本文以甲基丙烯酸(MAA)、甲基丙烯酸甲酯(MMA)、甲基丙烯酸全氟烷基乙基酯(FEMA)为单体,采用可逆加成-断裂链转移聚合法(RAFT),合成了含氟嵌段共聚物P(MMA-co-MAA)-b-PFEMA,并通过红外光谱、核磁共振、GPC等对产物结构进行了表征.同时还以甲苯、四氢呋喃(THF)、三氟甲苯(BTF)、三氟三氯(F113)乙烷为成膜溶剂制备了聚合物膜,研究了溶剂对膜表面结构和疏水性能的影响,其中甲苯所成膜的疏水性能最优,其接触角高达152.5°.
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