石墨烯由于具有优异的导电性、高的比表面积、好的生物相容性,受到各界广泛关注.本文利用肼化学还原法得到比表面积为535m2/g的石墨烯,利用此石墨烯修饰碳布(GNS-anode)作为微生物燃料电池阳极,并与多壁碳纳米管修饰的阳极(MWCNT-anode)和未修饰的碳布(CC-anode)进行了详细的比较.碳纳米管和石墨烯的形貌和特性采用SEM、BET、TEM、XRD表征.电极的电化学性质利用循环伏安法(CV)和交流阻抗谱(EIS)衡量.装配GNS-anode运行的微生物燃料电池获得的最大功率密度为652 mW/m2,分别是MWCNT-anode和CC-anode的1.4倍和2.0倍,表明石墨烯能够提高微生物燃料电池(MFC)阳极性能,从而提高MFC功率输出.
参考文献
[1] | Logan BE;Hamelers B;Rozendal R;Schrorder U;Keller J;Freguia S;Aelterman P;Verstraete W;Rabaey K .Microbial fuel cells: Methodology and technology[J].Environmental Science & Technology: ES&T,2006(17):5181-5192. |
[2] | Min Sun;Guo-Ping Sheng;Zhe-Xuan Mu;Xian-Wei Liu;Yong-Zhen Chen;Hua-Lin Wang;Han-Qing Yu .Manipulating the hydrogen production from acetate in a microbial electrolysis cell-microbial fuel cell-coupled system[J].Journal of Power Sources,2009(2):338-343. |
[3] | Wei, J.;Liang, P.;Huang, X. .Recent progress in electrodes for microbial fuel cells[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2011(20):9335-9344. |
[4] | MinghuaZhou;MeilingChi;Jianmei Luo;HuanhuanHe;TaoJin .An overview of electrode materials in microbial fuel cells[J].Journal of Power Sources,2011(10):4427-4435. |
[5] | Mei-xian Wang;Qi Liu;Hong-fang Sun .Preparation of high-surface-area carbon nanoparticle/ graphene composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,2012(10):3845-3853. |
[6] | YezhenZhang;GuangquanMo;Xuwen Li;WeideZhang;JiaqiZhang;Jianshan Ye;Xiaodan Huang;Chengzhong Yu .A graphene modified anode to improve the performance of microbial fuel cells[J].Journal of Power Sources,2011(13):5402-5407. |
[7] | Liu, J.;Qiao, Y.;Guo, C.X.;Lim, S.;Song, H.;Li, C.M. .Graphene/carbon cloth anode for high-performance mediatorless microbial fuel cells[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2012(1):275-280. |
[8] | Li D;Muller MB;Gilje S;Kaner RB;Wallace GG .Processable aqueous dispersions of graphene nanosheets[J].Nature nanotechnology,2008(2):101-105. |
[9] | Wang GX;Yang J;Park J;Gou XL;Wang B;Liu H;Yao J .Facile synthesis and characterization of graphene nanosheets[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(22):8192-8195. |
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