采用水热法在各种衬底上低温、一步合成出一维有序ZnO单晶纳米棒阵列.以透明导电玻璃(ITO)、聚对苯二甲酸乙二醇酯(PET)以及铜作为衬底时,必须预先沉积一层ZnO薄膜作为形核层才能获得ZnO纳米棒阵列.然而,以黄铜作为衬底时,无需形核层也能获得纳米棒阵列.采用SEM、XRD、紫外吸收光谱等方法对纳米棒的结构以及形貌等进行了表征.此外还发现ZnO纳米棒阵列具有很好的紫外光催化活性,3h内对亚甲基蓝的降解率达到53%.尽管修饰CdSe层有助于提高ZnO纳米棒阵列在可见光波段的吸收,但其紫外光催化活性反而降低.并具体讨论了ZnO纳米棒阵列的合成与光催化性能.
参考文献
[1] | Tsukazaki A;Ohtomo A;Onuma T et al.Repeated temperature modulation epitaxy for p-type doping and lightemitting diode based on ZnO[J].Nature Materials,2005,4:42. |
[2] | Yungryel Ryu;Tae-Seok Lee;Jorge A. Lubguban;Henry W. White;Bong-Jin Kim;Yoon-Soo Park;Chang-Joo Youn .Next generation of oxide photonic devices: ZnO-based ultraviolet light emitting diodes[J].Applied physics letters,2006(24):241108-1-241108-3-0. |
[3] | Zhu H;Shan C X;Yao B et al.Ultralow-threshold laser realized in zinc oxide[J].Advanced Materials,2009,21(16):1. |
[4] | W. Z. Xu;Z. Z. Ye;Y. J. Zeng;L. P. Zhu;B. H. Zhao;L. Jiang;J. G. Lu;H. P. He;S. B. Zhang .ZnO light-emitting diode grown by plasma-assisted metal organic chemical vapor deposition[J].Applied physics letters,2006(17):173506-1-173506-3-0. |
[5] | Zhang Z;Yuan H;Zhou J et al.Growth mechanism,photoluminescence,and field-emission properties of ZnO nanoneedle arrays[J].Journal of Physical Chemistry B,2006,110(17):8566. |
[6] | Liao L;Lu HB;Shuai M;Li JC;Liu YL;Liu C;Shen ZX;Yu T .A novel gas sensor based on field ionization from ZnO nanowires: moderate working voltage and high stability[J].Nanotechnology,2008(17):175501-1-175501-5-0. |
[7] | Law M;Greene LE;Johnson JC;Saykally R;Yang PD .Nanowire dye-sensitized solar cells[J].Nature materials,2005(6):455-459. |
[8] | Lee YJ;Ruby DS;Peters DW;McKenzie BB;Hsu JWP .ZnO nanostructures as efficient antireflection layers in solar cells[J].Nano letters,2008(5):1501-1505. |
[9] | 滕洪辉,徐淑坤,王猛.微乳液法合成不同维度氧化锌纳米材料及其光催化活性[J].无机材料学报,2010(10):1034-1040. |
[10] | Zha MZ;Calestani D;Zappettini A;Mosca R;Mazzera M;Lazzarini L;Zanotti L .Large-area self-catalysed and selective growth of ZnO nanowires[J].Nanotechnology,2008(32):325603-1-325603-5-0. |
[11] | Huo KF;Hu YM;Fu JJ;Wang XB;Chu PK;Hu Z;Chen Y .Direct and large-area growth of one-dimensional ZnO nanostructures from and on a brass substrate[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(16):5876-5881. |
[12] | Martinson ABF;Elam JW;Hupp JT;Pellin MJ .ZnO nanotube based dye-sensitized solar cells ZnO nanotube based dye-sensitized solar cells[J].Nano letters,2007(8):2183-2187. |
[13] | Vayssieres L .Growth of arrayed nanorods and nanowires of ZnO from aqueous solutions[J].Advanced Materials,2003,15(05):464. |
[14] | Honda K;Fujishima A .Electrochemical photolysis of water at a semiconductor electrode[J].Nature,1972,238:37. |
[15] | KE DAI;TIANYOU PENG;HAO CHEN .Photocatalytic Degradation of Commercial Phoxim over La-Doped TiO2 Nanoparticles in Aqueous Suspension[J].Environmental Science & Technology: ES&T,2009(5):1540-1545. |
[16] | Michael R. Hoffmann;Scot T. Martin;Wonyong Choi;Detlef W. Bahnemann .Environmental Applications of Semiconductor Photocatalysis[J].Chemical Reviews,1995(1):69-96. |
[17] | Hariharan C .Photocatalytic degradation of organic contaminants in water by ZnO nanoparticles: Revisited[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2006(1):55-61. |
[18] | N.Daneshvar;S.Aber;M.S.Seyed Dorraji .Photocatalytic degradation of the insecticide diazinon in the presence of prepared nanocrystalline ZnO powders under irradiation of UV-C light[J].Separation and Purification Technology,2007(1):91-98. |
[19] | 孙岚,李静,庄惠芳,赖跃坤,王成林,林昌健.TiO2纳米管阵列的制备、改性及其应用研究进展[J].无机化学学报,2007(11):1841-1850. |
[20] | Delgado, GT;Romero, CIZ;Hernandez, SAM;Perez, RC;Angel, OZ .Optical and structural properties of the sol-gel-prepared ZnO thin films and their effect on the photocatalytic activity[J].Solar Energy Materials and Solar Cells,2009(1):55-59. |
[21] | Karunakaran C;Senthilvelan S .Fe2O3-photocatalysis with sunlight and UV light:Oxidation of aniline[J].Electrochemistry Communications,2006,8(01):95. |
[22] | Guo YF;Quan X;Lu N;Zhao HM;Chen S .High photocatalytic capability of self-assembled nanoporous WO3 with preferential orientation of (002) planes[J].Environmental Science & Technology: ES&T,2007(12):4422-4427. |
[23] | Kumar, PSS;Raj, MR;Anandan, S;Zhou, MF;Ashokkumar, M .Visible light assisted photocatalytic degradation of acid red 88 using Au-ZnO nanophotocatalysts[J].Water Science and Technology,2009(6):1589-1596. |
[24] | Zeng H;Liu P;Cai W et al.Controllable Pt/ZnO porous nanocages with improved photocatalytic activity[J].Journal of Physical Chemistry C,2008,112(49):19620. |
[25] | Yuanhui Zheng;Lirong Zheng;Yingying Zhan .Ag/ZnO Heterostructure Nanocrystals:Synthesis,Characterization,and Photocatalysis[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2007(17):6980-6986. |
[26] | Youngjo Tak;Hyeyoung Kim;Dongwook.Type-Ⅱ CdS nanoparticle-ZnO nanowire heterostructure arrays fabricated by a solution process:Enhanced photocatalytic activity[J].Chemical Communications,2008(38):4585. |
[27] | Preparation of ZnO/Cu_2O compound photocatalyst and application in treating organic dyes[J].Journal of hazardous materials,2010(1/3):807. |
[28] | Smith W;Zhao Y .Enhanced photocatalytic activity by aligned WO3/TiO2 two-layer nanorod arrays[J].Journal of Physical Chemistry C,2008,112(49):19635. |
[29] | Yuh-Lang Lee;Yi-Siou Lo .Highly Efficient Quantum-dot-sensitized Solar Cell Based On Co-sensitization Of Cds/cdse[J].Advanced functional materials,2009(4):604-609. |
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