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采用共沉淀法制备了苯甲酸根插层纳米水滑石。借助红外光谱、X 射线衍射、热分析和高分辨透射电镜等表征手段对其进行了表征。结果表明,随着苯甲酸根插入镁铝水滑石层间,水滑石层间距有所增大,但仍具有完整的层状结构,同时,该材料的热稳定性也得到显著提高,具有潜在的应用价值。

The benzoic acid root intercalated into the nano MgAl-benzoic acid-LDH ( Layered Double Hydrox-ides) was synthesized using the co-precipitation method. The sample had been characterized by Fourier Trans-form Infrared (FT-IR) spectroscopy,X-Ray Diffraction (XRD),Thermogravimetry (TG) and High Resolution Transmission Electron Microscopy ( HRTEM). With benzoic acid into hydrotalcite interlayer,the results showed that hydrotalcite spacing increased,but it still had a complete lamellar structure. Also,the thermal stability of the MgAl-benzoic acid-LDH was remarkably improved,compared with that of MgAl-LDH,which has the potential ap-plication value.

参考文献

[1] Ferry Winter;Xinyu Xia;Bart P.C.Hereijgers;Johannes H.Bitter;A.Jos van Dillen.On the Nature and Accessibility of the Bronsted-Base Sites in Activated Hydrotalcite Catalysts[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,200618(18):9211-9218.
[2] LIU;Chun-Xia;HOU;Wan-Guo;LI;Yan;LI;Li-Fang.Synthesis and Characterization of Camptothecin Intercalated into Mg/AI Layered Double Hydroxide[J].中国化学(英文版),2008(10):1806-1810.
[3] Mohd Zobir bin Hussein;Tan Kim Hwa.Synthesis and properties of layered organic-inorganic hybrid material: Zn-Al layered double hydroxide-dioctyl sulfosuccinate nanocomposite[J].Journal of nanoparticle research: An interdisciplinary forum for nanoscale science and technology,20003(3):293-298.
[4] 赵维;李玉红;王贤.纳米铜-镁-铝类水滑石的制备与表征[J].无机盐工业,2010(1):57-59.
[5] Honk Chen;Wen-Gong Zhang.A Strong-Fluorescent Tb-Containing Hydrotalcite-Like Compound[J].Journal of the American Ceramic Society,20108(8):2305-2310.
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