采用微弧氧化技术在TiNbZrFe合金表面制备出含钙磷成分的多孔氧化膜,通过人体模拟液浸泡的方法诱导生成羟基磷灰石,并利用电化学阻抗谱(EIS)研究其在人体模拟液中浸泡不同时间后的耐腐蚀性能.结果表明,经400 V电压微弧氧化后TiNbZrFe合金表面氧化膜的形貌与成分达到最优化,且明显有α-Ca3(PO4)2相生成;α-Ca3 (PO4)2相能够起到良好的诱导生成羟基磷灰石(HA)的作用,在人体模拟液中浸泡ld后,通过XRD检测出有HA相生成,导致微弧氧化膜层表面的微孔被诱导生成物覆盖填充明显,较小微孔完全消失;随着浸泡时间的延长,经过微弧氧化膜诱导生成的HA涂层不断增厚,EIS结果表明其具有良好的隔绝渗透作用,能够阻碍腐蚀性介质在溶液和金属界面之间扩散和迁移,从而起到保护基体抗腐蚀的作用.
参考文献
| [1] | Wu, GM;Hsiao, WD;Kung, SF .Investigation of hydroxyapatite coated polyether ether ketone composites by gas plasma sprays[J].Surface & Coatings Technology,2009(17/18):2755-2758. |
| [2] | Huang, J.-C.;Ni, Y.-J.;Wang, Z.-C. .Preparation of hydroxyapatite functionally gradient coating on titanium substrate using a combination of electrophoretic deposition and reaction bonding process[J].Surface & Coatings Technology,2010(21/22):3387-3392. |
| [3] | Ping Huang;Fei Wang;Kewei Xu;Yong Han .Mechanical properties of titania prepared by plasma electrolytic oxidation at different voltages[J].Surface & Coatings Technology,2007(9/11):5168-5171. |
| [4] | Shi, X.;Xu, L.;Wang, Q. .Porous TiO_2 film prepared by micro-arc oxidation and its electrochemical behaviors in Hank's solution[J].Surface & Coatings Technology,2010(6):1730-1735. |
| [5] | Song WH.;Jun YK.;Han Y.;Hong SH. .Biomimetic apatite coatings on micro-arc oxidized titania[J].Biomaterials,2004(17):3341-3349. |
| [6] | Yao ZQ;Ivanisenko Y;Diemant T;Caron A;Chuvilin A;Jiang JZ;Valiev RZ;Qi M;Fecht HJ .Synthesis and properties of hydroxyapatite-containing porous titania coating on ultrafine-grained titanium by micro-arc oxidation.[J].Acta biomaterialia,2010(7):2816-2825. |
| [7] | Kokubo T;Takadama H .How useful is SBF in predicting in vivo bone bioactivity?[J].Biomaterials,2006(15):2907-2915. |
| [8] | 王庆良,葛世荣,史兴岭.钛合金微弧氧化陶瓷层的结构研究[J].中国矿业大学学报,2008(04):462-466. |
| [9] | 李利群,袭建军,姚英学.钛合金微弧氧化技术的研究[J].焊接,2008(05):15-18. |
| [10] | 余森,于振涛,Gui WANG,韩建业,麻西群,Matthew S.DARGUSCH.Ti-3Zr-2Sn-3Mo-25Nb 合金表面活性微弧氧化膜的制备及其骨诱导性[J].中国有色金属学报（英文版）,2011(03):573-580. |
| [11] | Han Y.;Hong SH.;Xu KW. .Structure and in vitro bioactivity of titania-based films by micro-arc oxidation[J].Surface & Coatings Technology,2003(2/3):249-258. |
| [12] | da Silva MHP.;Lemos AF.;Gibson IR.;Ferreira JMF.;Santos JD. .Porous glass reinforced hydroxyapatite materials produced with different organic additives[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2002(1/3):286-292. |
| [13] | 宋宏杰,梁星,骆筱秋,陈明,孙惠强.α-磷酸三钙骨水泥修复骨缺损及其降解物诱导成骨的实验研究[J].四川大学学报（医学版）,2005(06):847-849,869. |
| [14] | Montemor MF;Trabelsi W;Zheludevich M;Ferreira MGS .Modification of bis-silane solutions with rare-earth cations for improved corrosion protection of galvanized steel substrates[J].Progress in Organic Coatings: An International Review Journal,2006(1):67-77. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%