以Y(NO3)3·6H2O和Fe(NO3)3·9H2O为原料,分别与NaOH和C6H8O7·H2O经室温固相反应合成了粒径分布为20～40 nm的YIG纳米粉体.采用XRD和TEM对粉体产物的晶体结构、形貌、粒径进行了表征,并用该粉体制备了YIG多晶铁氧体,讨论了烧结温度对YIG铁氧体显微结构和磁性能的影响.结果表明:选取柠檬酸为原料其YIG结晶化温度比以NaOH为原料低了接近100 ℃;在1320 ℃烧结3 h可得到显微结构均匀致密的YIG铁氧体,其饱和磁化强度受烧结温度影响很小,基本上在170 mT左右.
参考文献
| [1] | 都有为.铁氧体[M].南京:江苏科学技术出版社,1996:172-204. |
| [2] | Harris, VG;Geiler, A;Chen, YJ;Yoon, SD;Wu, MZ;Yang, A;Chen, ZH;He, P;Parimi, PV;Zuo, X;Patton, CE;Abe, M;Acher, O;Vittoria, C .Recent advances in processing and applications of microwave ferrites[J].Journal of Magnetism and Magnetic Materials,2009(14):2035-2047. |
| [3] | Garskaite E;Gibson K;Leleckaite A;Glaser J;Niznansky D;Kareiva A;Meyer HJ .On the synthesis and characterization of iron-containing garnets (Y3Fe5O12, YIG and Fe3Al5O12, IAG)[J].Chemical Physics: A Journal Devoted to Experimental and Theoretical Research Involving Problems of Both a Chemical and Physical Nature,2006(2-3):204-210. |
| [4] | Sanchez RD;Ramos CA;Rivas J;Vaqueiro P;Lopez-Quintela MA .Ferromagnetic resonance and magnetic properties of single-domain particles Of Y3Fe5O12 prepared by sol-gel method[J].Physica, B. Condensed Matter,2004(1/4):104-107. |
| [5] | S. Hosseini Vajargah;H.R. Madaah Hosseini;Z.A. Nemati .Synthesis of nanocrystalline yttrium iron garnets by sol-gel combustion process: The influence of pH of precursor solution[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2006(1/3):211-215. |
| [6] | Sōzeri H;Ghazanfari N .The Synthesis of Nanocrystalline YIG in an Ammonium Nitrate Melt[J].Materials Chemistry and Physics,2008,79(08):1-5. |
| [7] | L.Fernandez-Garcia;M.Suarez;J.L.Menendez .Synthesis of mono and multidomain YIG particles by chemical coprecipitation or ceramic procedure[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(1):196-199. |
| [8] | Motlagh, ZA;Mozaffari, M;Amighian, J .Preparation of nano-sized Al-substituted yttrium iron garnets by the mechanochemical method and investigation of their magnetic properties[J].Journal of Magnetism and Magnetic Materials,2009(13):1980-1984. |
| [9] | 黄磊 .低温固相反应法制备CoFe<,2>O<,4>，Co<,x>Zn<,1-x>Fe<,2>O<,4>纳米颗粒与磁性研究[D].兰州大学,2009. |
| [10] | Fashen Li;Haibo Wang;Li Wang .Magnetic properties of ZnFe_2O_4 nanoparticles produced by a low-temperature solid-state reaction method[J].Journal of Magnetism and Magnetic Materials,2007(1):295-299. |
| [11] | 焦万丽,张磊.微波辐射低温固相反应法制备NiFe2O4纳米片晶[J].人工晶体学报,2008(05):1215-1218,1223. |
| [12] | 庄稼,迟燕华,石均宁,王清成,张欢,贾殿赠.低热固相反应制备纳米铈镍铁氧体粉末[J].功能材料,2002(03):253-255. |
| [13] | 张枫,徐庆,陈文,黄端平,刘韩星,周建.BaxSr1-xTiO3的EDTA-柠檬酸法合成与电性能研究[J].压电与声光,2007(01):71-73,76. |
| [14] | Van Uitert L O;Swanekamp F W;Preziosi S .Ferrimagnetic Resonance Line Widths and Phase Distributions in Sintered Yttrium Iron Garnets[J].Journal of the American Ceramic Society,1959,42(10):471-473. |
| [15] | 姜寿亭;李卫.凝聚态磁性物理[M].北京:北京科学技术出版社,2003:84-94. |
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