以咔唑、菲醌等为原料合成了三种菲并咪唑类有机小分子3a、3b和3c,并研究了其光谱、电化学和热稳定性.结果表明,化合物3a、3b和3c在二氯甲烷稀溶液中属于近紫外发射,而在薄膜状态下发出蓝色荧光;循环伏安法检测表明,3a、3b和3c的HOMO能级均在-5.88～-5.99eV之间,与阳极ITO的能级相匹配,LUMO能级均在-2.64～-2.77eV之间,接近于常用的电子输入材料PBD(-2.82eV),因此这三种化合物同时具有空穴传导和电子传导的双极性质;3a、3b和3c的热分解温度均在300℃以上,热稳定性优良.综上所述,3a、3b和3c是一类具有潜在应用前景的新型双极发光材料.
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