为了建立Ti-Al-Cr-Mn系的热力学数据库,对该四元系中子三元系Al-Cr-Mn体系的富Al角作了热力学评估.对于该三元系中的化学计量比化合物,如Al<,6>Mn和Al<,12>Mn等采用模型Al<,m>(Cr,Mn)<,n>,θ Al<,7>Cr、η_Al<,11>Cr2及μ_Al<,4>(Cr,Mn)相选用点阵模型Al<,m>(Al,Cr,Mn)<,n>,T_HTAl<,11>Mn<,4>及γ2_aAl<,8>(Cr,Mn)<,5>相的点阵模型分别处理为(Al,Mn)<,29>(Cr,Mn)<,10>和(Al,Cr)<,12>(Al,Cr,Mn)<,5>(Al,Cr,Mn)<,9>.并对该系进行一系列热力学优化及相图计算并与相应的实验结果作了比较,发现计算结果与大部分实验结果基本吻合,但在1 283 K等温面中,Al<,8>(Cr,Mn)<,5>化合物只存在一个γ2_aAl<,8>(Cr,Mn)<,5>结构,而实验相图中还存在γ1 βAl<,8>(Cr,Mn)<,5>结构.分析Al-Mn体系认为,γ1_βAl<,8>(Cr,Mn)<,5>在1 283 K时不会稳定存在,且1173 K等温面中出现η_Al<,11>Cr2相,而实验相图中不存在该相.通过对Al-Cr系调研可以发现,η_Al<,11>Cr2相在温度下降到1204 K时通过L+Al<,4>Cr→Al<,11>Cr2生成,因此,在外推Al-Cr-Mn三元系时,η Al<,11>Cr2相在1173 K时会稳定存在.
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