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制备不同成分的TiNbSn合金,分别进行了DTA、XRD和TEM分析.结果表明,随着Sn含量的增加,TiNbSn合金晶粒尺寸减小;当Sn含量≤4.2mol%时,合金未发生马氏体相变.当Sn含量为4.71mol%和5.02mol%时,合金在加热过程中热弹性马氏体消失,在冷却时形成.这两种合金具有对室温相以及高温相的形状记忆效应.

参考文献

[1] Eiji Takahashi;Tasuku Sakurai;Sadao Watanabe .Effect of Heat Treatment and Sn Content on Superelasticity in Biocompatible TiNbSn Alloys[J].Materials transactions,2002(12):2978-2983.
[2] Kawashima A;Watanabe S;Asamik .XPS study of corrosion behavior of Ti-18Nb-4Sn shape memory alloy in a 0.05 mass% HCl solution[J].MATERIALS TRANSACTIONS,2003,44(05):1405-1411.
[3] 李炎,祝要民,杜三民,张兴渊.TiNbSn合金室温组织结构的电子显微分析[J].电子显微学报,2005(04):288.
[4] Hiroaki Matsumoto;Sadao Watanabe;Shuji Hanada .Microstructures and mechanical properties of metastable beta TiNbSn alloys cold rolled and heat treated[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2007(1/2):146-155.
[5] Hao YL;Li SJ;Sun SY;Zheng CY;Yang R .Elastic deformation behaviour of Ti-24Nb-4Zr-7.9Sn for biomedical applications.[J].Acta biomaterialia,2007(2):277-286.
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