在对LaNi5晶体结构进行分析之后,认为一个晶胞是由3个十二面体,9个八面体,6个六面体和36个四面体所组成.四面体间隙太小,不能储存氢原子.这样,一个晶胞内可以储存18个氢原子,氢原子与金属原子比为H/M=1.LaNi5最大储氢量为1.379%.
参考文献
[1] | 钱存富,杜昊,王洪祥.LaNi5型储氢材料最大储氢量的讨论[J].稀有金属材料与工程,2000(01):25-27. |
[2] | 周公度;段连运.结构化学基础[M].北京:北京大学出版社,2001:475. |
[3] | 车云霞;申泮文.化学元素周期系[M].天津:南开大学出版社,1999:112. |
[4] | Vainshtein B K;Fridkin V M;Indenbom V L.Modern Crystallography II[M].New York: Springer-Verlag,1982:12-71. |
[5] | K.Nakatsuka;M.Yoshino .Roles of the hydride forming and non-forming elements in hydrogen storage alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(0):222-226. |
[6] | H.Yukawa;T.Matsumura .Chemical bond state and hydride stability of hydrogen storage alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(0):227-230. |
[7] | Morinaga M;Yukawa H;Nakatsuka K;Takaji M .Roles of the Constituent Elements and Design of Hydrogen Storage Alloys[J].Journal of Alloys and Compounds,2002,330-332:20-24. |
[8] | G.Liang;J.Huot;R.Schulz .Hydrogen storage properties of the mechanically alloyed LaNi_5-based materials[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2001(1):133-139. |
[9] | D.V. Schur;S.Yu. Zaginaichenko;Z.A. Matysina .Hydrogen in lanthan-nickel storage alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2002(0):70-75. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%