首先介绍了氧化钨薄膜的气致变色效应及其潜在的应用,然后概述了氧化钨气致变色机理的双注入模型和氧空位扩散模型及其存在的争议性问题,并在此基础上介绍了由本研究组发展的气致变色结构水分子模型.最后,指出氧化钨薄膜气致变色机理的研究工作不仅有助于人们更好地理解薄膜材料的变色效应,有效地提高变色器件的性能,同时也能推动相关学科(如氢的储存、氢的探测、离子传输材料以及半导体表面催化等学科)的发展.
参考文献
| [1] | Leftheriotis G;Papaefthimiou S;Yianoulis P et al.Effect of the tungsten oxidation states in the thermal coloration and bleaching of amorphous WO3 films[J].Thin Solid Films,2001,384(02):298. |
| [2] | Zhao Y;Feng Z C;Liang Y et al.Laser-induced coloration of WO3[J].Applied Physics Letters,1997,71(16):2227. |
| [3] | Azens A;Avendano E et al.Flexible electrochromic foils:Science,technology and application[J].Proc SPIE A,2005,5946:59461. |
| [4] | C. G. Granqvist;A. Azens;A. Hjelm;L. Kullman;G. A. Niklasson;D. Ronnow;M. S. Mattsson;M. Veszelei;G. Vaivars .Recent advances in electrochromics for smart windows applications[J].Solar Energy,1998(4):199-216. |
| [5] | Deb SK .Opportunities and challenges in science and technology of WO3 for electrochromic and related applications[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2008(2):245-258. |
| [6] | Zayat M;Reisfeld R;Minti H et al.Gasochromic effect inplatinum-doped tungsten trioxide films prepared by the solgel method[J].Journal of Sol-Gel Science and Technology,1998,11(02):161. |
| [7] | Orel B.;Krasovec UO.;Gabrscek M.;Bukovec P.;Reisfeld R.;Groselj N. .Gasochromic effect of palladium doped peroxopolytungstic acid films prepared by the sol-gel route[J].Sensors and Actuators, B. Chemical,1998(3):234-245. |
| [8] | Wittwer V;Datz M;Ell I;Georg A;Graf W;Walze G .Gasochromic windows[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2004(1/4):305-314. |
| [9] | Granqvist CG. .Electrochromic tungsten oxide films: Review of progress 1993-1998 [Review][J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2000(3):201-262. |
| [10] | Yong Shin Kim;Seung-Chul Ha;Kyuwon Kim;Haesik Yang;Sung-Yool Choi;Youn Tae Kim;Joon T. Park;Chang Hoon Lee;Jiyoung Choi;Jungsun Paek;Kwangyeol Lee .Room-temperature semiconductor gas sensor based on nonstoichiometric tungsten oxide nanorod film[J].Applied physics letters,2005(21):213105.1-213105.3. |
| [11] | Zhang, X.;Lu, X.;Shen, Y.;Han, J.;Yuan, L.;Gong, L.;Xu, Z.;Bai, X.;Wei, M.;Tong, Y.;Gao, Y.;Chen, J.;Zhou, J.;Wang, Z.L. .Three-dimensional WO_3 nanostructures on carbon paper: Photoelectrochemical property and visible light driven photocatalysis[J].Chemical communications,2011(20):5804-5806. |
| [12] | Zhi-Gang Zhao;Masahiro Miyauchi .Nanoporous-Walled Tungsten Oxide Nanotubes as Highly Active Visible-Light-Driven Photocatalysts[J].Angewandte Chemie,2008(37):7051-7055. |
| [13] | Abe R;Takami H;Murakami N;Ohtani B .Pristine simple oxides as visible light driven photocatalysts: Highly efficient decomposition of organic compounds over platinum-loaded tungsten oxide[J].Journal of the American Chemical Society,2008(25):7780-7781. |
| [14] | Gr(a)tzel M .Photoelectrochemical cells[J].Nature,2001,414:338. |
| [15] | Carcenac F;Vieu C et al.High voltage electron beam nanolithography on WO3[J].Journal of Vacuum Science and Technology B:Microelectronics and Nanometer Structures,1996,14(06):4283. |
| [16] | Xu X Q;Shen H;Xiong X Y .Gasochromic effect of sol-gel WO3-SiO2 films with evaporated platinum catalyst[J].Thin Solid Films,2002,415(01):290. |
| [17] | Shanak H;Schmitt H;Nowoczin J;Ziebert C .Effect of Pt-catalyst on gasochromic WO3 films: optical, electrical and AFM investigations[J].Solid state ionics,2004(1/2):99-106. |
| [18] | Shimizu K;Chinzei I;Nishiyama H;Kakimoto S;Sugaya S;Yokoi H;Satsuma A .Hydrogen sensor based on WO3 subnano-clusters and Pt co-loaded on ZrO2[J].Sensors and Actuators, B. Chemical,2008(2):618-624. |
| [19] | Ando M;Chabicovsky R;Haruta M .Optical hydrogen sensitivity of noble metal-tungsten oxide composite films prepared by sputtering deposition[J].Sensors and Actuators B:Chemical,2001,76(01):13. |
| [20] | Cheong H;Jo C H;Kim K M .Hydrogen sensors based on gasochromic oxide thin films[J].Journal of the Korean Physical Society,2005,46(S):121. |
| [21] | Maciak E;Opilski Z;Urbanczyk M .Optical hydrogen sensitivity of Pd-metal oxide composite films prepared on fiber optics[J].Proc SPIE R,2005,5952:59521. |
| [22] | Sunmida S;Okazaki S et al.Distributed hydrogen determi nation with fiber-optic sensor[J].Sensors and Actuators B:Chemical,2005,108(01):508. |
| [23] | Sekimoto S.;Okazaki S.;Fukuda K.;Asakura S.;Shigemori T. Takahashi S.;Nakagawa H. .A fiber-optic evanescent-wave hydrogen gas sensor using palladium-supported tungsten oxide[J].Sensors and Actuators, B. Chemical,2000(1/3):142-145. |
| [24] | Maciak E;Opilski Z .Transition metal oxides covered Pd film for optical H-2 gas detection[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2007(23):8351-8355. |
| [25] | Faughnan B W;Crandall R S et al.Electrochromism in WO3 amorphous films[J].RCA Review,1975,36:177. |
| [26] | 罗坚义 .氧化钨纳米线薄膜的光学特性的基础研究[D].中山大学,2009. |
| [27] | Lee SH.;Liu P.;Smith D.;Tracy CE.;Mascanrenhas A.;Pitts JR.;Deb SK.;Cheong HM. .Gasochromic mechanism in a-WO3 thin films based on Raman spectroscopic studies[J].Journal of Applied Physics,2000(5):3076-3078. |
| [28] | Lee S H;Cheong H M et al.Raman spectroscopic studies of gasochromic a-WO3 thin films[J].Electrochimica Acta,2001,46(13):1995. |
| [29] | Chen HJ;Xu NS;Deng SZ;Lu DY;Li ZL;Zhou J;Chen J .Gasochromic effect and relative mechanism of WO3 nanowire films[J].Nanotechnology,2007(20):5701-1-5701-6-0. |
| [30] | Gerard P;Deneuville A;Courths R .Characterization of aWO3 thin films before and after colouration[J].Thin Solid Films,1980,71(02):221. |
| [31] | Wagner W;Rauch F;Ottermann et al.Hydrogen dynamics in electrochromic multilayer systems investigated by 15N technique[J].Nuclear Instrum Methods Phys Res Sec B,1990,50(01):27. |
| [32] | Georg A.;Neumann R.;Wittwer V.;Graf W. .Mechanism of the gasochromic coloration of porous WO3 films[J].Solid state ionics,2000(3/4):319-328. |
| [33] | Luo J Y;Deng S Z et al.Evidence of localized water molecules and their role in the gasochromic effect of WO3 nanowire films[J].Journal of Physical Chemistry C,2009,113(36):15877. |
| [34] | Zhu, L.F.;She, J.C.;Luo, J.Y.;Deng, S.Z.;Chen, J.;Ji, X.W.;Xu, N.S. .Self-heated hydrogen gas sensors based on Pt-coated W_(18)O _(49) nanowire networks with high sensitivity, good selectivity and low power consumption[J].Sensors and Actuators, B. Chemical,2011(2):354-360. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%