回顾了近年来TiO2纳米管阵列在染料敏化太阳能电池中的应用现状和最新研究成果,综述了影响染料吸附量和电池效率的一些关键因素,包括管几何结构(长度、直径、顶部形态)、晶体结构(无定形、锐钛型、金红石型),以及表面改性、染料浸润敏化时间、温度和先进结构.当考虑所有这些因素时,现在纯纳米管体系太阳能电池的最高效率可以达到4％～5％,一些混合系统可以达到7％左右.还讨论了这两种体系现在存在的主要问题和提升的空间,并概述了今后的改进策略.
参考文献
| [1] | Macak JM;Tsuchiya H;Ghicov A;Schmuki P .Dye-sensitized anodic TiO2 nanotubes[J].Electrochemistry communications,2005(11):1133-1137. |
| [2] | Jennings JR;Ghicov A;Peter LM;Schmuki P;Walker AB .Dye-sensitized solar cells based on oriented TiO2 nanotube arrays: Transport, trapping, and transfer of electrons[J].Journal of the American Chemical Society,2008(40):13364-13372. |
| [3] | Kuang D;Brillet J et al.Application of highly ordered TiO2 nanotube arrays in flexible dye-sensitized solar cells[J].ACS Nano,2008,2(06):1113. |
| [4] | Kai Zhu;Todd B.Vinzant;Nathan R.Neale .Removing Structural Disorder from Oriented TiO2 Nanotube Arrays:Reducing the Dimensionality of Transport and Recombination in Dye-Sensitized Solar Cells[J].Nano letters,2007(12):3739-3746. |
| [5] | Roy P;Kim D;Lee K et al.TiO2 nanotubes and their application in dye-sensitized solar cells[J].Nanoscale,2009,2(01):45. |
| [6] | Andrei Ghicov;Sergiu P. Albu;Robert Hahn;Doohun Kim;Thomas Stergiopoulos;Julia Kunze;Carl-Albrecht Schiller;Polycarpos Falaras;Patrik Schmuki .TiO_(2) Nanotubes in Dye-Sensitized Solar Cells: Critical Factors for the Conversion Efficiency[J].Chemistry, an Asian journal,2009(4):520-525. |
| [7] | 赖跃坤,孙岚,左娟,林昌健.氧化钛纳米管阵列制备及形成机理[J].物理化学学报,2004(09):1063-1066. |
| [8] | 包祖国,陶杰,王玲,何雪婷.TiO2纳米管阵列对染料敏化太阳能电池性能的影响[J].电子元件与材料,2010(06):64-68. |
| [9] | Albu, S.P.;Tsuchiya, H.;Fujimoto, S.;Schmuki, P. .TiO_2 nanotubes - Annealing effects on detailed morphology and structure[J].European journal of inorganic chemistry,2010(27):4351-4356. |
| [10] | Sergiu P. Albu;Andrei Ghicov;Saule Aldabergenova;Peter Drechsel;Darren LeClere;George E. Thompson;Jan M. Macak;Patrik Schmuki .Formation of Double-Walled TiO_2 Nanotubes and Robust Anatase Membranes[J].Advanced Materials,2008(21):4135-4139. |
| [11] | Roy P;Kim D;Paramasivam I et al.Improved efficiency of TiO2 nanotubes in dye sensitized solar cells by decoration with TiO2 nanoparticles[J].Electrochemistry Communications,2009,11(05):1001. |
| [12] | Sun, WT;Yu, Y;Pan, HY;Gao, XF;Chen, Q;Peng, LM .CdS quantum dots sensitized TiO2 nanotube-array photoelectrodes[J].Journal of the American Chemical Society,2008(4):1124-1125. |
| [13] | Xian-Feng Gao;Wen-Tao Sun;Guo Ai;Lian-Mao Peng .Photoelectric performance of TiO_(2) nanotube array photoelectrodes cosensitized with CdS/CdSe quantum dots[J].Applied physics letters,2010(15):153104-1-153104-3. |
| [14] | Liu Y B;Zhou B X;Cai W M et al.Preparation of short,robust and highly ordered TiO2 nanotube arrays and their applications as electrode[J].Appl Cataly B:Environ,2009,92(3-4):326. |
| [15] | Liu, Y.;Li, M.;Wang, H.;Zheng, J.;Xu, H.;Ye, Q.;Shen, H. .Synthesis of TiO_2 nanotube arrays and its application in mini-3D dye-sensitized solar cells[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,2010(20):205103-1-205103-6. |
| [16] | Lai Y K;Chen Y C;Lin C J et al.A facile method for synthesis of Ag/TiO2 nanostructures[J].Materials Letters,2008,62(21-22):3688. |
| [17] | ChengLin Wang;Lan Sun;Hong Yun;Jing Li;YueKun Lai;ChangJianLin .Sonoelectrochemical synthesis of highly photoelectrochemically active TiO_2 nanotubes by incorporating CdS nanoparticles[J].Nanotechnology,2009(29):295601-6. |
| [18] | Park JH;Lee TW;Kang MG .Growth, detachment and transfer of highly-ordered TiO2 nanotube arrays: use in dye-sensitized solar cells[J].Chemical communications,2008(25):2867-2869. |
| [19] | Kim D;Ghicov A;Schmuki P .TiO2 Nanotube arrays: Elimination of disordered top layers ("nanograss") for improved photoconversion efficiency in dye-sensitized solar cells[J].Electrochemistry communications,2008(12):1835-1838. |
| [20] | Song, YY;Lynch, R;Kim, D;Roy, P;Schmuki, P .TiO2 Nanotubes: Efficient Suppression of Top Etching during Anodic Growth[J].Electrochemical and solid-state letters,2009(7):C17-C20. |
| [21] | Albu, S.P.;Schmuki, P. .Highly defined and ordered top-openings in TiO_2 nanotube arrays[J].physica status solidi(RRL): rapid research letterse,2010(7):151-153. |
| [22] | Mor G K;Shankar K et al.Use of highly-ordeared TiO2nanotube arrays in dye-esensitized sdar cells[J].Nano Letters,2005,6:215. |
| [23] | Sergiu P. Albu;Doohun Kim;Patrik Schmuki .Growth of Aligned TiO2 Bamboo-Type Nanotubes and Highly Ordered Nanolace[J].Angewandte Chemie,2008(10):1916-1919. |
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