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LPCNi3.55Co0.75Mn0.4Al0.3 hydrogen storage alloy was investigated, and the effects of thickness of its strip casting ingots(as-cast) on the electrochemical performances were discussed. It was found that the 0.2 C discharge capacity increased with the increase of the thickness (from 1 mm to 10 mm) of the ingots, mainly due to the enlargement of the unit cell volume; Among the thickness of the ingots in our study, 10 mm sample showed a better activation property; LPCNi3.55Co0.75Mn0.4Al0.3 alloy with 10mm showed higher comprehensive properties than those with other thickness under 1C rate.

参考文献

[1] Sakai Tetsuo;Uehara Ituki .Ishikawa Hiroshi. R &D on metal hydride materials and Ni-MH batteries in Japan[J].Journal of Alloys and Compounds,1999,293-295:762.
[2] Sandrock Gary .A panoramic overview of hydrogen storage alloys from a gas reaction point of view[J].Journal of Alloys and Compounds,1999,293-295:877.
[3] Mishima R;Miyamura H;Sakai T et al.Hydrogen storage alloys rapidly solidified by the melt-spinning method and their characteristics as metal hydride electrodes[J].Journal of Alloys and Compounds,1993,192:176.
[4] Nakamura H;Nakamura Y;Fujitani S et al.Influence of annealing on hydrogenation characteristics and microstructure of LaNi4.55Al0.45 alloy[J].Journal of Alloys and Compounds,1995,218:216.
[5] Hu Weikang;Kim Dongmyung;Jeon Seok-Won et al.Studies on Co-free rare-earth-based hydrogen storage alloys[J].Journal of Alloys and Compounds,1998,270:255.
[6] Zhang LY .Electrochemical characteristics of AB sub 5 -type hydrogen storage alloys solidified at different cooling rates[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(0):621-625.
[7] Zhang L Y;Klein Michael;Czajkowski Bob et al.Effects of cooling rate during casting on performance of metal hydride electrodes and nickel-metal hydride batteries[J].Journal of Alloys and Compounds,1999,293-295:608.
[8] Li Chuanjian;Wang Xinlin;Li Xiumei et al.The effect of cast rate on the electrochemical properties of Ml(NiCoMnTi)5 hydrogen storage alloy[J].金属学报,1998,34(03):288.
[9] Li Chuanjian;Wang Xinlin;Wang Chongyu .Temperature characterization of the melt-spun Mm(NiCoMnTi)5 hydrogen storage alloy and the mechanism therein[J].电源技术,1998,22(02):68.
[10] Cai Guanming;Chen Changpin;An Yue et al.Hydrogen Absorption Themodymic Properties of RE Based Hydrogen Storage Alloy in Benzene[J].Journal of Rare Earths,2002,20(01):29.
[11] Ye H.;Zhang H. .Effect of Ni content on the structure, thermodynamic and electrochemical properties of the non-stoichiometric hydrogen storage alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):163-171.
[12] 任可,雷永泉,陈立新,张庆安,王启东.Ml(Ni4.55-xCOxMn0.4Ti0.05)合金的相结构与电化学性能[J].金属学报,2000(04):364-369.
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