镍系锂离子电池正极材料的合成工艺及改性研究

材料导报, 2006, 20(5): 92-96.

镍系锂离子电池正极材料的合成工艺及改性研究

常照荣 ^1, , 齐霞 ^2, , 吴锋 ^3, , 孙东 ^4, , 苗旺 ^5,

1.河南师范大学化学与环境科学学院,新乡,453007;北京理工大学化工与环境学院,北京,100080

2.河南师范大学化学与环境科学学院,新乡,453007

3.北京理工大学化工与环境学院,北京,100080

4.河南师范大学化学与环境科学学院,新乡,453007

5.河南师范大学化学与环境科学学院,新乡,453007

基金项目: 中国科学院资助项目(90206043)

关键词：锂离子电池 , 正极材料 , LiNiO2 , 合成方法 , 掺杂 , 表面修饰

Research on the Synthetic Technics and Modification of the Nickel-based Cathode Materials for Lithium Ion Battery

通过分析镍系锂离子电池正极材料LiNiO2的结构特点和现阶段存在的问题,综述了近几年从合成方法和元素掺杂、表面修饰方面对镍系正极材料进行研究的概况,并从实用化角度讨论了其发展的方向.

参考文献

[1]	Obrovac MN.;Dahn JR.;Mao O. .Structure and electrochemistry of LiMO2, (M = Ti, Mn, Fe, Co, Ni) prepared by mechanochemical synthesis[J].Solid state ionics,1998(1/2):9-19.
[2]	Wulff H.;Rao MM.;Scholz F. .Crystallographic evidence for the formation of a continuous series of mixed crystals between NiO and LiNiO2[J].Chemistry of Materials,2003(4):988-993.
[3]	Delmas C;Pérès J P;Rougier A et al.On the behavior of the LixNiO2 system:an electrochemical and structural overview[J].Journal of Power Sources,1997,68(01):120.
[4]	Kanno R;Kubo H;Kawamoto Y et al.Phase relationship and lithium deintercalation in lithium nickel oxide[J].Journal of Solid State Chemistry,1994,110(02):216.
[5]	Lee K K;Yoon W S;Kim K B et al.Thermal behavior and the decomposition mechanism of electrochemically delithiated Li1-xNiO2[J].Journal of Power Sources,2001,97-98:321.
[6]	Arai H;Sakurai Y .Characteristics of LixNiO2 obtained by chemical delithiation[J].Journal of Power Sources,1999,81-82:401.
[7]	Broussely M;Perton F;Labat J et al.Li/LixNiO2 and Li/LixCoO2 rechargeable systems:comparative study and performance of practical cells[J].Journal of Power Sources,1993,43(1-3):209.
[8]	Yamada S;Fujiwara M;Kanda M .Synthesis and properties of LiNiO2 as cathode material for secondary batteries[J].Journal of Power Sources,1995,54:209.
[9]	Song M Y;Lee R .Synthesis by sol-gel method and electrochemical properties of LiNiO2 cathode material for lithium secondary battery[J].Journal of Power Sources,2002,111(01):97.
[10]	Kim J H;Sun Y K .Electrochemical performance of Li[LixNi(1-3x)/2Mn(1+x)/2]O2 cathode materials synthesized by a sol-gel method[J].Journal of Power Sources,2003,119-121:166.
[11]	Caurant D;Baffier N;Garcia B et al.Synthesis by a soft chemistry route and characterization of LiNixCo1-x O2 (0 ≤x ≤ 1) cathode materials[J].Solid State Ionics,1996,91(1-2):45.
[12]	Cho J;Park B .Preparation and electrochemical/thermal properties of LiNi0 74Co0 26 O2 cathode material[J].Journal of Power Sources,2001,92(1-2):35.
[13]	Fujita Y;Amine K;Maruta J et al.LiNi1-xCoxO2 prepared at low temperature using β-Ni1-xCoxOOH and either LiNO3 or LiOH[J].Journal of Power Sources,1997,68(01):126.
[14]	Lee Y S;Sun Y K;Nahm K S .Synthesis and characterization of LiNiO2 cathode material prepared by an adiphic acidassisted sol-gel method for lithium secondary batteries[J].Solid State Ionics,1999,118(1-2):159.
[15]	Han KS.;Fujita H.;Yoshimura M.;Song SW. .Single-step fabrication of Li1-xNi1+xOx and LiCoO2 films by soft solution-processing at 20-200 degrees C[J].Solid state ionics,2000(1/4):273-276.
[16]	Maruta J;Yasuda H;Yamachi M .Low-temperature synthesis of lithium nickelate positive active material from nickel hydroxide for lithium cells[J].Journal of Power Sources,2000,90(01):89.
[17]	Han CH.;Hong YS.;Kim K. .Cyclic performances of HT-LiCo0.8M0.2O2 (M=Al, Ni) powders prepared by the molten salt synthesis method[J].Solid state ionics,2003(3/4):241-247.
[18]	Han C H;Hong Y S;Park C M et al.Synthesis and electrochemical properties of lithium cobalt oxides prepared by molten-salt synthesis using the eutectic mixture of LiClLi2CO3[J].Journal of Power Sources,2001,92(1-2):95.
[19]	Gopukumar S;Chung K Y;Kim K B .Novel synthesis of layered LiNi1/2 Mn1/2 O2 as cathode material for lithium rechargeable cells[J].Electrochimica Acta,2004,49:803.
[20]	Kalyani P;Kalaiselvi N;Renganathan N G .Microwave-assisted synthesis of LiNiO2-a preliminary investigation[J].Journal of Power Sources,2003,123(01):53.
[21]	Banov B;Bourilkov J;Mladenov M .Cobalt stabilized layered lithium-nickel oxides cathodes in lithium rechargeable cells[J].Journal of Power Sources,1995,54(02):268.
[22]	Cho J;Jung H S;Park Y C et al.Electrochemical properties and thermal stability of LiδNi1-xCoxO2 cathode materials[J].Journal of the Electrochemical Society,2000,147(01):15.
[23]	J. Kim;K. Amine .The effect of tetravalent titanium substitution in LiNi_(1-x)Ti_xO_2 (0.025 ≤ x ≤ 0.2) system[J].Electrochemistry communications,2001(2):52-55.
[24]	Kim J;Amine K .A comparative study on the substitution of divalent trivalent and tetravalent metal ions in LiNi1-x-MxO2 (M = Cu2+ Al3+ and Ti4+)[J].Journal of Power Sources,2002,104(01):33.
[25]	Yoshio M;Noguchi H;Itoh J I et al.Preparation and properties of LiCoyMnxNi1-x-yO2 as a cathode for lithium ion batteries[J].Journal of Power Sources,2000,90(02):176.
[26]	Guilmard M et al.Effects of aluminum on the structural and electrochemical properties of LiNiO2[J].Journal of Power Sources,2003,115(02):305.
[27]	Park S H;Park K S;Sun Y K et al.Structural and electrochemical characterization of lithium excess and Al-doped nickel oxides synthesized by the sol-gel method[J].Electrochimica Acta,2001,46:1215.
[28]	Nishida Y;Nakane K;Satoh T .Synthesis and properties of gallium-doped LiNiO2 as the cathode material for lithium secondary batteries[J].Journal of Power Sources,1997,68(02):561.
[29]	C.-C. Chang;J. Y. Kim .Synthesis and Electrochemical Characterization of Divalent Cation-Incorporated Lithium Nickel Oxide[J].Journal of the Electrochemical Society,2000(5):1722-1729.
[30]	Pouillerie C.;Croguennec L. .Synthesis and characterization of New LiNi_(1-y)Mg_yO_2 Positive Electrode Materials for Lithium Ion Batteries[J].Journal of the Electrochemical Society,2000(6):2061-2069.
[31]	Naghash A R;Lee J Y .Lithium nickel oxyfluoride (Li1-z Ni1+z FyO2-y) and lithium magnesium nickel oxide (Li1-z (MgxNi1-x)1+zFyO2) cathodes for lithium rechargeable batteries[J].Electrochimica Acta,2001,46:2293.
[32]	P. Kalyani;N. Kalaiselvi;N. Muniyandi .On the Effects of Simultaneous Substitution of Al~(3+) and B~(3+) in LiNiO_2 Cathodes[J].Journal of the Electrochemical Society,2003(6):A759-A764.
[33]	Chowdari BVR.;Chow SY.;Rao GVS. .Cathodic behavior of (Co, Ti, Mg)-doped LiNiO2[J].Solid state ionics,2001(1/2):55-62.
[34]	Belharouak I;SunYK;LiuJ et al.Li (Ni1/3Co1/3Mn1/3)O2as a suitable cathode for high power applications[J].Journal of Power Sources,2003,123(02):247.
[35]	Chen Y;Wang G X;Konstantinov K et al.Synthesis and characterization of LiCoxMny Ni1-x-yO2 as a cathode material for secondary lithium batteries[J].Journal of Power Sources,2003,119-121:184.
[36]	刘汉三,杨勇,张忠如,林祖赓.锂离子电池正极材料锂镍氧化物研究新进展[J].电化学,2001(02):145-154.
[37]	Kweon H J;Kim S J;Park D G .Modification of LixNi1-y CoyO2 by applying a surface coating of MgO[J].Journal of Power Sources,2000,88(02):255.
[38]	Liu HS;Zhang ZR;Gong ZL;Yang Y .A comparative study of LiNi0.8Co0.2O2 cathode materials modified by lattice-doping and surface-coating[J].Solid state ionics,2004(3/4):317-325.
[39]	Ying J R;Wan C R et al.Surface treatment of LiNi 0 8Co0 2O2 cathode material for lithium secondary batteries[J].Journal of Power Sources,2001,102(1-2):162.

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材料期刊网

镍系锂离子电池正极材料的合成工艺及改性研究

Research on the Synthetic Technics and Modification of the Nickel-based Cathode Materials for Lithium Ion Battery

参考文献