详细研究了氧化铝悬浮液的分散行为及固含量、pH值和聚丙烯酸(PAA)添加量对分散行为的影响.实验结果表明,固含量、pH值和PAA添加量对氧化铝悬浮液的分散行为有显著影响.粘度法及Zeta电位测试法所反映的悬浮液分散性随pH值和分散剂添加量的变化规律基本一致.当pH=9~10、分散剂添加量的质量分数为2.0%~2.5%时粘度最低、Zeta电位绝对值最大、分散效果最好.分散剂添加量存在最佳范围,且最佳范围不随固含量的变化而改变.随固含量的增加,粘度开始缓慢上升,到达一定程度后迅速增大.
Dispersion behavior of alumina suspension and effects of the solid loading,pH value and polyacrylic acid(PAA) content on the dispersion behavior are examined in detail.The experimental results show that the solid loading,pH value and PAA content significantly influence the dispersion behavior.The variation tendencies of the suspension dispersity with the changes of pH value and dispersant content from the viscosity measurement are almost consistent with those from the Zeta potential measurement.The viscosity achieves the minimum,absolute value of the Zeta potential achieves the maximum and the dispersity achieves the best at pH=9~10 and the dispersant content 2.0%~2.5%(wt).The dispersant content has a suitable range,and the suitable range does not change with the solid loading.The viscosity increases slowly at first and rapidly after achieving a certain degree,with enhancing the solid loading.
参考文献
[1] | Lange F .Powder processing science and technology for increased reliability[J].Journal of the American Ceramic Society,1989,72(01):3. |
[2] | 刘宣勇;苏文强;钱瑞芬 .陶瓷粉料在液相介质中分散的稳定机制[J].陶瓷工程,1999,33(01):52. |
[3] | 黄新民,吴玉程,郑玉春.纳米功能复合涂层[J].功能材料,2000(04):419-420. |
[4] | 高濂;孙静;刘阳桥.纳米粉体的分散和表面改性[M].北京:化学工业出版社,2003 |
[5] | Binner J;Murfin A .The effect of temperature,heating method and state of dispersion on the vaccum filter casting of alumina suspensions[J].Journal of the European Ceramic Society,1998,18:791. |
[6] | Blanco M;Rand B;Riley F .Polymeric stabilization of aqueous suspensions of barium titanate.Part 1:Effect of pH[J].Journal of the European Ceramic Society,2000,20(10):1587. |
[7] | 李登好,郭露村.超细氧化铝水悬浮液分散稳定性研究[J].硅酸盐通报,2005(01):36-40. |
[8] | 朱新文,江东亮,谭寿洪,张兆泉.氧化铝粉体在硅溶胶中分散行为的研究[J].硅酸盐学报,2001(03):263-266. |
[9] | Bronswijk W;Watling H;Yu Z .A study of the adsorption of acyclic polyols on hydrated alumina[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1999,157(1-3):85. |
[10] | 李登好,郭露村.α-Al2O3-H2O-聚丙烯酸悬浮液流变性的研究[J].硅酸盐学报,2004(01):80-84. |
[11] | Napper D.Polymeric stabilization of colloidal dispersions[M].London,UK:Academic Press,1983:183. |
[12] | 张立明,马天,杨金龙,黄勇.氧化铝悬浮液剪切流变特性的研究[J].无机材料学报,2004(05):1145-1150. |
[13] | Guo LC.;Uchida N.;Uematsu K.;Zhang Y. .Adsorption effects on the rheological properties of aqueous alumina suspensions with polyelectrolyte[J].Journal of the American Ceramic Society,1998(3):549-556. |
[14] | Hunter R.Zeta potential in colloid science-principle and application[M].New York:Academic Press,Inc,1981 |
[15] | Ogden A;Lewis J .Effect of unabsorbed polymer on the stability of weakly flocculated suspensions[J].Langmuir,1996,12:3413. |
[16] | 缪大梅,周竹发,王淑梅.氧化铝陶瓷凝胶注模成型工艺浆料流变性的研究[J].江苏陶瓷,2005(02):3-5. |
[17] | 王浩 et al.高聚物对陶瓷料浆性能的影响机理[J].山东陶瓷,2000,23(04):16. |
[18] | 陈友强,张新霓,陈沙鸥,戚凭.共聚物型分散剂对α-Al2O3水悬浮体系分散性能的影响[J].硅酸盐学报,2005(02):170-174. |
[19] | 谭训彦,尹衍升.氧化铝陶瓷的凝胶注模成型研究 (1)悬浮液的分散与流变性[J].山东大学学报(工学版),2004(03):1-4. |
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