根据阻燃剂在聚氨酯中的化学反应性,可以将聚氨酯的阻燃剂分为非反应型阻燃剂、反应型阻燃剂和纳米材料阻燃剂三大类.并根据这三大类分别综述了阻燃聚氨酯的研究现状,简要介绍了各类阻燃剂的阻燃机理,阐述了其使用过程中存在的优缺点,并展望了阻燃聚氨酯的发展趋势.
参考文献
| [1] | 徐培林;张淑琴.聚氨酯材料手册[M].北京:化学工业出版社,2002:179. |
| [2] | 欧育湘.国外阻燃剂发展动态及对发展我国阻燃剂工业之浅见[J].精细与专用化学品,2003(02):3-6. |
| [3] | Bian XC;Tang JH;Li ZM .Flame Retardancy of Whisker Silicon Oxide/Rigid Polyurethane Foam Composites with Expandable Graphite[J].Journal of Applied Polymer Science,2008(6):3871-3879. |
| [4] | Ye, L;Meng, XY;Ji, X;Li, ZM;Tang, JH .Synthesis and characterization of expandable graphite-poly(methyl methacrylate) composite particles and their application to flame retardation of rigid polyurethane foams[J].Polymer Degradation and Stability,2009(6):971-979. |
| [5] | D.K. Chattopadhyay;Dean C. Webster .Thermal stability and flame retardancy of polyurethanes[J].Progress in Polymer Science,2009(10):1068-1133. |
| [6] | 杨伟平;戴震;许戈文 .聚氨酯阻燃的研究进展[J].PU技术,2010,21(05):66. |
| [7] | Seong-Woo Choi;Sharon Ohba;Zdenka Brunovska;Kasinee Hemvichian;Hatsuo Ishida .Synthesis, characterization and thermal degradation of functional benzoxazine monomers and polymers containing phenylphosphine oxide[J].Polymer Degradation and Stability,2006(5):1166-1178. |
| [8] | 史以俊,罗振扬,何明,顾晓利.含磷阻燃剂对聚氨酯硬泡燃烧特性影响的研究[J].聚氨酯工业,2009(05):23-25. |
| [9] | Wang CS.;Shieh JY. .Synthesis and properties of epoxy resins containing 2-(6-oxid-6H-dibenz[c,e][1,2]oxaphosphorin-6-yl)1,4-benzenediol[J].Polymer: The International Journal for the Science and Technology of Polymers,1998(23):5819-5826. |
| [10] | Chu C S;Fu S C;Chen L W et al.Aryl phosphinate anhydride curing for flame retardant epoxy networks[J].Polymer International,1998,47(02):203. |
| [11] | Lin CH.;Wang CS.;Wu CY. .Synthesis and properties of phosphorus-containing advanced epoxy resins. II[J].Journal of Applied Polymer Science,2000(1):228-235. |
| [12] | Shieh JY.;Wang CS. .Synthesis and properties of novel phosphorus-containing hardener for epoxy resins[J].Journal of Applied Polymer Science,2000(9):1636-1644. |
| [13] | Ging Ho Hsiue;Ying Ling Liu;Hsin Hao Liao .Flame-Retardant Epoxy Resins: An Approach from Organic-Inorganic Hybrid Nanocomposites[J].Journal of Polymer Science, Part A. Polymer Chemistry,2001(7):986-996. |
| [14] | Wang Chun Shan;Lin Ching Hsuan .Properties and curing kinetic of diglycidyl ether of bisphenol a cured with a phosphorus-containing diamine[J].Journal of Applied Polymer Science,1999(7):1635-1645. |
| [15] | Schafer A;Seibold S;Lohstroh W;Walter O;Doring M .Synthesis and properties of flame-retardant epoxy resins based on DOPO and one of its analog DPPO[J].Journal of Applied Polymer Science,2007(2):685-696. |
| [16] | 张军;纪奎江;夏延致.聚合物燃烧与阻燃技术[M].北京:化学工业出版社,2005:34. |
| [17] | 房晓敏,欧育湘.阻燃剂V6的合成及其在聚氨酯中的应用[J].塑料工业,2006(03):54-56. |
| [18] | Lin CH;Hwang TY;Taso YR;Lin TL .Phosphorus-containing epoxy curing agents via imine linkage[J].Macromolecular chemistry and physics,2007(24):2628-2641. |
| [19] | Lewin M;Atlas S M;Pearce E M.Flame retardant polymeric materials[M].New York:Plenum Press,1978:53. |
| [20] | Roy W Tess;Gary W Poehlein.Applied polymer science[M].Washington DC:Am Chem Soc,1985:59. |
| [21] | 张军;纪奎江;夏延致.聚合物燃烧与阻燃技术[M].北京:化学工业出版社,2005:91. |
| [22] | 吕咏梅.我国无机阻燃剂研究及应用进展[J].塑料助剂,2004(04):1-3. |
| [23] | 王勋章,姜丹蕾,李美荣,高天坤.无卤阻燃剂季戊四醇双磷酸蜜胺盐的合成与应用[J].化工科技,2006(03):15-18. |
| [24] | 欧育湘 .从欧盟对阻燃剂危害性的评估看我国阻燃剂产业发展[J].中国化工信息,2004,38(05):12. |
| [25] | Price D;Liu Y;Milnes G J et al.An investigation into the mechanism of flame retardancy and smoke suppression by mela mine in flexible polyurethane foam[J].Fire and Materials,2002,26(425):201. |
| [26] | 殷锦捷,孙家琛.环氧树脂改性水性聚氨酯阻燃涂料的研究[J].电镀与涂饰,2009(05):51-53. |
| [27] | Thomas L;Munchberg D E;Hanners O et al.Intumerscent textile,useful for the production of curtains,sun screens,tents and clothing,is coated with a polyacrylate containing aqueous dispersion,an isocyanate or melamine formaldehyde and a flame retardant[P].US,20060057915A1,2006. |
| [28] | Hana Matsushita;Sang-Hyeup Lee;Meyoungju Joung;Bruce Clapham;Kim D.Janda .Smart cleavage reactions:the synthesis of benzimidazoles and benzothiazoles from polymer-bound esters[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,2004(2):313-316. |
| [29] | Ma Haiyun;Tong Lifang;Xu Zhongbin et al.A novel intumescent flame retardant:Synthesis and application in ABS copolymer[J].Polymer Degradation and Stability,2007,92(01):720. |
| [30] | 张静,吴清国,赵亚娟.合成革用聚氨酯浆料阻燃性能的研究[J].科技信息,2008(26):337-338. |
| [31] | Gilman J W .Flammability and thermal stability studies of polymer-layered silicates (clay) nanocomposites[J].Applied Clay Science,2011,15(1-2):31. |
| [32] | 烟台万华超纤维股份有限公司 .一种阻燃性聚氨酯合成革及其制备方法[P].中国,1693577A,2005-11-09. |
| [33] | 王炜,徐鹏.水性聚氨酯阻燃剂的研制[J].印染助剂,2004(05):32-35. |
| [34] | 韩冬;吕侠;朱敏 等.阻燃型聚氨酯水性分散体及其制备方法[P].中国,1749291A,2007. |
| [35] | Celebi F.;Polat O.;Aras L.;Gunduz G.;Akhmedov IM. .Synthesis and characterization of water-dispersed flame-retardant polyurethane resin using phosphorus-containing chain extender[J].Journal of Applied Polymer Science,2004(2):1314-1321. |
| [36] | 王萃萃,戴震,许戈文.硬段阻燃改性水性聚氨酯的研究[J].中国涂料,2010(08):57-60. |
| [37] | Song, L;Hu, Y;Tang, Y;Zhang, R;Chen, ZY;Fan, WC .Study on the properties of flame retardant polyurethane/organoclay nanocomposite[J].Polymer Degradation and Stability,2005(1):111-116. |
| [38] | Huang, GB;Gao, JR;Li, YJ;Han, L;Wang, X .Functionalizing nano-montmorillonites by modified with intumescent flame retardant: Preparation and application in polyurethane[J].Polymer Degradation and Stability,2010(2):245-253. |
| [39] | 王萃萃;江飞;许戈文 .无卤阻燃水性聚氨酯的制备及研究[J].聚氨酯,2010,95(04):71. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%