和力学性能的关系[J].硅酸盐学报,1997,25(4):420-426.Liu Ning,Hu Zhenhua,Cui Kun.Valence electron structure eigenproperties of (TIC,W)C ceramic phase[J].Journal of the Chinese Ceramic Society,1997,25(4):420-426. |
[16] | 陈剑锋,武高辉,孙东立.等.金属基复合材料的强化机制[J].航空材料学报,2002,22(2):49-53.Chen Jianfeng,Wu Gaohui,Sun Dongli,et al.Strengthening mechanisms of metal matrix composites[J].Journal of Aeronautical Materials,2002,22(2):49-53. |
[17] | 周玉,宋桂明,王玉金,等.TiCP/w复合材料的断裂行为[J].中国有色金属学报,1999,9(增刊1):158-165.Zhou Yu,Song Guiming,Wang Yujin,et al.Fracture behavior of TiCp/W composites[J].The Chinese Journal of Nonferrous Metals,1999,9(Suppl 1):158-165. |
[18] | 郑茂盛,赵更申,井新利,等.关于颗粒增强金属基复合材料的协同强化[J].稀有金属材料与工程,1996,25(5):16-17.Zheng Maosheng,Zhao Gengshen,Jing Xinli,et al.The coordinate strengthening on metal-matrix strengthened by particles[J].Rare Metals Materials and Engineering,1996,25(5):16-17. |
[19] | 权高峰,柴东朗,宋余九,涂铭旌.复合材料中增强粒子与基体中微观应力与残余应力分析[J].复合材料学报,1995,12(3):70-75.Quan Gaofeng,Chai Donglang,Song Yujiu,Tu Mingjing.Analyses of thermal residual microstresses in particle and matrix composites[J].Acta Materiae Compositae Sinica,1995,12(3):70-75. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%