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An icosahedral phase in as-cast Mg 5. 78Zn-0.89Y-0.48Zr (wt-%) alloy has been identified with transmission electron microscope (TPM) The selected area diffraction patterns (SADP) from the phase show a five-fold symmetry of a quasicrystalline structure. The energy dispersive X-ray spectra (EDXS) indicate that the quaternary phase has a chemical composition of 67.6Zn-1 9.4Mg-8,1 Y-4 9Zr in at -%

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