大豆油基聚氨酯泡沫塑料的制备

材料导报, 2008, 22(Z2): 405-407.

大豆油基聚氨酯泡沫塑料的制备

王丽军 ^1, , 李渊 ^2, , 魏俊富 ^3, , 路华飞 ^4,

1.天津工业大学材化学院,天津,300160;天津工业大学改性与功能纤维天津市重点实验室,天津,300160

2.天津工业大学材化学院,天津,300160;天津工业大学改性与功能纤维天津市重点实验室,天津,300160

3.天津工业大学材化学院,天津,300160;天津工业大学改性与功能纤维天津市重点实验室,天津,300160

4.廊坊华宇创新科技有限公司,廊坊,065001

基金项目: 天津工业大学青年基金(029515) 天津市奥华实业有限公司提供横向经费支持项目

关键词：大豆油 , 环氧大豆油 , 大豆油多元醇 , 聚氨酯泡沫塑料

Preparation of Soybean Soil-based Polyurethane Foams

以大豆油为原料,经环氧化反应、开环反应制备了大豆油基多元醇,并由此大豆油基多元醇与多亚甲基多苯基多异氰酸酯(PAPl27)反应制备了大豆油基聚氨酯泡沫塑料.制备环氧大豆油阶段,采用改进的过氧甲酸原位生成法,在优化条件下制备出环氧值为6.7的环氧大豆油;制备多元醇阶段,以甲醇与水的混合溶液为开环试剂,在氟硼酸催化作用下进行开环反应,制得羟值为409mgKOH/g的大豆油多元醇;由此多元醇合成了大豆油基聚氨酯泡沫塑料,并对此大豆油基聚氨酯泡沫塑料与聚醚型聚氨酯泡沫塑料进行了热重对比分析.实验结果表明:前者在热稳定性方面优于后者,显示出大豆油基多元醇在聚氨酯行业中广阔的应用前景.

参考文献

[1]	Tu YC;Kiatsimkul P;Suppes G;Hsieh FH .Physical properties of water-blown rigid polyurethane foams from vegetable oil-based polyols[J].Journal of Applied Polymer Science,2007(2):453-459.
[2]	孙刚,刘预,冯芳,孙洪广,边开胜,胡克鳌.聚氨酯泡沫材料的研究进展[J].材料导报,2006(03):29-32,36.
[3]	Biermann U.;Lang S.;Luhs W.;Machmuller G.;Metzger JO. Klaas MR.;Schafer HJ.;Schneider MP.;Friedt W. .New syntheses with oils and fats as renewable raw materials for the chemical industry [Review][J].Angewandte Chemie International Edition,2000(13):2206-2224.
[4]	Petrovic ZS.;Zhang W.;Guo A. .Structure and properties of polyurethanes based on halogenated and nonhalogenated soy-polyols[J].Journal of Polymer Science, Part A. Polymer Chemistry,2000(22):4062-4069.
[5]	Javni I.;Zhang W.;Petrovic ZS. .Effect of different isocyanates on the properties of soy-based polyurethanes[J].Journal of Applied Polymer Science,2003(13):2912-2916.
[6]	George J.Piazza;Thomas A.Foglia .One-Pot Synthesis of Fatty Acid Epoxides from Triacylglycerols Using Enzymes Present in Oat Seeds[J].Journal of the American Oil Chemists' Society,2006(12):1021-1025.
[7]	A.P.Singh;M.Bhattacharya .Viscoelastic Changes and Cell Opening of Reacting Polyurethane Foams From Soy Oil[J].Polymer engineering and science,2004(10):1977-1986.
[8]	Warwel S;Brüse F;Demes C et al.Polymers and surfactants on the basis of renewable resources[J].Chemosphere,2001,43:39.
[9]	J.-P. Latere Dwan'Isa;A. K. Mohanty;M. Misra;L. T. Drzal;M. Kazemizadeh .Novel Biobased Polyurethanes Synthesized from Soybean Phosphate Ester Polyols: Thermomechanical Properties Evaluations[J].Journal of polymers and the environment,2003(4):161-168.
[10]	张兴英;李齐方.高分子科学实验[M].北京:化学工业出版社,2004
[11]	Javni I;Zhang W;Petrovi c Z S .Soybean-oil-based polyisocyanurate rigid foarns[J].Journal of Polymers and the Environment,2004,12(03):123.

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