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选用含量相同的六种不同粘土(煅烧高岭土、蒙脱土、凹凸棒土、膨润土、海泡石和硅藻土),采用反相悬浮法制备了一系列聚(丙烯酸/丙烯酰胺/粘土)高吸水树脂,并比较了不同粘土对高吸水树脂结构、吸水倍率、吸盐水倍率以及保水性能、热稳定性的影响。通过比较发现,添加膨润土的高吸水树脂具有最高的吸水倍率(450 g/g)和吸盐水倍率(92 g/g);添加膨润土和煅烧高岭土均可提高高吸水树脂的保水性能。此外,煅烧高岭土可以更为有效地提高高吸水树脂的热稳定性。

A series of poly(acrylic acid/acrylamide/clay) superabsorbents with 10% different kinds clay,which including calcined kaolin,montmorillonite,attapulgite,bentonite,sepiolite and diatomite,were prepared by inverse suspension polymerization method.The effects of clay kinds on structure,equilibrium water absorbency,equilibrium 0.9% NaCl absorbency,the water-retention capability and thermal stability of the superabsorbent composites were also systematically investigated in the same condition.It is found that the superabsorbent incorporated with bentonite has the best equilibrium water absorbency(450 g/g) and equilibrium 0.9% NaCl absorbency(92 g/g).Moreover,bentonite and calcined kaolin ones show the best capability of maintenancewater.Besides,the calcined kaolin can enhance the thermal stability of corresponding superabsorbent to the highest degree.

参考文献

[1] Wu JH;Zhong JF;Lin JM;Wei YL;Xie YM .Swelling behavior of poly(sodium aicrylate)/kaoline superabsorbent composite[J].Polymer engineering and science,2006(3):324-328.
[2] Kun Xu;Jihua Wang;Sheng Xiang;Qiang Chen;Wende Zhang;Pixin Wang .Study on the synthesis and performance of hydrogels with ionic monomers and montmorillonite[J].Applied clay science,2007(1/2):139-145.
[3] Junping Zhang;Ruifeng Liu;An Li;Aiqin Wang .Preparation, swelling behaviors and application of polyacrylamide/attapulgite superabsorbent composites[J].Polymers for advanced technologies,2006(1):12-19.
[4] Daungtawan Foungfung;Siriwan Phattanarudee;Nispa Seetapan;Suda Kiatkamjornwong .Acrylamide-itaconic acid superabsorbent polymers and superabsorbent polymer/mica nanocomposites[J].Polymers for advanced technologies,2011(5):635-647.
[5] Santiago F;Mucientes AE;Osorio M;Rivera C .Preparation of composites and nanocomposites based on bentonite and poly(sodium acrylate). Effect of amount of bentonite on the swelling behaviour[J].European Polymer Journal,2007(1):1-9.
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