以离子液体[MEIM]+[ES]-为晶体生长调控剂,采用简便的电化学方法合成了特定形貌的氢氧化镁纳米结构薄膜.对影响电沉积氢氧化镁薄膜的合成参数(如离子液体的含量、沉积电位和沉积时间)进行了研究,并分别用电镜、X射线衍射和热分析技术对所得氢氧化镁薄膜的形貌和热稳定性进行了表征.此外,该电化学过程可望推广到制备其它形貌独特和性能奇特的纳米/介观结构.
参考文献
| [1] | Seddon KR .Ionic liquids for clean technology[J].Journal of Chemical Technology & Biotechnology,1997(4):351-356. |
| [2] | Markus Antonietti;Daibin kuang;Bernd Smarsly;Yong Zhou .Ionic Liquids for the Convenient Synthesis of Functional Nanoparticles and Other Inorganic Nanostructures[J].Angewandte Chemie,2004(38):4988-4992. |
| [3] | Nakashima T;Kimizuka N .Interfacial synthesis of hollow TiO2 microspheres in ionic liquids[J].Journal of the American Chemical Society,2003,125(21):6386. |
| [4] | Ying-Jie Zhu;Wei-Wei Wang;Rui-Juan Qi;Xian-Luo Hu .Microwave-Assisted Synthesis of Single-Crystalline Tellurium Nanorods and Nanowires in Ionic Liquids[J].Angewandte Chemie,2004(11):1410-1414. |
| [5] | Yong Zhou;Jan H. Schattka;Markus Antonietti .Room-Temperature Ionic Liquids as Template to Monolithic Mesoporous Silica with Wormlike Pores via a Sol-Gel Nanocasting Technique[J].Nano letters,2004(3):477-481. |
| [6] | S. Zein El Abedin;N. Borissenko;F. Endres .Electrodeposition of nanoscale silicon in a room temperature ionic liquid[J].Electrochemistry communications,2004(5):510-514. |
| [7] | Andrew P.Abbott;Katy J.McKenzie .Application of ionic liquids to the electrodeposition of metals[J].Physical chemistry chemical physics: PCCP,2006(37):4265-4279. |
| [8] | Sherif Zein El Abedin;Frank Endres .Electrodeposition of Metals and Semiconductors in Air-and Water-Stable Ionic Liquids[J].Chemphyschem: A European journal of chemical physics and physical chemistry,2006(1):58-61. |
| [9] | Mei-Chen Lin;Po-Yu Chen;I-Wen Sun .Electrodeposition of Zinc Telluride from a Zinc Chloride-1-Ethyl-3-methylimidazolium Chloride Molten Salt[J].Journal of the Electrochemical Society,2001(10):C653-C658. |
| [10] | Li H;Liu R;Zhao RX;Zheng YF;Chen WX;Xu ZD .Morphology control of electrodeposited Cu2O crystals in aqueous solutions using room temperature hydrophilic ionic liquids[J].Crystal growth & design,2006(12):2795-2798. |
| [11] | Lieth R M A.Preparation and crystal growth of materials with layered structures[A].Holland:Reidel Publishing Company,1977:71. |
| [12] | Tan YW;Steinmiller EMP;Choi KS .Electrochemical tailoring of lamellar-structured ZnO films by interfacial surfactant templating[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(21):9618-9624. |
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